Welding Metallurgy

Welding Metallurgy
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Discover the extraordinary progress that welding metallurgy has experienced over the last two decades Welding Metallurgy, 3rd Edition is the only complete compendium of recent, and not-so-recent, developments in the science and practice of welding metallurgy. Written by Dr. Sindo Kou, this edition covers solid-state welding as well as fusion welding, which now also includes resistance spot welding. It restructures and expands sections on Fusion Zones and Heat-Affected Zones. The former now includes entirely new chapters on microsegregation, macrosegregation, ductility-dip cracking, and alloys resistant to creep, wear and corrosion, as well as a new section on ternary-alloy solidification. The latter now includes metallurgy of solid-state welding. Partially Melted Zones are expanded to include liquation and cracking in friction stir welding and resistance spot welding. New chapters on topics of high current interest are added, including additive manufacturing, dissimilar-metal joining, magnesium alloys, and high-entropy alloys and metal-matrix nanocomposites.  Dr. Kou provides the reader with hundreds of citations to papers and articles that will further enhance the reader’s knowledge of this voluminous topic. Undergraduate students, graduate students, researchers and mechanical engineers will all benefit spectacularly from this comprehensive resource. The new edition includes new theories/methods of Kou and coworkers regarding: · Predicting the effect of filler metals on liquation cracking · An index and analytical equations for predicting susceptibility to solidification cracking · A test for susceptibility to solidification cracking and filler-metal effect · Liquid-metal quenching during welding · Mechanisms of resistance of stainless steels to solidification cracking and ductility-dip cracking · Mechanisms of macrosegregation · Mechanisms of spatter of aluminum and magnesium filler metals, · Liquation and cracking in dissimilar-metal friction stir welding, · Flow-induced deformation and oscillation of weld-pool surface and ripple formation · Multicomponent/multiphase diffusion bonding Dr. Kou’s Welding Metallurgy has been used the world over as an indispensable resource for students, researchers, and engineers alike. This new Third Edition is no exception.

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Sindo Kou. Welding Metallurgy

Table of Contents

List of Tables

List of Illustrations

Guide

Pages

Welding Metallurgy

Copyright

Preface to Third Edition

1 Welding Processes

1.1 Overview. 1.1.1 Fusion Welding Processes

1.1.1.1 Power Density of Heat Source

1.1.1.2 Welding Processes and Materials

1.1.1.3 Types of Joints and Welding Positions

1.1.2 Solid‐State Welding Processes

1.2 Gas Welding. 1.2.1 The Process

1.2.2 Three Types of Flames. 1.2.2.1 Neutral Flame

1.2.2.2 Reducing Flame

1.2.2.3 Oxidizing Flame

1.2.3 Advantages and Disadvantages

1.3 Arc Welding. 1.3.1 Shielded Metal Arc Welding

1.3.1.1 Functions of Electrode Covering

1.3.1.2 Advantages and Disadvantages

1.3.2 Gas–Tungsten Arc Welding. 1.3.2.1 The Process

1.3.2.2 Polarity

1.3.2.3 Electrodes

1.3.2.4 Shielding Gases

1.3.2.5 Advantages and Disadvantages

1.3.3 Plasma Arc Welding. 1.3.3.1 The Process

1.3.3.2 Arc Initiation

1.3.3.3 Keyholing

1.3.3.4 Advantages and Disadvantages

1.3.4 Gas–Metal Arc Welding. 1.3.4.1 The Process

1.3.4.2 Shielding Gases

1.3.4.3 Modes of Metal Transfer

1.3.4.4 Advantages and Disadvantages

1.3.5 Flux‐Cored Arc Welding. 1.3.5.1 The Process

1.3.6 Submerged Arc Welding. 1.3.6.1 The Process

1.3.6.2 Advantages and Disadvantages

1.3.7 Electroslag Welding. 1.3.7.1 The Process

1.3.7.2 Advantages and Disadvantages

1.4 High‐Energy‐Beam Welding. 1.4.1 Electron Beam Welding. 1.4.1.1 The Process

1.4.1.2 Advantages and Disadvantages

1.4.2 Laser Beam Welding. 1.4.2.1 The Process

1.4.2.2 Reflectivity

1.4.2.3 Shielding Gas

1.4.2.4 Laser‐Assisted Arc Welding

1.4.2.5 Advantages and Disadvantages

1.5 Resistance Spot Welding

1.6 Solid‐State Welding. 1.6.1 Friction Stir Welding

1.6.2 Friction Welding

1.6.3 Explosion and Magnetic‐Pulse Welding

1.6.4 Diffusion Welding

Examples

Answer:

