Applied Water Science

Applied Water Science
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Water is one of the most precious and basic needs of life for all living beings, and a precious national asset. Without it, the existence of life cannot be imagined. Availability of pure water is decreasing day by day, and water scarcity has become a major problem that is faced by our society for the past few years. Hence, it is essential to find and disseminate the key solutions for water quality and scarcity issues. The inaccessibility and poor water quality continue to pose a major threat to human health worldwide. Around billions of people lacking to access drinkable water. The water contains the pathogenic impurities; which are responsible for water-borne diseases. The concept of water quality mainly depends on the chemical, physical, biological, and radiological measurement standards to evaluate the water quality and determine the concentration of all components, then compare the results of this concentration with the purpose for which this water is used. Therefore, awareness and a firm grounding in water science are the primary needs of readers, professionals, and researchers working in this research area. This book explores the basic concepts and applications of water science. It provides an in-depth look at water pollutants’ classification, water recycling, qualitative and quantitative analysis, and efficient wastewater treatment methodologies. It also provides occurrence, human health risk assessment, strategies for removal of radionuclides and pharmaceuticals in aquatic systems. The book chapters are written by leading researchers throughout the world. This book is an invaluable guide to students, professors, scientists and R&D industrial specialists working in the field of environmental science, geoscience, water science, physics and chemistry.

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Группа авторов. Applied Water Science

Table of Contents

Guide

List of Illustrations

List of Tables

Pages

Applied Water Science Volume 1. Fundamentals and Applications

Preface. Applied Water Science I-Fundamentals and Applications

1. Sorbent-Based Microextraction Techniques for the Analysis of Phthalic Acid Esters in Water Samples

1.1 Introduction

1.2 Solid-Phase Microextraction

1.3 Stir Bar Sorptive Extraction

1.4 Solid-Phase Extraction

1.5 Others Minor Sorbent-Based Microextraction Techniques

1.6 Conclusions

Acknowledgements

References

2. Occurrence, Human Health Risks, and Removal of Pharmaceuticals in Aqueous Systems: Current Knowledge and Future Perspectives

