Food Chemistry

Food Chemistry
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FOOD CHEMISTRY A unique book detailing the impact of food adulteration, food toxicity and packaging on our nutritional balance, as well as presenting and analyzing technological advancements such as the uses of green solvents with sensors for non-destructive quality evaluation of food. Food Chemistry: The Role of Additives, Preservatives and Adulteration is designed to present basic information on the composition of foods and the chemical and physical changes that their characteristics undergo during processing, storage, and handling. Details concerning recent developments and insights into the future of food chemical risk analysis are presented, along with topics such as food chemistry, the role of additives, preservatives, and food adulteration, food safety objectives, risk assessment, quality assurance, and control. Moreover, good manufacturing practices, food processing systems, design and control, and rapid methods of analysis and detection are covered, as well as sensor technology, environmental control, and safety. The book also presents detailed information about the chemistry of each major class of food additive and their multiple functionalities. In addition, numerous recent findings are covered, along with an explanation of how their quality is ascertained and consumer safety ensured. Audience The core audience of this book include food technologists, food chemists, biochemists, biotechnologists, food, and beverage technologists, and nanoscientists working in the field of food chemistry, food technology, and food and nanoscience. In addition, R&D experts, researchers in academia and industry working in food science/safety, and process engineers in industries will find this book extremely valuable.

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Группа авторов. Food Chemistry