Answer

References

Further Reading

Problems

2 Heat Flow in Welding

2.1 Heat Source. 2.1.1 Heat Source Efficiency

2.1.1.1 Definition

2.1.1.2 Measurements

2.1.1.3 Heat Source Efficiencies in Various Welding Processes

2.1.2 Melting Efficiency

2.1.3 Power Density Distribution of Heat Source. 2.1.3.1 Effect of Electrode Tip Angle

2.1.3.2 Measurements

2.2 Heat Flow During Welding. 2.2.1 Response of Material to Welding Heat Source

2.2.2 Rosenthal's Equations

2.2.2.1 Rosenthal's Two‐Dimensional Equation

2.2.2.2 Rosenthal's Three‐Dimensional Equation

2.2.2.3 Step‐by‐Step Application of Rosenthal's Equations

2.2.3 Adams' Equations

2.3 Effect of Welding Conditions

2.4 Computer Simulation

2.5 Weld Thermal Simulator. 2.5.1 The Equipment

2.5.2 Applications

2.5.3 Limitations

Examples

Answer:

Answer:

Answer:

References

Further Reading

Problems

3 Fluid Flow in Welding

3.1 Fluid Flow in Arcs

3.1.1 Sharp Electrode

3.1.2 Flat‐End Electrode

3.2 Effect of Metal Vapor on Arcs. 3.2.1 Gas−Tungsten Arc Welding

3.2.2 Gas−Metal Arc Welding

3.3 Arc Power‐ and Current‐Density Distributions

3.4 Fluid Flow in Weld Pools. 3.4.1 Driving Forces for Fluid Flow

3.4.2 Heiple's Theory for Weld Pool Convection

3.4.3 Physical Simulation of Fluid Flow and Weld Penetration

3.4.4 Computer Simulation of Fluid Flow and Weld Penetration

3.5 Flow Oscillation and Ripple Formation

3.6 Active Flux GTAW

3.7 Resistance Spot Welding

Examples

Answer

Answer

References

Further Reading

Problems

4 Mass and Filler–Metal Transfer

4.1 Convective Mass Transfer in Weld Pools

4.2 Evaporation of Volatile Solutes

4.3 Filler‐Metal Drop Explosion and Spatter

4.4 Spatter in GMAW of Magnesium

4.5 Diffusion Bonding

Examples

Answer:

Answer:

References

Problems

5 Chemical Reactions in Welding

5.1 Overview. 5.1.1 Effect of Nitrogen, Oxygen, and Hydrogen

5.1.2 Protection Against Air

5.1.3 Evaluation of Weld Metal Properties

5.2 Gas–Metal Reactions

5.2.1 Thermodynamics of Reactions

5.2.2 Hydrogen. 5.2.2.1 Magnesium

5.2.2.2 Aluminum

5.2.2.3 Titanium

5.2.2.4 Copper

5.2.2.5 Steels

Sources of Hydrogen

Measuring Hydrogen Content

Hydrogen Reduction Methods

5.2.3 Nitrogen

5.2.3.1 Steel

Effect of Nitrogen

Protection Against Nitrogen

5.2.3.2 Titanium

5.2.4 Oxygen. 5.2.4.1 Magnesium

5.2.4.2 Aluminum

5.2.4.3 Titanium

5.2.4.4 Steel. Sources of Oxygen

Effect of Oxygen

5.3 Slag–Metal Reactions. 5.3.1 Thermochemical Reactions

5.3.1.1 Decomposition of Flux

5.3.1.2 Removal of S and P from Liquid Steel

5.3.2 Effect of Flux on Weld Metal Oxygen

5.3.3 Types of Fluxes, Basicity Index, and Weld Metal Properties

5.3.4 Basicity Index

5.3.5 Electrochemical Reactions

Examples

Answer:

