Sustainable Solutions for Environmental Pollution, Volume 2

Sustainable Solutions for Environmental Pollution, Volume 2
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SUSTAINABLE SOLUTIONS FOR ENVIRONMENTAL POLLUTIONS This second volume in a broad, comprehensive two-volume set, “Sustainable Solutions for Environmental Pollution”, concentrates on air, water, and soil reclamation, some of the biggest challenges facing environmental engineers and scientists today. This second, new volume in the two-volume set, Sustainable Solutions for Environmental Pollution, picks up where volume one left off, covering the remediation of air, water, and soil environments. Outlining new methods and technologies for all three environmental scenarios, the authors and editor go above and beyond, introducing naturally-based techniques in addition to changes and advances in more standard methods. Written by some of the most well-known and respected experts in the field, with a prolific and expert editor, this volume takes a multidisciplinary approach, across many scientific and engineering fields, intending the two-volume set as a “one-stop shop” for all of the advances and emerging techniques and processes in this area. This groundbreaking new volume in this forward-thinking set is the most comprehensive coverage of all of these issues, laying out the latest advances and addressing the most serious current concerns in environmental pollution. Whether for the veteran engineer or the student, this is a must-have for any library. This volume: Offers new concepts and techniques for air, water, and soil environment remediation, including naturally-based solutions Provides a comprehensive coverage of removing heavy chemicals from the environment Offers new, emerging techniques for pollution prevention Is filled with workable examples and designs that are helpful for practical applications Is useful as a textbook for researchers, students, and faculty for understanding new ideas in this rapidly emerging field AUDIENCE: Petroleum, chemical, process, and environmental engineers, other scientists and engineers working in the area of environmental pollution, and students at the university and graduate level studying these areas.

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Группа авторов. Sustainable Solutions for Environmental Pollution, Volume 2