Table of Contents

List of Illustrations

List of Tables

Guide

Pages

Food Chemistry. The Role of Additives, Preservatives and Adulteration

Preface

1. Food Chemistry: Role of Additives, Preservatives, and Adulteration

1.1 Introduction

1.2 Categories of Food Colors

1.3 Natural Colors Are Best Over Artificial Colors

1.4 Classification of Food Colorants. 1.4.1 Natural Colorants

1.4.2 Synthetic Colorants

1.4.2.1 Water Soluble Synthetic Colors

1.4.2.2 Fat Soluble Synthetic Colorants

1.4.2.3 Lake Colorants

1.4.2.3.1 How to Minimize the Health Risk of Food Additives Consumption?

1.5 Classification of Food Additives

1.5.1 Why Food Colors Are Preferred

1.5.2 E-Numbering

1.6 Food Spoilage and Preservation

1.6.1 Causes of Spoilage

1.6.2 Principle of Food Preservation

1.7 Preservatives

1.7.1 Factors Affecting Preservative Efficiency. 1.7.1.1 Interaction With Formulation Components

1.7.1.2 Properties of Preservatives

1.7.1.3 Effect of Containers

1.7.1.4 Types of Micro-Organisms

1.7.1.5 Influence of pH

1.7.2 Factors Affecting Chemical Preservation

1.7.3 Classification of Chemical Preservatives

1.7.4 Types of Chemical Preservatives

1.7.5 Natural Chemical Preservatives

1.7.6 Methods of Food Preservation

1.8 Antioxidants

1.9 Oils and Spices

1.10 Introduction to Hurdle Technology

1.10.1 Advantages of Food Additives and Preservatives

1.10.2 Disadvantages of Food Additives and Preservatives

1.10.3 Effects of Food Additives and Food Preservatives

1.10.4 Safety of Food Additives and Preservatives

1.11 Adulteration

1.11.1 History of Food Adulteration

1.11.2 Types of Food Adulteration

1.11.2.1 Intentional Adulteration

1.11.2.2 Incidental Adulteration

1.11.2.3 Metallic Adulteration

1.11.3 A Food Is Considered Adulterated if It Has the Following Factors

1.11.4 Effects of Adulterated Food on Human Health

1.11.5 Reasons for Food Adulteration

1.11.6 Methods of Food Adulteration

1.11.7 Trends of Food Adulteration in Developing Countries

1.12 Food Safety and Standards Act

1.12.1 Few Steps to Avoid Adulteration

1.12.2 Detection Methods of Adulteration

1.12.3 Technique to Check Food Adulteration

1.13 Conclusion

References

2. Additives and Preservatives Used in Food Processing and Preservation, and Their Health Implication

Abbreviations

2.1 Introduction

2.2 Merits and Demerits of Food Additives and Preservatives. 2.2.1 Merits of Food Additives and Preservatives

2.2.2 Demerits of Food Additives and Preservatives

2.3 Types of Food Additives and Preservatives

2.3.1 Preservatives

2.3.2 Nutritional Additives

2.3.3 Flavoring Agent

2.3.4 Coloring Agent

2.3.5 Texturizing Agent

2.3.6 Miscellaneous Additives. 2.3.6.1 Acidity Regulator

2.3.6.2 Anti-Caking Agent

2.3.6.3 Antifoaming Agent

2.3.6.4 Flour Treatment Agents

2.3.6.5 Fat Replacers

2.3.6.6 Sweeteners

2.3.6.6.1 Nutritive Sweeteners

2.3.6.6.2 Non-Nutritive Sweetener

2.3.6.6.3 Artificial Non-Nutritive Sweeteners

2.3.6.7 Leavening Agent

2.3.6.8 Firming Agent

2.3.6.9 Glazing Agent

2.3.6.10 Humectant

2.3.6.11 Sequestering Agent

2.3.6.12 Gelling Agent

2.3.6.13 Propellants

2.3.6.14 Foaming Agent

2.3.6.15 Seasoning

2.3.6.16 Curing Agents

2.3.6.17 Probiotics

2.3.6.18 Other Food Additives

2.3.6.19 Indirect Food Additives

2.4 Health Effect of Food Additives and Preservatives

2.5 Conclusion

References

3. Role of Packaging in Food Processing

3.1 Introduction

3.2 State-of-the-Art

3.3 Raw Materials Used in Food Packaging

3.3.1 Metals

3.3.2 Glass

3.3.3 Plastics

3.3.4 Paper and Cardboard

3.4 Packaging Footprints on Quality, Shelf Life, and Safety of Food

3.5 Prolegomenon on Active and Smart Packaging Systems

3.5.1 Active Packaging

3.5.2 Intelligent Packaging System

3.6 Aseptic Packaging in Food Processing

3.7 The Paradigm in Strategies for Improvement of Food Packaging

3.7.1 Bequest of Packaging Into the Cycle of Food Chain Sustainability

3.7.2 Selection of Materials With the Objective of Recyclability

3.7.3 Escalating Protective Role of Packaging

3.7.4 How Biodegradable Polymers can Mitigate the Plight of Packaging in Food Processing

3.8 Integration of Nanotechnology to Ameliorate Food Packaging

3.9 Life Cycle Assessment (LCA)

3.10 Deciphering the Challenges for Sustainable Food Packaging