Answer:

References

Further Reading

Problems

6 Residual Stresses, Distortion, and Fatigue

6.1 Residual Stresses

6.1.1 Development of Residual Stresses. 6.1.1.1 Stresses Induced By Welding

6.1.1.2 Welding

6.1.2 Analysis of Residual Stresses

6.2 Distortion. 6.2.1 Cause

6.2.2 Remedies

6.3 Fatigue. 6.3.1 Mechanism

6.3.2 Fractography

6.3.3 S–N Curves

6.3.4 Effect of Joint Geometry

6.3.5 Effect of Stress Raisers

6.3.6 Effect of Corrosion

6.3.7 Remedies. 6.3.7.1 Shot Peening

6.3.7.2 Reducing Stress Raisers

6.3.7.3 Laser Shock Peening

6.3.7.4 Use of Low–Transformation–Temperature Fillers

Examples

Answer:

Answer:

References

Further Reading

Problems

7 Introduction to Solidification

7.1 Solute Redistribution During Solidification. 7.1.1 Directional Solidification

7.1.2 Equilibrium Segregation Coefficient k

7.1.3 Four Cases of Solute Redistribution

7.2 Constitutional Supercooling

7.3 Solidification Modes

7.4 Microsegregation Caused by Solute Redistribution

7.5 Secondary Dendrite Arm Spacing

7.6 Effect of Dendrite Tip Undercooling

7.7 Effect of Growth Rate

7.8 Solidification of Ternary Alloys. 7.8.1 Liquidus Projection

7.8.2 Solidification Path

7.8.3 Ternary Magnesium Alloys

7.8.4 Ternary Fe‐Cr‐Ni Alloys

7.8.4.1 Fe‐Cr‐Ni Phase Diagram

7.8.4.2 Solidification Paths

7.8.4.3 Microstructure. Primary Austenite

Primary Ferrite

Examples

Answer

Answer

References

Further Reading

Problems

8 Solidification Modes

8.1 Solidification Modes

8.1.1 Temperature Gradient and Growth Rate

8.1.2 Variations in Solidification Mode Across Weld

8.2 Dendrite Spacing and Cell Spacing

8.3 Effect of Welding Parameters. 8.3.1 Solidification Mode

8.3.2 Dendrite and Cell Spacing

8.4 Refining Microstructure Within Grains

8.4.1 Arc Oscillation

8.4.2 Arc Pulsation

Examples

Answer

Answer

References

Further Reading

Problems

9 Nucleation and Growth of Grains

9.1 Epitaxial Growth at the Fusion Line

9.2 Nonepitaxial Growth at the Fusion Line. 9.2.1 Mismatching Crystal Structures

9.2.2 Nondendritic Equiaxed Grains

9.3 Growth of Columnar Grains

9.4 Effect of Welding Parameters on Columnar Grains

9.5 Control of Columnar Grains

9.6 Nucleation Mechanisms of Equiaxed Grains. 9.6.1 Microstructure Around Pool Boundary

9.6.2 Dendrite Fragmentation

9.6.3 Grain Detachment

9.6.4 Heterogeneous Nucleation

9.6.5 Effect of Welding Parameters on Heterogeneous Nucleation

9.6.6 Surface Nucleation

9.7 Grain Refining

9.7.1 Inoculation

9.7.2 Weld Pool Stirring. 9.7.2.1 Magnetic Weld Pool Stirring

9.7.2.2 Ultrasonic Weld Pool Stirring

9.7.3 Arc Pulsation

9.7.4 Arc Oscillation

9.8 Identifying Grain‐Refining Mechanisms. 9.8.1 Overlap Welding Procedure

9.8.2 Identifying the Grain‐Refining Mechanism

9.8.3 Effect of Arc Oscillation on Dendrite Fragmentation

9.8.4 Effect of Arc Oscillation on Constitutional Supercooling

9.8.5 Effect of Composition on Grain Refining by Arc Oscillation

9.9 Grain‐Boundary Migration

Examples

Answer:

Answer:

References

Further Reading

Problems

10 Microsegregation

10.1 Microsegregation in Welds

10.2 Effect of Travel Speed on Microsegregation

10.3 Effect of Primary Solidification Phase on Microsegregation

10.4 Effect of Maximum Solid Solubility on Microsegregation

Examples

Answer:

Answer:

References

Further Reading

Problems

11 Macrosegregation

11.1 Macrosegregation in the Fusion Zone

11.2 Quick Freezing of One Liquid Metal in Another

11.3 Macrosegregation in Dissimilar‐Filler Welding. 11.3.1 Bulk Weld‐Metal Composition

11.3.2 Mechanism I

11.3.3 Mechanism II

11.4 Macrosegregation in Dissimilar‐Metal Welding. 11.4.1 Mechanism I

11.4.2 Mechanism II

11.5 Reduction of Macrosegregation

11.6 Macrosegregation in Multiple‐Pass Welds

Answer:

References

Further Reading

Problems

12 Some Alloy‐Specific Microstructures and Properties

12.1 Austenitic Stainless Steels. 12.1.1 Microstructure Evolution in Stainless Steels

12.1.2 Mechanisms of Ferrite Formation

12.1.3 Prediction of Ferrite Content

12.1.4 Effect of Cooling Rate. 12.1.4.1 Changes in Solidification Mode

12.1.4.2 Dendrite Tip Undercooling

12.2 Low‐Carbon, Low‐Alloy Steels. 12.2.1 Microstructure Development

12.2.2 Factors Affecting Microstructure

12.2.3 Weld Metal Toughness

12.3 Ultralow Carbon Bainitic Steels

12.4 Creep‐Resistant Steels

12.5 Hardfacing of Steels

References

Further Reading

Problems

13 Solidification Cracking

13.1 Characteristics of Solidification Cracking

13.2 Theories of Solidification Cracking

13.2.1 Criterion for Cracking Proposed by Kou

13.2.2 Index for Crack Susceptibility Proposed by Kou

13.2.3 Previous Theories

13.3 Binary Alloys and Analytical Equations

13.4 Solidification Cracking Tests

13.4.1 Varestraint Test

13.4.2 Controlled Tensile Weldability Test

13.4.3 Transverse‐Motion Weldability Test

13.4.4 Circular‐Patch Test

13.4.5 Houldcroft Test

13.4.6 Cast‐Pin Test

13.4.7 Ring‐Casting Test

13.4.8 Other Tests

13.5 Solidification Cracking of Stainless Steels. 13.5.1 Primary Solidification Phase

13.5.2 Mechanism of Crack Resistance

13.6 Factors Affecting Solidification Cracking. 13.6.1 Primary Solidification Phase

13.6.2 Grain Size

13.6.3 Solidification Temperature Range

13.6.4 Back Diffusion

13.6.5 Dihedral Angle

13.6.6 Grain‐Boundary Angle

13.6.7 Degree of Restraint

13.7 Reducing Solidification Cracking. 13.7.1 Control of Weld Metal Composition

13.7.2 Control of Weld Microstructure

13.7.3 Control of Welding Conditions

13.7.4 Control of Weld Shape

Examples

References

Further Reading

Problems

14 Ductility‐Dip Cracking

14.1 Characteristics of Ductility‐Dip Cracking

14.2 Theories of Ductility‐Dip Cracking

14.3 Test Methods

14.4 Ductility‐Dip Cracking of Ni‐Base Alloys. 14.4.1 Grain‐Boundary Sliding

14.4.2 Grain‐Boundary Misorientation

14.4.3 Grain‐Boundary Tortuosity and Precipitates

14.4.4 Grain Size

14.4.5 Factors Affecting Ductility‐Dip Cracking

14.5 Ductility‐Dip Cracking of Stainless Steels

Examples