Table of Contents

List of Tables

List of Illustrations

Guide

Pages

Sustainable Solutions for Environmental Pollution

Air, Water and Soil Reclamation

Preface

1. Natural-Based Solutions for Bioremediation in Water Environment

1.1 Introduction

1.2 Basic Principles. 1.2.1 Bioremediation

1.2.2 Self-Purification

1.2.2.1 Redox Processes

1.2.2.2 Photo-Degradation

1.3 Aquatic Bioremediation Structures

1.4 Constructed Porous Ramps

1.5 Bank Filtration for Water Treatment

1.6 Constructed Wetlands (CWs)

1.6.1 Water Flow

1.6.2 Aquatic Vegetation

1.7 Phytoremediation and Constructed Wetlands

1.7.1 Phytoremediation Techniques

1.7.2 Aquatic Phytobiome

1.7.3 Various Aquatic Plants Used

1.7.4 Emergent Aquatic Plants

1.7.5 Floating Leaved Aquatic Plants

1.7.6 Floating Aquatic Plants

1.7.7 Submerged Aquatic Plants

1.7.8 Mixture of Macrophytes and Microalgae

1.8 Phycoremediation

1.8.1 Carbon and Nutrients (N and P) Removal

1.8.2 Micropollutant Removal

1.9 Phytoremediation

1.9.1 Carbon and Nutrients (N and P) Removal

1.9.2 Metals Removal

1.9.3 Organic Micropollutant Removal

1.10 Improving Bioremediation Systems. 1.10.1 Introduction

1.10.2 Floating Treatment Constructed Wetlands

1.10.3 Electro-Bioremediation

1.10.4 Bench Tests

1.10.5 Pilot Tests

1.10.6 Field Implementations

1.10.7 Maintenance of Aquatic Bioremediation Systems

1.10.8 Biomass Management

1.10.9 Sediment Management

1.11 Animal Biodiversity

1.11.1 Biodiversity Management

1.12 Nuisances. 1.12.1 Greenhouse Gases (GHG)

1.12.2 Noxious Gases

1.12.3 Mosquitoes

1.12.4 Burrowing Animals

1.12.5 Algal Blooms

1.13 Wetland Monitoring. 1.13.1 Monitoring Large-Scale CWs

1.13.2 Vegetation Monitoring

1.14 Wetland Modeling

1.14.1 Aquatic Plant Development Models

1.14.1.1 Submerged Aquatic Plants

1.14.1.2 Duckweed

1.14.2 Micropollutants Sorption

1.14.3 Organic Micropollutant Photolysis

1.14.4 Global CW Modeling

1.15 Social Acceptance

1.15.1 Yzeron Watershed Case Study (France)

1.15.2 South Africa Case Study

1.16 Ecohydrology, an Integrative NBS Implementation

1.16.1 Three Nested Logics for Innovative NBS Implementation

1.16.2 Ecohydrology on Small Watersheds

1.17 Conclusion

Acknowledgement

References

2. Removal of Heavy Metals From the Environment by Phytoremediation and Microbial Remediation

2.1 Introduction

2.2 Linking Heavy Metals Toxicity With Their Discharge and Removal From the Environmental Compartments

2.3 Bio-Alternative Approaches Used for Heavy Metals Removal and/or Recovery From the Environment. 2.3.1 Biosorption and Bioaccumulation

