Functional Metal-Organic Frameworks

Functional Metal-Organic Frameworks
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Описание книги

Owing to the extensive interest in construction of functional metal organic frameworks (FMOFs), this book discusses the roles of functional groups on the structure and application of metal organic frameworks (MOFs). The contents of the book are classified based on the structural and chemical properties of organic functions, in order to make readers able to compare the different effects of each function on the structure and application of the MOFs. In each chapter, the chemical properties of applied functional groups are gathered to give deeper insight into the roles of organic functions in the structure and application of MOFs. In the function-application properties, the authors discuss how a functional group can dominate the host-guest chemistry of the MOFs and how this host-guest chemistry can expand the effectiveness and efficiency of the material in different fields of applications. Finally, function-structure properties are discussed. In function-application properties, it is discussed how a functional group can affect the topology, porosity, flexibility and stability of the framework. The features of this subject are novel and are presented for the first time.

Оглавление

Ali Morsali. Functional Metal-Organic Frameworks

Table of Contents

List of Illustrations

Guide

Pages

Functional Metal-Organic Frameworks. Structure, Properties and Applications

Preface

1. Introduction to Functional Metal–Organic Frameworks

1.1 Coordination Polymers

1.2 Metal–Organic Frameworks

1.3 Functional Metal–Organic Frameworks

References

2. Amine Decorated Metal–Organic Frameworks

2.1 General Chemical Properties of Amine Function

2.2 Function–Application Properties

2.3 Function–Structure Properties

References

3. Azo and Azine Decorated Metal–Organic Frameworks

3.1 General Chemical Properties of Azine and Azo Functions

3.2 Function–Application Properties

3.3 Function-Structure Properties

References

4. Imidazolium and Pyridinium Decorated Metal-Organic Frameworks

4.1 Imidazolium Functionalized Metal–Organic Frameworks. 4.1.1 General Chemical Properties of Imidazolium Function

4.1.2 Function–Application Properties

4.1.3 Function–Structure Properties

4.2 Pyridinium Functionalized Metal–Organic Frameworks. 4.2.1 General Chemical Properties of Pyridinium Function

4.2.2 Function–Application Properties

4.2.3 Function–Structure Properties

References

5. Heterocyclic Azine Decorated Metal-Organic Frameworks

5.1 General Chemical Properties of Heterocyclic Azine Functions

5.2 Function–Application Properties

5.3 Function–Structure Properties

References

6. Heterocyclic Azole Decorated Metal-Organic Frameworks

6.1 General Chemical Properties of Heterocyclic Azole Functions

6.2 Function–Application Properties

6.3 Function–Structure Properties

References

7. Functional Metal–Organic Frameworks by Oxygen and Sulfur Based Functions

7.1 Functionalized Metal–Organic Frameworks by Oxygen Based Functions. 7.1.1 Function–Application Properties

7.1.2 Function–Structure Properties

7.2 Functionalized Metal–Organic Frameworks by Sulfur Based Functions

7.2.1 Functionalized Metal–Organic Frameworks by Thiol and Sulfide Functions

7.2.2 Functionalized Metal–Organic Frameworks by Sulfonate-Sulfonic Acid Function

7.2.3 Functionalized Metal–Organic Frameworks by Other S-Based Functions

References

8. Urea and Amide Decorated Metal-Organic Frameworks

8.1 Functionalized Metal–Organic Frameworks by Amide Function. 8.1.1 General Chemical Properties of Amide Function

8.1.2 Function–Application Properties

8.1.3 Function–Structure Properties

8.2 Functionalized Metal–Organic Frameworks by Urea Function. 8.2.1 General Chemical Properties of Urea Function

8.2.2 Function–Application Properties

8.2.3 Structure–Function Properties

8.3 Functionalized Metal–Organic Frameworks by Squaramide Function

References

9. Carbonyl, Carboxy and Imide Functionalized Metal–Organic Frameworks

9.1 Functionalized Metal–Organic Frameworks by Carbonyl Function. 9.1.1 General Chemical Properties of Carbonyl Functional Group

9.1.2 Function–Application Properties

9.1.3 Function–Structure Properties

9.2 Functionalized Metal–Organic Frameworks by Carboxy Function. 9.2.1 General Chemical Properties of Carboxy Function

9.2.2 Synthesis of Functionalized Metal-Organic Frameworks with Free Carboxy Function

9.2.3 Function–Application Properties

9.2.4 Function–Structure Properties

9.3 Functionalized Metal–Organic Frameworks by Imide Function. 9.3.1 General Chemical Properties of Imide Function

9.3.2 Function–Application Properties

References

10. Fluorine and Phosphonate Functional Metal–Organic Frameworks

10.1 Functionalized Metal–Organic Frameworks by Phosphonic Acid/Phosphonate Functions

10.2 Functionalized Metal–Organic Frameworks by Fluorine Function

References

Index

WILEY END USER LICENSE AGREEMENT

Отрывок из книги

Scrivener Publishing

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20. Getman, R.B., Bae, Y.-S., Wilmer, C.E., Snurr, R.Q., Review and analysis of molecular simulations of methane, hydrogen, and acetylene storage in metal–organic frameworks. Chem. Rev., 112, 703–723, 2011.

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