References

Further Reading

Problems

15 Liquation in the Partially Melted Zone

15.1 Formation of the Partially Melted Zone

15.2 Liquation Mechanisms

15.2.1 Mechanism I: Alloy with Co>CSM

15.2.2 Mechanism II: Alloy with Co<CSM and no AxBy or Eutectic

15.2.3 Mechanism III: Alloy with Co<CSM and AxBy or Eutectic

15.2.4 Additional Mechanisms of Liquation

15.3 Directional Solidification of Liquated Material

15.4 Grain‐Boundary Segregation

15.5 Loss of Strength and Ductility

15.6 Hydrogen Cracking

15.7 Effect of Heat Input

15.8 Effect of Arc Oscillation

Examples

References

Problems

16 Liquation Cracking

16.1 Liquation Cracking in Arc Welding

16.1.1 Crack Susceptibility Tests

16.1.1.1 Varestraint Testing

16.1.1.2 Circular‐Patch Testing

16.1.1.3 Hot Ductility Testing

16.1.2 Mechanism of Liquation Cracking

16.1.3 Predicting Effect of Filler Metal on Crack Susceptibility

16.1.4 Factors Affecting Liquation Cracking. 16.1.4.1 Filler Metal

16.1.4.2 Heat Source

16.1.4.3 Degree of Restraint

16.1.4.4 Base Metal

16.2 Liquation Cracking in Resistance Spot Welding

16.3 Liquation Cracking in Friction Stir Welding

16.4 Liquation Cracking in Dissimilar‐Metal FSW

Examples

References

Problems

17 Introduction to Solid‐State Transformations

17.1 Work‐Hardened Materials

17.2 Heat‐Treatable Al Alloys

17.3 Heat‐Treatable Ni‐Base Alloys

17.4 Steels. 17.4.1 Fe‐C Phase Diagram and CCT Diagrams

17.4.2 Carbon Steels

17.4.3 Dual‐Phase Steels

17.5 Stainless Steels. 17.5.1 Types of Stainless Steels

17.5.2 Sensitization of Unstabilized Grades

17.5.3 Sensitization of Stabilized Grades

17.5.4 σ‐Phase Embrittlement

Examples

References

Problems

18 Heat‐Affected‐Zone Degradation of Mechanical Properties

18.1 Grain Coarsening

18.2 Recrystallization and Grain Growth

18.3 Overaging in Al Alloys. 18.3.1 Al‐Cu‐Mg (2000‐Series) Alloys. 18.3.1.1 Microstructure and Strength

18.3.1.2 Effect of Welding Parameters or Process

18.3.2 Al‐Mg‐Si (6000‐Series) Alloys. 18.3.2.1 Microstructure and Strength

18.3.2.2 Effect of Welding Processes and Parameters

18.3.3 Al‐Zn‐Mg (7000‐Series) Alloys

18.4 Dissolution of Precipitates in Ni‐Base Alloys

18.5 Martensite Tempering in Dual‐Phase Steels

Examples

References

Further Reading

Problems

19 Heat‐Affected‐Zone Cracking

19.1 Hydrogen Cracking in Steels

19.1.1 Cause

19.1.2 Appearance

19.1.3 Susceptibility Tests

19.1.4 Remedies. 19.1.4.1 Preheating

19.1.4.2 Postweld Heating

19.1.4.3 Bead Tempering

19.1.4.4 Use of Low‐H Processes and Consumables

19.1.4.5 Use of Lower‐Strength Filler Metals

19.1.4.6 Use of Austenitic‐Stainless‐Steel Filler Metals

19.2 Stress‐Relief Cracking in Steels

19.3 Lamellar Tearing in Steels

19.4 Type‐IV Cracking in Grade 91 Steel

19.5 Strain‐Age Cracking in Ni‐Base Alloys

Examples

References

Further Reading

Problems

20 Heat‐Affected‐Zone Corrosion

20.1 Weld Decay of Stainless Steels

20.2 Weld Decay of Ni‐Base Alloys

20.3 Knife‐Line Attack of Stainless Steels