2.3.2 Phytoremediation

2.3.2.1 Limitation and Challenges of Phytoremediation

2.4 Interactions of Heavy Metals With Biological Systems and Toxicity Threats

2.4.1 Some Expressions of Metal Toxicity in Living Organisms

2.4.2 Heavy Metals, Free Radicals, Antioxidants and Oxidative Stress

2.4.3 Some Effects of Humans’ Exposure to Heavy Metals Toxicity

2.4.4 Effects of Plants Exposure to Heavy Metals Toxicity

2.4.5 Effects of Microbes Exposure to Heavy Metals Toxicity

2.5 Synergistic Use of Plants and Bacteria for Cleaning Up the Environment Polluted With Heavy Metals

2.6 Conclusions

Acknowledgments

References

Website

3. Bioremediation as a Sustainable Solution for Environmental Contamination by Petroleum Hydrocarbons

3.1 Introduction

3.2 Principles of Bioremediation

3.3 Bioremediation and Biodegradation

3.3.1 Natural Bioremediation Mechanism

3.3.2 Traditional Bioremediation Methods

3.3.3 Enhanced Bioremediation Treatment

3.4 Mechanism of Biodegradation

3.4.1 Chemical Reactions

3.5 Bioremediation of Land Ecosystems

3.5.1 Soil Evaluation

3.5.1.1 Chemical Properties

3.5.1.2 Biological Properties

3.5.1.3 Effect of Temperature

3.5.1.4 Effect of pH

3.5.1.5 Effect of Salinity

3.6 Bioremediation of Water Ecosystems

3.6.1 Biodegradation

3.6.2 Bioremediation

3.6.2.1 Temperature

3.6.2.2 Effect of Oxygen

3.6.2.3 Nutrients

3.6.2.4 Effect of Petroleum Characteristics

3.6.2.5 Effect of Prior Exposure

3.6.2.6 Effect of Dispersants

3.6.2.7 Effect of Flowing Water

3.6.2.8 Effect of Deep-Sea Environments

3.7 Challenges and Opportunities

References

4. Pollution Protection Using Novel Membrane Catalytic Reactors

Nomenclatures

Greek Letters

Abbreviations

4.1 Introduction

4.2 Autothermal Systems. 4.2.1 Dehydrogenation (Dehydro) and Hydrogenation (Hydro) Reactions

4.2.2 Dehydrogenation (Dehydro) Definition

4.2.3 Dehydro Reaction and the Generated Hydrogen Consumption

4.2.4 Endothermic (Endo) Dehydro Coupled With Exothermic (Exo) Reactions

4.3 The Thermal Coupling and the Autothermal (Auto) Reactors

4.3.1 Recuperative Coupling Reactor

4.3.1.1 Recuperative Coupling Reactors Design

4.3.1.2 Examples of Recuperative Reactions Coupling

4.3.2 Regenerative Coupling Reactor

4.3.3 Direct Coupling Reactor

4.4 The Membrane Reactor

4.5 Development Fischer-Tropsch Synthesis

4.5.1 Gas-to-Liquid Fuel

4.5.2 High-Temperature Fisher-Tropsch (HTFT) Processes

4.6 HTFT Reactor Type and Developments

4.6.1 Fixed-Bed Reactor

4.6.2 Fluidized-Bed Reactor

4.6.2.1 The Fluidization Principle

4.6.2.2 Classification of Fluidized Reactor

4.6.3 Bubble Column Reactors

4.6.4 Dual-Type Membrane Reactor

4.7 Membrane Reactors Classification

4.8 Rate Expressions

4.8.1 Modeling of the Dehydro Process in Membrane Reactor

4.9 Industrial Applications

4.9.1 Heterogeneous Catalytic Gas-Phase Reactions. 4.9.1.1 Catalytic Cracking

4.9.1.2 Synthesis of Acrylonitrile

4.9.1.3 Fischer-Tropsch Synthesis

4.9.1.4 Other Processes

4.9.2 Homogeneous Gas-Phase Reactions

4.9.3 Gas-Solid Reactions

4.9.4 Applications in Biotechnology

4.10 Catalytic Membrane Reactors Coupling Dehydro of EB to S With Hydro NB to A as a Case Study

4.10.1 Introduction

4.10.2 Reactor Configuration

4.10.3 Reactor Model

4.11 Case Study of Use the Membranes in Fischer-Tropsch Reactors. 4.11.1 Introduction

4.11.2 Use of Semi-Permeable Membranes in FTS

4.11.3 Water-Selective Semi-Permeable Membranes for Water Removal

4.11.4 The Use of Non-Selective Porous Membranes in FTS. 4.11.4.1 Concept of the Plug-Through Contactor Membranes Using the Permeable Composite Monolith (PCM)

4.11.4.2 Preparation of PCM, the Possibility to Control the Porous Structure Parameters at the Preparation Stage. 4.11.4.2.1 Preparation Procedure

4.11.4.2.2 Characterization of PCM Samples

4.11.5 Fischer-Tropsch Synthesis in a PCM Membrane Reactor. 4.11.5.1 Dry Mode of Operation

4.11.5.2 Flooded Mode of Operation, the Effect of the Pore Structure and Membrane Geometry on the Magnitude of the Mass-Transfer Constrains