2.1 Introduction

2.2 Occurrence and Behaviour of Pharmaceutics in Aquatic Systems. 2.2.1 Nature and Sources

2.2.2 Dissemination and Occurrence in Aquatic Systems

2.2.3 Behaviour in Aquatic Systems

2.3 Human Health Risks and Their Mitigation. 2.3.1 Human Exposure Pathways

2.3.2 Potential Human Health Risks

2.3.3 Human Health Risks: A Developing World Perspective

2.3.4 Removal of Pharmaceuticals

2.3.4.1 Conventional Removal Methods

2.3.4.2 Advanced Removal Methods

2.3.4.2.1 Advanced Oxidation Processes

2.3.4.2.2 Photolysis

2.3.4.2.3 Ozonation

2.3.4.2.4 O3/UV/H2O2 as an Oxidant

2.3.4.2.5 Fenton Process

2.3.4.2.6 Adsorption

2.3.4.3 Hybrid Removal Processes

2.4 Knowledge Gaps and Future Research Directions

2.4.1 Increasing Africa’s Research Footprint

2.4.2 Hotspot Sources and Reservoirs

2.4.3 Behaviour and Fate in Aquatic Systems

2.4.4 Ecotoxicology of Pharmaceuticals and Metabolites

2.4.5 Human Exposure Pathways

2.4.6 Human Toxicology and Epidemiology

2.4.7 Removal Capacity of Low-Cost Water Treatment Processes

2.5 Summary, Conclusions, and Outlook

Author Contributions

References

3. Oil-Water Separations

3.1 Introduction

3.2 Sources and Composition

3.3 Common Oil-Water Separation Techniques

3.4 Oil-Water Separation Technologies

3.4.1 Advancement in the Technology of Membrane

3.4.1.1 Polymer-Based Membranes

3.4.1.2 Ceramic-Based Membranes

3.5 Separation of Oil/Water Utilizing Meshes

3.5.1 Mechanism Involved

3.5.2 Meshes Functionalization

3.5.2.1 Inorganic Materials

3.5.2.2 Organic Materials

3.6 Separation of Oil-Water Mixture Using Bioinspired Surfaces

3.6.1 Nature’s Lesson

3.6.2 Superhydrophilic/Phobic and Superoleophilic/Phobic Porous Surfaces

3.7 Conclusion

Acknowledgment

References

4. Microplastics Pollution

4.1 Introduction and General Considerations

4.2 Key Scientific Issues Concerning Water and Microplastics Pollution

4.3 Marine Microplastics: From the Anthropogenic Litter to the Plastisphere

4.4 Social and Human Perspectives: From Sustainable Development to Civil Science

4.5 Conclusions and Future Projections

References

5. Chloramines Formation, Toxicity, and Monitoring Methods in Aqueous Environments

5.1 Introduction

5.2 Inorganic Chloramines Formation and Toxicity

5.3 Analytical Methods for Inorganic Chloramines

5.3.1 Colorimetric and Batch Methods

5.3.2 Chromatographic Methods

5.3.3 Membrane Inlet Mass Spectrometry

5.4 Organic Chloramines Formation and Toxicity

5.5 Analytical Methods for Organic Chloramines

5.6 Conclusions

References

6. Clay-Based Adsorbents for the Analysis of Dye Pollutants

6.1 Introduction

6.1.1 Biological Method

6.1.2 Physical Method

6.1.3 Why Only Clays?

6.1.4 Clay-Based Adsorbents

6.1.4.1 Kaolinite

6.1.4.2 Rectorite

6.1.4.3 Halloysite

6.1.4.4 Montmorillonite

6.1.4.5 Sepiolite

6.1.4.6 Laponite

6.1.4.7 Bentonite

6.1.4.8 Zeolites

6.2 Membrane Filtration

6.3 Chemical Treatment

6.3.1 Fenton and Photo-Fenton Process

6.3.2 Mechanism Using Acid and Base Catalyst

6.4 Photo-Catalytic Oxidation

6.5 Conclusions

Acknowledgments

References

7. Biochar-Supported Materials for Wastewater Treatment

7.1 Introduction

7.2 Generalities of Biochar: Structure, Production, and Properties. 7.2.1 Biochar Structure

7.2.2 Biochar Production

7.2.2.1 Pyrolysis

7.2.2.2 Gasification

7.2.2.3 Hydrothermal Carbonization

7.2.3 Biochar Properties

7.2.3.1 Porosity

7.2.3.2 Surface Area

7.2.3.3 Surface Functional Groups

7.2.3.4 Cation Exchange Capacity

7.2.3.5 Aromaticity