3.11 Conclusion and the Way Forward

Acknowledgement

References

4. Laws Impacting Chemicals Added to Food

4.1 Introduction

4.2 Functions of Food Additives

4.2.1 Sustain or Enhance the Shelf Life and Freshness of a Product

4.2.2 Sustain or Enhance the Nutritional Quality of a Product

4.2.3 Improve the Aesthetic Appeal and Sensory Attributes of a Product

4.3 Classification of Food Additives. 4.3.1 Classification Based on Functionality

4.3.1.1 Flavoring Agents

4.3.1.2 Enzyme Preparations

4.3.1.3 Other Additives

4.4 Classification Based on Primary and Secondary Technological Roles—Direct and Indirect Additives

4.5 Evaluating the Health Risk of Food Additives

4.6 International Regulations for the Efficacy of Food Additives

4.7 International Laws. 4.7.1 US Food and Drug Administration

4.8 Indian Regulations—Food Safety and Standards Authority of India (FSSAI), Additives Regulations (Regulation 3.1)

4.9 Safety Assessment: Redbook’s Principles of Safety Evaluation

4.10 Levels of Concern for Direct Food Additives

4.11 Threshold Regulation Exemption for Indirect Food Additives

4.12 Estimated Daily Intakes

4.13 Human Data and Clinical Studies

4.14 GRAS Substances

4.15 European Union Legislation

4.16 Categorization of Food Additives. 4.16.1 Additives Can Be Used for the Following Purposes

4.17 Safety Assessment of Food Additives

4.18 Safety Evaluation Process and Authorization

4.19 Use of Food Additives in Food Products. 4.19.1 Traditional Foods

4.19.2 Restricted Provisions

4.20 Labeling Regulations and Guidelines

4.21 Conclusion

References

5. Detection of Food Adulterants in Different Foodstuff

5.1 Introduction

5.2 Types of Adulteration

5.3 Impact of Adulteration on Health

5.4 Approaches for Adulterant Authentication in Food Materials

5.5 Physical Authentication Techniques

5.6 Application of Biochemical and Analytical Methods in Adulterant Authentication

5.6.1 Adulterant Authentication Through HPLC

5.6.2 Adulterant Authentication Through GCMS

5.6.3 Adulterant Authentication Through Spectroscopic Method

5.6.4 Adulterant Authentication Through Ambient Mass Spectroscopy Techniques

5.6.5 Adulterant Authentication Through Nuclear Magnetic Resonance Technique

5.7 Adulterant Identification by Molecular Techniques

5.7.1 Polymerase Chain Reaction–Based Techniques for Adulterant Identification

5.7.2 Application of Real-Time PCR in Adulterant Authentication

5.7.3 Isothermal Amplification Methods for Adulterant Identification

5.7.4 Sequencing and Hybridization-Based Methods in Adulterant Identification

5.8 Limitation in Use of Molecular-Based Methods for Adulterant Authentication

5.9 Conclusion

References

6. Trends of Food Adulteration in Developing Countries and Its Remedies

6.1 Introduction

6.2 Food Fraud in Developing Countries

6.2.1 Impact of Adulteration

6.3 Classification of Food Adulteration

6.3.1 Intentional Adulteration

6.4 Common Food Adulterants

6.5 Adulteration Remedy Strategies. 6.5.1 Government and Regulatory Agency Initiative

6.5.2 Loopholes in Existing Method of Eliminating Adulteration

6.5.3 Process and Product Verification

6.5.4 Higher Levels of Transparency/Traceability in Supply Chain

6.5.5 Use of Novel Technology

6.5.6 Training

6.5.7 Awareness

6.6 Conclusion

References

7. Food Adulteration and Its Impacts on Our Health/Balanced Nutrition

7.1 Introduction

7.2 Types of Adulteration

7.2.1 Intentional Adulteration

7.2.2 Incidental Adulteration

7.2.3 Other Types of Adulteration. 7.2.3.1 Natural Contamination

7.2.3.2 Metallic Contamination

7.2.3.3 Microbial Contamination

7.2.3.4 Adulteration in Organic Foods

7.2.3.5 Adulteration During Irradiation of Foods

7.2.3.6 Genetically Modified Foods

7.3 Adulteration in Foods

7.3.1 Global Food Environment

7.4 Effects of Food Adulteration. 7.4.1 Health Effects

7.4.2 Balanced Nutrition

7.5 Measures to Mitigate Food Adulteration. 7.5.1 Producer’s or Manufacturer’s End

7.5.2 Consumer’s End

7.5.3 Government and Regulatory Agencies

References

8. Natural Food Toxins as Anti-Nutritional Factors in Plants and Their Reduction Strategies

Abbreviations

8.1 Introduction

8.2 Anti-Nutritional Factor. 8.2.1 Tannins

8.2.1.1 Types

8.2.1.2 Adverse Effects

8.2.2 Saponins. 8.2.2.1 Saponins

8.2.2.2 Adverse Effects