4.12 Biofuel and Sustainability

4.13 Conclusions

References

5. Removal of Microbial Contaminants From Polluted Water Using Combined Biosand Filters Techniques

5.1 Introduction

5.2 Slow Sand Filtration

5.2.1 Sand Filters and Removal of Pollutants

5.2.1.1 Effect of Sand Grain Size on Removal of Pollutants

5.2.1.2 Effect of Sand Bed Depth on Removal of Pollutants

5.2.1.3 Effect of Retention Time on Removal of Pollutants

5.3 Wetlands

5.3.1 Natural Wetlands

5.3.2 Constructed Wetlands

5.3.2.1 Types of Macrophytes in Constructed Wetlands

5.3.2.2 Constructed Wetlands and Removal of Pollutants

5.3.2.3 Combined Macrophyte Species in Constructed Wetlands

5.3.2.4 Advantages of Constructed Wetlands

5.4 Combination of Sand Filters With Constructed Wetlands Systems

5.5 Conclusions

References

6. Biosurfactants: Promising Biomolecules for Environmental Cleanup

6.1 Introduction

6.2 Biosurfactants Types

6.3 Biosurfactants Mechanism of Remediation

6.4 Bioremediation of Petro-Hydrocarbon Contaminants

6.5 Microbial Enhance Oil Recovery (MEOR)

6.5.1 Mechanism of MEOR

6.6 Biosurfactants and Agro-Ecosystem Pollutants

6.7 Heavy Metals Removal

6.8 Biosurfactants for Sustainability

6.8.1 Low-Cost Substrates

6.9 Production Processes

6.10 Concluding Remarks

6.11 Future Aspects

References

7. Metal Hyperaccumulation in Plants: Phytotechnologies

7.1 Introduction

7.2 Phytotechnologies and Terminologies. 7.2.1 Phytoaccumulation/Phytoextraction

7.2.2 Rhizofiltration

7.2.3 Phytovolatilization

7.2.4 Rhizodegradation

7.2.5 Phytodegradation/Phytotransformation

7.2.6 Phytostabilization

7.3 Biological Mechanisms

7.4 Present Gaps and Prospects

7.5 Conclusion

Acknowledgements

References

8. Microbial Remediation Approaches for PAH Degradation

8.1 Introduction

8.2 Biogeochemical Properties and Sources of PAH

8.3 Fate of PAH

8.4 PAH: Soil and Air Pollution

8.5 Harmful Effects of PAH

8.6 Microbe Assisted Biodegradation

8.6.1 Bacterial Assisted PAH Degradation

8.6.2 Mechanism

8.6.3 Mycoremediation

8.6.3.1 Mechanism

8.6.4 Algae Assisted PAH Degradation

8.7 Genes and Enzymes Involved in Microbial Degradation

8.8 Factors Affecting Microbial Biodegradation

8.9 Bioremediation and Genetic Engineering

8.10 Conclusion and Future Prospects

References

9. Biomorphic Synthesis of Nanosized Zinc Oxide for Water Purification

9.1 Introduction

9.2 Properties of ZnO NPs

9.2.1 Structure and Lattice Parameters of ZnO

9.2.2 Mechanical Properties

9.2.3 Electronic Properties

9.2.4 Optical Properties

9.3 Protocol for the Biosynthesis of ZnO NPs. 9.3.1 Natural Extract–Based ZnO Nanostructure

9.3.2 Microorganism-Based ZnO Nanostructures

9.3.3 Solvent System-Based “Green” Synthesis

9.4 Factors Affecting the Synthesis of ZnO Nanoparticles

9.4.1 pH

9.4.2 Temperature

9.4.3 Influence of the Reactant

9.4.4 Effect of Metabolites

9.5 Applications of Biologically Synthesized NPs. 9.5.1 Antibacterial Effect of ZnO-NPs

9.5.2 Photocatalytic Activity

9.5.3 ZnO NPs and ROS Production

9.6 Mechanism of Biogenic Synthesis of ZnO NPs

9.7 Cytotoxicity of Nanoparticles

9.8 Conclusions and Future Outlook

References

10. Pollution Dynamics of Urban Catchments

10.1 Introduction. 10.1.1 Environmental Protection for Sustainable Development

10.1.2 Sustainability in Industrial Wastewater Treatment

10.1.3 Sustainability in Organic Solid Waste Management

10.2 Sustainability in Domestic Wastewater Treatment. 10.2.1 Centralized Sanitation and Sustainability

10.2.2 Decentralized Sanitation and Sustainability

10.2.3 Merits of Centralized Over Decentralized Sanitation

10.3 Source Area Pollutant Generation Processes

10.3.1 Automotive Activities

10.3.2 Atmospheric Depositions

10.4 Polluting Activities. 10.4.1 Industrial

10.5 Characterization of Urban Pollutants. 10.5.1 Air Pollution Measurements Used in Estimating Annual Average Concentrations

10.5.2 Comparative Quantification of Health Risks

10.6 The Fate and Transport of Urban Pollutants

10.7 Spatial Distribution of Urbans Pollutants. 10.7.1 Tools for Monitoring the Spatial Distribution. 10.7.1.1 Geographic Information System and Remote Sensing

10.7.1.2 Shetran Modeling

10.7.1.2.1 Catchment Flow Modeling

10.7.1.2.2 Structure of SHETRAN

10.8 Case Study: City of Harare

10.9 Conclusions, Challenges, Opportunities, and/or Future Aspects

References

11. Bioupgrading of Crude Oil and Crude Oil Fractions

11.1 Introduction

11.2 Microbial Enhanced Oil Recovery

11.3 Biotransformation of Heavy Crude Oil

11.4 Biorefining of Crude Oil

11.4.1 Biodesulfurization

11.4.2 Biodenitrogenation

11.4.3 Biodemetallization

11.5 The Future of Biotechnology in the Refinery

References

12. Recyclable Porous Adsorbents as Environmentally Approach for Greenhouse Gas Capture

12.1 Introduction

12.2 Classification of Porous Materials

12.3 Recyclability Routes of Biomass to Porous Carbons

12.4 Activation Routes Processes. 12.4.1 Physical Activation

12.4.2 Chemical Activation

12.5 CO2 Capture in Recyclable Porous Carbon Materials

12.6 CO2 Capture Mechanism in Porous Carbons

12.7 Prospects and Outlooks

12.8 Conclusion

Acknowledgements

References

About the Editor

Index

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Daghio, M., Aulenta, F., Vaiopoulou, E., Franzetti, A., Arends, J.B.A., Sherry, A., Suarez-Suarez, A., Head, I.M., Bestetti, G., Rabaey, K., Electrobioremediation of oil spills. Water Res., 114, 351–370, 2017, doi: 10.1016/j.watres.2017.02.030.

Daghio, M., Vaiopoulou, E., Patil, S.A., Suarez-Suarez, A., Head, I.M., Franzetti, A., Rabaey, K., Anodes stimulate anaerobic toluene degradation via sulfur cycling in marine sediments. Appl. Environ. Microbiol., 82, 1, 297–307, 2016, doi: 10.1128/aem.02250-15.

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