7.3 Biochar-Supported Materials

7.3.1 Magnetic Biochar Composites

7.3.2 Nano-Metal Oxide/Hydroxide-Biochar Composites

7.3.3 Functional Nanoparticles-Coated Biochar Composites

7.4 Conclusion

References

8. Biological Swine Wastewater Treatment

8.1 Introduction

8.2 Swine Wastewater Characteristics

8.3 Microorganisms of Biological Swine Wastewater Treatment

8.4 Classification of Biological Swine Wastewater Treatment

8.5 Biological Processes For Swine Wastewater Treatment

8.5.1 Suspended Growth Processes. 8.5.1.1 Activated Sludge Process

8.5.1.2 Sequential Batch Reactor

8.5.1.3 Sequencing Batch Membrane Bioreactor

8.5.1.4 Anaerobic Contact Process

8.5.1.5 Anaerobic Digestion

8.5.2 Attached Growth Processes. 8.5.2.1 Rotating Biological Contactor

8.5.2.2 Upflow Anaerobic Sludge Blanket

8.5.2.3 Anaerobic Filter

8.5.2.4 Hybrid Anaerobic Reactor

8.6 Challenges and Future Prospects in Swine Wastewater Treatment

References

9. Determination of Heavy Metal Ions From Water

9.1 Introduction

9.2 Detection of Heavy Metal Ions

9.2.1 Atomic Absorption Spectroscopy

9.2.2 Nanomaterials

9.2.3 High-Resolution Surface Plasmon Resonance

9.2.4 Biosensors

9.2.4.1 Enzyme-Based Biosensors

9.2.4.2 Electrochemical Sensors

9.2.4.3 Polymer-Based Biosensors

9.2.4.4 Bacterial-Based Sensors

9.2.4.5 Protein-Based Sensors

9.2.5 Attenuated Total Reflectance

9.2.6 High-Resolution Differential Surface Plasmon Resonance Sensor

9.2.7 Hydrogels

9.2.8 Chelating Agents

9.2.9 Ionic Liquids

9.2.10 Polymers

9.2.10.1 Dendrimers

9.2.11 Macrocylic Compounds

9.2.12 Inductively Coupled Plasma Mass Spectrometry

9.3 Conclusions

References

10. The Production and Role of Hydrogen-Rich Water in Medical Applications

10.1 Introduction

10.2 Functional Water

10.3 Reduced Water

10.4 Production of Hydrogen-Rich Water

10.5 Mechanism of Hydrogen Molecules During Reactive Oxygen Species Scavenging

10.6 Hydrogen-Rich Water Effects on the Human Body. 10.6.1 Anti-Inflammatory Effects

10.6.2 Anti-Radiation Effects

10.6.3 Wound Healing Effects

10.6.4 Anti-Diabetic Effects

10.6.5 Anti-Neurodegenerative Effects

10.6.6 Anti-Cancer Effects

10.6.7 Anti-Arteriosclerosis Effects

10.7 Other Effects of Hydrogenated Water. 10.7.1 Effect of Hydrogen-Rich Water in Hemodialysis

10.7.2 Effect on Anti-Cancer Drug Side Effects

10.8 Applications of Hydrogen-Rich Water. 10.8.1 In Health Care

10.8.2 In Sports Science

10.8.3 In Therapeutic Applications and Delayed Progression of Diseases

10.9 Safety of Using Hydrogen-Rich Water

10.10 Concluding Remarks

References

11. Hydrosulphide Treatment

11.1 Introduction

11.1.1 Agriculture

11.1.2 Medical

11.1.3 Industrial

11.2 Conclusions

References

12. Radionuclides: Availability, Effect, and Removal Techniques

12.1 Introduction

12.1.1 Available Radionuclides in the Environment. 12.1.1.1 Uranium

12.1.1.2 Thorium (Z = 90)

12.1.1.3 Radium (Z = 88)

12.1.1.4 Radon (Z = 86)

12.1.1.5 Polonium and Lead

12.1.2 Presence of Radionuclide in Drinking Water

12.1.2.1 Health Impacts of Radionuclides

12.1.2.2 Health Issues Caused Due to Uranium

12.1.2.3 Health Issues Caused Due to Radium

12.1.2.4 Health Issues Caused Due to Radon

12.1.2.5 Health Issues Caused Due to Lead and Polonium

12.2 Existing Techniques and Materials Involved in Removal of Radionuclide. 12.2.1 Ion Exchange

12.2.2 Reverse Osmosis

12.2.3 Aeration

12.2.4 Granulated Activated Carbon

12.2.5 Filtration

12.2.6 Lime Softening, Coagulation, and Co-Precipitation

12.2.7 Flocculation