8.2.3 Lectins and Hemagglutinin

8.2.3.1 Adverse Effects

8.2.4 Alkaloids

8.2.4.1 Adverse Health Effects

8.2.5 Oxalates

8.2.5.1 Adverse Effects

8.2.6 Cyanogenic Glycosides

8.2.6.1 Adverse Effects

8.2.7 Goitrogens

8.2.7.1 Adverse Effects

8.3 Methods to Reduce Levels of Anti-Nutritional Factors in Foods

8.3.1 Soaking

8.3.2 Fermentation

8.3.3 Germination

8.3.4 Milling

8.3.5 Extrusion

8.3.6 Heating-Autoclaving (Wet Heating) and Roasting (Dry Heating)

8.3.7 Gamma Radiation

8.3.8 Genomic Technology

8.4 Conclusion

References

9. Feeding the Future—Challenges and Limitations

9.1 Introduction

9.2 Early Life Nutrition and Healthy Future

9.2.1 Choice of Food and “Nutrition Transition”

9.3 Challenges and Opportunities in Developing the Future Food Systems

9.4 Sustainable Diet for the Future

9.5 Research Trends and Green Food Technologies

9.5.1 Green Technologies in Food Processing

9.5.2 Nanotechnology in Food Processing and Food Safety

9.5.3 CRISPR-Based Technologies

9.5.4 Future Directives

9.5.4.1 3D Food Printing and Mass Customization of Diet

9.6 Regulations and Trade

9.7 Conclusion

References

10. Alternate Food Preservation Technology

10.1 Introduction

10.2 Non-Thermal Preservation Technique

10.2.1 Packaging Technology

10.2.1.1 Challenges and Future Scope of MAP Processing

10.2.2 Ozone (O3) Treatment

10.2.2.1 Properties of O3

10.2.2.2 Principle of O3 Generation

10.2.2.3 Challenges and Future Scope of O3 Processing

10.2.3 High Hydrostatic Pressure Treatment

10.2.3.1 Principles of HPP Treatment

10.2.3.2 HPP Time

10.2.3.3 Challenges and Future Scope of HPP Treatment

10.2.4 Ultrasound Treatment

10.2.4.1 Principle of Ultrasound Treatment

10.2.4.2 Challenges and Future Scope of Ultrasound Treatment

10.2.5 Pulsed Electric Field Treatment

10.2.5.1 Principle of PEF Treatment

10.2.5.2 Challenges and Future Scope of PEF Treatment

10.2.6 Cold Plasma Treatment

10.2.6.1 Generation of CP Treatment

10.2.6.2 Challenges and Future Scope of CP

10.2.7 Oscillating Magnetic Field

10.2.7.1 Challenges and Future Scope of OMF

10.2.8 Membrane Filtration Process

10.2.8.1 Principle of the Membrane Filtration Process

10.2.8.2 Microfiltration

10.2.8.3 Ultrafiltration

10.2.8.4 Nanofiltration

10.2.8.5 Reverse Osmosis

10.2.8.6 Challenges and Future Scope of the Membrane Filtration Process

10.3 Novel-Thermal Preservation Technique

10.3.1 Ohmic Heating Treatment

10.3.1.1 Application of OH Treatment

10.3.1.2 Challenges and Future Scope of OH Treatment

10.3.2 Microwave Heating

10.3.2.1 Principle of MW Heating

10.3.2.2 Applications of MW Heating

10.3.2.3 Challenges and Future Scope of MW Heating

10.3.3 Infrared Heating (IRH)

10.3.3.1 Application of IRH

10.3.3.2 Challenges and Future Scope of IRH

10.3.4 Radio Frequency Heating

10.3.4.1 Principle of RF Heating

10.3.4.2 Factor Influencing of RF Heating

10.3.4.3 Challenges and Future Scope of RF Heating

10.4 Other Alternate Preservation Techniques. 10.4.1 Freezing

10.4.1.1 Challenges and Future Scope of Freezing

10.4.2 Dehydration

10.4.3 Frying

10.4.4 Chilling

10.4.5 Extrusion

10.4.6 Three-Dimensional (3-D) Printing

10.4.6.1 Principle of 3-D Printing

10.4.6.2 Factor Influencing 3-D Printing

10.4.7 Blanching

10.5 Hurdle Technology for Preservation of Food

10.6 Irradiation Process for Preservation of Food

10.6.1 Electron Beam

10.6.2 X-Radiation (X-Ray)

10.6.3 Gamma Rays

10.7 Food Additives for the Preservation of Food

10.7.1 Natural Additives

10.7.2 Synthetic Additives

10.7.3 Challenges and Future Scope of Additives

10.8 Conclusion

References

11. Green Solvents for Food Processing Applications

11.1 Introduction

11.2 Green Solvents

11.2.1 Water as Green Solvent

11.2.2 Subcritical Water Extraction

11.2.3 Supercritical Fluids as Green Solvent

11.2.4 Gas Expanded Liquids as Green Solvent

11.2.5 Ionic Liquids as Green Solvent

11.2.5.1 Classification of Ionic Liquids

11.2.6 Solvents Derived From Biomass as Green Solvent

11.2.7 Deep Eutectic Solvents as Green Solvents

11.3 Synthesis of NADES

11.3.1 NADES for Extraction of Phenolic Compounds

11.3.2 NADES for Extraction of Flavonoids

11.3.3 NADES for Extraction of Other Polar Compounds. 11.3.3.1 Ferulic Acid Extraction From Ligusticum Chuanxiong Hort and NADES

