Biobased Composites

Biobased Composites
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Explore the world of biocomposites with this one-stop resource edited by four international leaders in the field Biobased Composites: Processing, Characterization, Properties, and Applications delivers a comprehensive treatment of all known characterization methods, properties, and industry applications of biobased composites materials. This unique, one-stop resource covers all major developments in the field from the last decade of research into this environmentally beneficial area. The internationally recognized editors have selected resources that represent advances in the mechanical, thermal, tribological, and water sorption properties of biobased composites, and cover new areas of research in physico-chemical analysis, flame retardancy, failure mechanisms, lifecycle assessment, and modeling of biobased composites. The low weight, low cost, excellent thermal recyclability, and biodegradability of biobased composites make them ideal candidates to replace engineered plastic products derived from fossil fuel. This book provides its readers with the knowledge they'll require to understand a new class of materials increasingly being used in the automotive and packaging industries, aerospace, the military, and construction. It also includes: An extended discussion of the environmental impact of biobased composites using a life cycle methodology A review of forecasts of natural fiber reinforced polymeric composites and its degradability concerns An analysis of the physical and mechanical properties of a biobased composite with sisal powder A comprehensive treatment of the mechanical, thermal, tribological, and dielectric properties of biobased composites A review of processing methods for the manufacture of biobased composites Perfect for materials scientists in private industry, government laboratories, or engaged in academic research, Biobased Composites will also earn a place in the libraries of industrial and manufacturing engineers who seek a better understanding of the beneficial industrial applications of biocomposites in industries ranging from automobiles to packaging.

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Группа авторов. Biobased Composites