20.4 Sensitization of Ferritic Stainless‐Steel Welds

20.5 Stress Corrosion Cracking of Austenitic Stainless Steels

20.6 Corrosion Fatigue of Al Welds

Examples

References

Further Reading

Problems

21 Additive Manufacturing

21.1 Heat and Fluid Flow

21.2 Residual Stress and Distortion

21.3 Lack of Fusion and Gas Porosity

21.4 Grain Structure

21.5 Solidification Cracking

21.6 Liquation Cracking

21.7 Graded Transition Joints

21.8 Further Discussions

Examples

Example 21.1

Answer

Example 21.2

Answer

References

Further Reading

Problems

22 Dissimilar‐Metal Joining

22.1 Introduction

22.2 Arc and Laser Joining

22.2.1 Al‐to‐Steel Arc Brazing

22.2.1.1 Effect of Lap Joint Gap

22.2.1.2 Effect of Heat Input

22.2.1.3 Effect of Ultrasonic Vibration

22.2.1.4 Effect of Preheating

22.2.1.5 Effect of Postweld Heat Treatment

22.2.1.6 Butt Joint

22.2.2 Al‐to‐Steel Laser Brazing

22.2.3 Al‐to‐Steel Laser Welding

22.2.4 Mg‐to‐Steel Brazing

22.2.5 Al‐to‐Mg Welding

22.3 Resistance Spot Welding. 22.3.1 Al‐to‐Steel RSW

22.3.2 Mg‐to‐Steel RSW

22.3.3 Al‐to‐Mg RSW

22.4 Friction Stir Welding

22.4.1 Al‐to‐Cu FSSW

22.4.2 FSSW of Al to Galvanized Steel

22.4.3 Effect of Coating on Al‐to‐Steel FSSW

22.5 Other Solid‐State Welding Processes. 22.5.1 Friction Welding

22.5.2 Explosion Welding

22.5.3 Magnetic Pulse Welding

Examples

Answer

Answer

Answer

References

Further Reading

Problems

23 Welding of Magnesium Alloys

23.1 Spatter. 23.1.1 Spatter in Mg GMAW

23.1.2 Mechanism of Spatter

23.1.3 Elimination of Spatter

23.1.4 Irregular Weld Shape and Its Elimination

23.2 Porosity. 23.2.1 Porosity in Mg GMAW

23.2.2 Mechanisms of Porosity Formation and Elimination

23.2.3 Comparing Porosity in Al and Mg Welds

23.3 Internal Oxide Films. 23.3.1 Mechanism

23.3.2 Remedies

23.4 High Crowns

23.4.1 Mechanism of High‐Crown Formation

23.4.2 Reducing Crown Height

23.5 Grain Refining

23.5.1 Ultrasonic Weld Pool Stirring

23.5.2 Arc Pulsation

23.5.3 Arc Oscillation

23.6 Solidification Cracking

23.7 Liquation Cracking

23.7.1 A Simple Test for Crack Susceptibility

23.7.2 Effect of Filler Metals

23.7.3 Effect of Grain Size

23.8 Heat‐Affected Zone Weakening

Examples

Answer

Answer

Answer

Answer

References

Further Reading

Problems

24 Welding of High‐Entropy Alloys and Metal‐Matrix Nanocomposites

24.1 High‐Entropy Alloys. 24.1.1 Solidification Microstructure

24.1.2 Weldability

24.2 Metal‐Matrix Nanocomposites

24.2.1 Nanoparticles Increasing Weld Size

24.2.2 Nanoparticles Refining Microstructure

24.2.3 Nanoparticles Reducing Cracking During Solidification

24.2.4 Nanoparticles Allowing Friction Stir Welding

Examples

References

Further Reading

Problems

Appendix A Analytical Equations for Susceptibility to Solidification Cracking

Index

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Third Edition

Sindo Kou

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Sindo Kou

Madison, Wisconsin, 2020

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