11.3.4 NADES for Extraction of Food Samples. 11.3.4.1 Extraction of Vanillin With NADES

11.3.4.2 Extraction of Anthocyanins With NADES

11.3.4.3 Extraction of Phenolic Compounds With NADES

11.3.5 General Considerations Using NADES as Extraction Solvents

11.4 Conclusion and Future Trends

References

12. Technological Advancement in Food Additives and Preservatives

Abbreviations

12.1 Introduction

12.2 Food Additives and Preservatives

12.2.1 Classes of Food Additives

12.2.2 Significance in Food Processing and Preservation

12.2.3 Mechanism of Action of Food Preservatives

12.3 Regulatory Aspects of Food Additives and Preservatives

12.3.1 Generally Recognized as Safe

12.3.2 FSSAI Regulations on Permissible Limits of Food Additives

12.4 Health Concerns of Conventional Food Additives

12.5 Technological Advancements in Food Additives and Preservatives. 12.5.1 Novel Food Additives

12.5.1.1 Essential Oils/Phytochemicals

12.5.1.2 Metallic Nanoparticles as Antimicrobial (Green Route)

12.6 Novel Technological Approaches for Enhanced Functionality. 12.6.1 Nanoencapsulation

12.6.1.1 Fundamentals and Techniques

12.6.1.2 Types of Encapsulating Material

12.7 Methods for Food Additives Determination. 12.7.1 Analytical Methods

12.7.1.1 Spectroscopy Techniques

12.7.1.2 Chromatographic Techniques

12.7.1.3 Electroanalytical Techniques

12.8 Future Prospects

12.9 Conclusion

References

13. Sensors for Non-Destructive Quality Evaluation of Food

13.1 Introduction

13.2 Different Types of Non-Destructive Methods

13.2.1 Mechanical Method

13.2.1.1 Mechanical Thumb Method

13.2.1.2 Sinclair IQTM–Firmness Tester (SIQ-FT)

13.2.1.3 Laser Air-Puff

13.2.2 Chemical Method. 13.2.2.1 Electronic Nose

13.2.3 Electromagnetic Method

13.2.3.1 Nuclear Magnetic Resonance (NMR)

13.2.3.2 Magnetic Resonance Imaging

13.2.4 Optical Method

13.2.4.1 NIR Spectroscopy

13.2.4.2 Image Analysis Techniques

13.2.4.2.1 Hyperspectral Imaging

13.2.4.2.2 Machine Vision

13.2.4.3 Time-Resolved Reflectance Spectrometry

13.2.5 Dynamic Method. 13.2.5.1 X-Rays

13.2.5.2 Computed Tomography

13.2.5.3 Ultrasonic

13.2.5.4 Acoustic Techniques

13.2.6 Sensor Fusion

13.3 Non-Destructive Quality Testing in Various Food Commodities. 13.3.1 Staple Foods

13.3.1.1 Sensory Aspect

13.3.1.2 Adulteration Aspects

13.3.1.3 Chemical Aspects

13.3.2 Fruits

13.3.2.1 Fruit Quality Inspection Using Electronic Nose

13.3.2.2 Fruit Quality Inspection Using UV-VIS-NIR Spectroscopy

13.3.2.3 Fruit Quality Inspection Using Ultrasound Sensing Technique

13.3.2.4 Fruit Quality Inspection Using Machine Vision Sensing Technique

13.3.2.5 Fruit Quality Inspection Using Acoustic Impulse Technique

13.3.3 Vegetables

13.3.3.1 Spectroscopic Techniques. 13.3.3.1.1 Visual Spectroscopy

13.3.3.1.2 Near-Infrared Spectroscopy

13.3.3.1.3 Microwave Dielectric Spectroscopy

13.3.3.1.4 X-Ray and Computerized Tomography

13.3.3.2 Sound Waves Techniques

13.3.3.2.1 Acoustics

13.3.3.2.2 Ultrasound

13.3.3.3 Imaging Analysis Techniques

13.3.3.3.1 Hyperspectral Imaging

13.3.3.3.2 Machine Vision

13.3.3.3.3 Magnetic Resonance Imaging

13.4 Conclusion

References

Index

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Be Aware: Try to purchase food and vegetables either from organic markets or from farmers; do not purchase food items kept in open.

We should know the identification of adulterants, so various types of methods come into progress based on anatomical/morphological characterization, color, texture, scent, and chemical testing.

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