Table of Contents

List of Tables

List of Illustrations

Guide

Pages

Biobased Composites. Processing, Characterization, Properties, and Applications

List of Contributors

Preface

1 Introduction to Biobased Composites

1.1 Introduction

1.2 Biodegradable Materials

1.3 Polymers in Tissue Engineering

1.4 Environmental Realization

1.4.1 Green Biomass‐based Composites

1.4.2 Selection Considerations

1.4.2.1 Materials Implementation Requirements

1.4.2.2 Material Cost

1.5 Biomass Composites Characteristics and Testing

1.6 Life‐cycle Assessment

1.7 Conclusions

References

2 Processing Methods for Manufacture of Biobased Composites

2.1 Introduction

2.2 Biobased Materials

2.3 Processing Methods

2.4 Fabrication Techniques of Biobased Composites

2.4.1 Solvent Casting and Particulate Leaching

2.4.2 Emulsion Freeze Drying

2.4.3 Electrospinning

2.4.4 Blow Film Extrusion

2.4.5 3D Printing

2.5 Fillers and Reinforcements Used in the Preparation of Biobased Composites

2.5.1 Biobased Fillers/Reinforcements with Non‐biobased Polymers

2.5.2 Non‐biobased Fillers/Reinforcements with Biobased Polymers

2.5.3 Biobased Filler/Reinforcement and Biobased Polymer

2.6 Conclusion

References

3 Physicochemical Analysis of Biobased Composites

3.1 Introduction

3.2 Performance of Biocomposites

3.2.1 Tensile Properties

3.2.2 Flexural Properties

3.2.3 Impact Properties

3.2.4 Creep

3.2.5 Brittleness and Ductility

3.2.6 Toughness

3.3 Physicochemical Properties

3.4 Conclusion

References

4 Characterization of Biobased Composites

4.1 Introduction

4.2 The Conception of Composites

4.3 Classification of Biocomposites

4.4 Materials for the Synthesis of Biobased Composites

4.4.1 Biopolymers as Matrix of Green Composites

4.4.2 Fibers as Natural Reinforcement

4.5 Challenges of the Introduction of Natural Fiber

References

5 Mechanical, Thermal, Tribological, and Dielectric Properties of Biobased Composites

5.1 Introduction

5.2 Characterization of Biobased Composites

5.3 Factors Influencing Various Properties of the Biobased Composites

5.3.1 Constituents of Biobased Composites

5.3.2 Fabrication Techniques of Biobased Composites

5.3.3 Aging and Their Impact on the Composite Properties

5.4 Mechanical Properties of Biobased Composites

5.5 Thermal Properties of Biobased Composites

5.5.1 Thermogravimetric Analysis of Biobased Composites

5.5.2 Dynamic Mechanical Analysis of Biobased Composites

5.6 Tribological Properties of Biobased Composites

5.7 Dielectric Properties of Biobased Composites

5.8 Conclusions

References

6 Flame Retardancy of Biobased Composites

6.1 Introduction

6.1.1 Flame Retardants

6.1.2 Types of Flame Retardants

6.2 Types of Biobased Polymer Composites Used in a Flame‐Retardant Application

6.3 Role and Effect of Natural Byproducts on the Flame‐Retardant Behavior of a Biocomposite

6.3.1 Flammability of Biochar Reinforced Biocomposites

6.3.2 Commonly Used Agro‐wastes to Improve the Flame Retardancy of a Biocomposite

6.4 Role and Effect of Biobased Natural Fibers on the Flammability of a Biocomposite

6.5 Summary

References

7 Failure Mechanisms of Biobased Composites

7.1 Introduction

7.1.1 Fiber Reinforcements in Biobased Composites

7.1.2 Fiber Failures

7.1.2.1 Fiber–Matrix Debonding

7.1.2.2 Fiber Pullout

7.1.2.3 Tear Type Failure

7.1.3 Fiber Pretreatments. 7.1.3.1 Defibration

7.1.3.2 Surface Modification

7.1.3.3 Coupling Agent

7.2 Matrix Materials for Biobased Composites

7.2.1 Matrix Failure

7.2.2 Matrix Treatment

7.3 Trends in Biobased Composites

7.3.1 Wood Plastic Composites

7.3.1.1 Failure in WPC

7.3.2 Hybrid Combination

7.4 Adapted Manufacturing Technologies

7.4.1 Injection Molding

7.4.2 Liquid Composite Molding

7.5 Other Failure Criteria

7.6 Conclusion

References

8 Recent Advances and Technologies of Biobased Composites

8.1 Introduction

8.2 Recent Advances on Biobased Matrices

8.2.1 Carbohydrate‐Based Matrices

8.2.2 Plant Oil‐Based Matrices

8.2.3 Biobased Polyester Matrices

8.2.4 Natural Rubber

8.2.5 Collagen

8.3 Recent Advances on Biobased Reinforcements

8.3.1 Biobased Fiber Reinforcements

8.3.2 Wood Biochar‐Based Reinforcements

8.3.3 Biobased Nanocomposite Reinforcements. 8.3.3.1 Cellulose Nanocomposites

8.3.3.2 Other Nanocomposites

8.4 Recent Advances on Biobased Composite Processing

8.4.1 Extrusion and Injection Molding Techniques

8.4.2 Wet Lay‐Up Techniques

8.4.3 3D Printing of Biobased Composites

8.5 Conclusion

References

9 Biocomposites for Energy Storage

9.1 Introduction

9.2 Fundamental Concepts. 9.2.1 Background

9.3 Selection Parameters for Biocomposites

9.3.1 Host Response and Biocompatibility

9.3.2 Biofunctionality

9.3.3 Functional Tissue Structure and Pathobiology

9.3.4 Toxicology

9.3.5 Design and Manufacturability

9.3.6 Mechanical Properties

9.3.7 Corrosion Resistance

9.3.8 Wear and Fatigue Resistance

9.4 Biocomposites for Energy Storage

9.5 Bioinspired Composite Materials

9.6 Bioinspired Composites for Energy Storage

9.7 Enzyme‐Based Materials

9.8 Biosensing/Bioimaging Applications

9.9 Conclusion

References

10 Analysis of the Physical and Mechanical Properties of A Biobased Composite with Sisal Powder

10.1 Introduction

10.2 Biobased Composites

10.3 Polyester Matrix Composites

10.4 Manufacture of Composites

10.5 Physical–Mechanical Tests

10.6 Analysis of Physical and Mechanical Properties

10.7 Conclusions

Acknowledgments

References

11 Physico‐Mechanical Properties of Biobased Composites

11.1 Introduction

11.1.1 Biobased Fibers

11.1.2 Biobased Matrices

11.2 Physico‐Mechanical Property of the Biobased Composites

11.2.1 Density of Biobased Composites

11.2.2 Mechanical Properties of Biobased Composites

11.3 Applications of Biobased Composites

11.4 Conclusions

References

12 Synthesis and Utilization of Biodegradable Polymers

12.1 Introduction

12.2 Synthesis Techniques of Biodegradable Polymers. 12.2.1 By Modifying Natural Polymers

12.2.2 Polymers Synthesized by Chemicals

12.2.3 Polymers Synthesized by Microorganisms

12.2.4 Synthesis by Enzymes

12.2.5 Synthesis by Chemo‐Enzymes

12.3 Biodegradable Polymers and Their Synthesis. 12.3.1 Starch

12.3.2 Polylactic Acid

12.3.3 Polycaprolactone

12.3.4 Polyhydroxyalkanoates/Polyhydroxybutyrate

12.3.5 Starch–Polyolefin Blends

12.3.6 Starch–Polyester Blends

12.3.7 Starch–PLA Blends

12.4 Applications of Biopolymers in Industries

12.5 Conclusion

References

13 Forecasts of Natural Fiber Reinforced Polymeric Composites and Its Degradability Concerns – A Review

13.1 Introduction

13.2 Recent Trends of Natural Fiber Production from Plants

13.3 Magnitude of Natural Fibers at this Juncture

13.4 Constraints and Competence of Natural Fibers

13.5 Degradability of Polymeric Natural Fiber Composites

13.6 Marine Application of Natural Fiber Composites and Its Degradation

13.7 Conclusion

Acknowledgments

References

14 Biofibers and Biopolymers for Biocomposites – in the Eyes of Spectroscopy

14.1 Introduction

14.1.1 Polylactic Acid

14.1.2 Polyhydroxyalkanoates

14.1.3 Polycaprolactone

14.2 Characterization

14.2.1 Scanning Electron Microscopy

14.2.1.1 Morphological Inspection by SEM

14.2.1.2 Degree of Adhesion by SEM

14.2.1.3 Water Absorption of Composites by SEM

14.2.2 Optical Microscopy

14.2.3 Atomic Force Microscopy

14.2.4 Transmission Electron Microscopy

14.2.5 Spectroscopic Techniques

14.2.5.1 NMR Analysis

14.2.5.2 Infrared Spectroscopy (IR)

14.2.5.3 Acoustic Emission Spectrometry

14.3 Conclusions

References

15 Environmental Impact Study on Biobased Composites Using Lifecycle Methodology

15.1 Introduction

15.2 Lifecycle Assessment

15.2.1 Goal and Scope

15.2.2 Inventory Data

15.2.3 Impact Assessment

15.2.4 Interpretation

15.3 Simplified Case Study

15.4 Goal and Scope

15.5 System Boundary

15.6 Inventory Analysis

15.7 Impact Assessment

15.8 Results

15.8.1 Normalization

15.9 Conclusion

References

Index. a

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First Edition

Anish Khan

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J. Maniraj Department of Mechanical Engineering, KIT‐Kalaignarkarunanidhi Institute of Technology, Coimbatore, Tamil Nadu, India

Moises Melo Department of Textile Engineering, Laboratory of Characterization of the Textile Materials, Federal University of Rio Grande do Norte, Natal, RN, Brazil

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