12.2.8 Nanofilteration

12.2.9 Greensand Filteration

12.2.10 Nanomaterials. 12.2.10.1 Radionuclides Sequestration by MOFs

12.2.10.2 Radionuclides Removal by COFs

12.2.10.3 Elimination of Radionuclides by GOs

12.2.10.4 Radionuclide Sequestration by CNTs

12.2.11 Ionic Liquids

12.3 Summary of Various Nanomaterial and Efficiency of Water Treating Technology

12.4 Management of Radioactive Waste

12.5 Conclusion

References

13. Applications of Membrane Contactors for Water Treatment

13.1 Introduction

13.2 Characteristics of Membrane Contactors

13.3 Membrane Module Configurations

13.4 Mathematical Aspects of Membrane Contactors

13.5 Advantages and Limitations of Membrane Contactors. 13.5.1 Advantages

13.5.1.1 High Interfacial Contact

13.5.1.2 Absence of Flooding and Loading

13.5.1.3 Minimization of Back Mixing and Emulsification

13.5.1.4 Freedom for Solvent Selection

13.5.1.5 Reduction in Solvent Inventory

13.5.1.6 Modularity

13.5.2 Limitations

13.6 Membrane Contactors as Alternatives to Conventional Unit Operations

13.6.1 Liquid-Liquid Extraction

13.6.2 Membrane Distillation

13.6.3 Osmotic Distillation

13.6.4 Membrane Crystallization

13.6.5 Membrane Emulsification

13.6.6 Supported Liquid Membranes

13.6.7 Membrane Bioreactors

13.7 Applications. 13.7.1 Wastewater Treatment

13.7.2 Metal Recovery From Aqueous Streams

13.7.3 Desalination

13.7.4 Concentration of Products in Food and Biotechnological Industries

13.7.5 Gaseous Stream Treatment

13.7.6 Energy Sector

13.8 Conclusions and Future Prospects

References

14. Removal of Sulfates From Wastewater

14.1 Introduction

14.2 Effect of Sulfate Contamination on Human Health

14.3 Groundwater Distribution of Sulfate

14.4 Traditional Methods for Sulfate Removal. 14.4.1 Treatment With Lime

14.4.2 Treatment With Limestone

14.4.3 Wetlands

14.5 Modern Day’s Technique for Sulfate Removal. 14.5.1 Nanofiltration

14.5.2 Electrocoagulation

14.5.3 Precipitation Methods

14.5.4 Adsorption

14.5.5 Ion Exchange

14.5.6 Biological Treatment

14.5.7 Removal of Sulfate by Crystallization

14.6 Conclusions and Future Perspective

Acknowledgment

References

15. Risk Assessment on Human Health With Effect of Heavy Metals

15.1 Introduction

15.2 Toxic Effects Heavy Metals on Human Health

15.3 Biomarkers and Bio-Indicators for Evaluation of Heavy Metal Contamination

15.3.1 Hazard Quotient

15.3.2 Transfer Factor

15.3.3 Daily Intake of Metal

15.3.4 The Bioaccumulation Factor

15.3.5 Translocation Factor

15.3.6 Enrichment Factor

15.3.7 Metal Pollution Index

15.3.8 Health Risk Index

15.3.9 Pollution Load Index

15.3.10 Index of Geo-Accumulation

15.3.11 Potential Risk Index

15.3.12 Exposure Assessment

15.3.13 Carcinogenic Risk

References

16. Water Quality Monitoring and Management: Importance, Applications, and Analysis

16.1 Qualitative Analysis: An Introduction to Basic Concept

16.2 Significant Applications of Qualitative Analysis

16.2.1 Water Quality

16.2.2 Water Quality Index

16.3 Qualitative Analysis of Water

16.3.1 Sampling Procedure

16.3.2 Sample Transportation and Preservation

16.3.3 Some Important Physico-Chemical Parameters of Water Quality

16.4 Existing Water Quality Standards

16.5 Quality Assurance and Quality Control

16.6 Conclusions

References

17. Water Quality Standards

17.1 Introduction

17.2 Chemical Standards for Water Quality

17.2.1 Physical Standards

17.2.2 Chemical Standards for Salt Water Quality

17.2.3 Biological Standards

17.2.4 Radiation Standards

17.2.5 Wastewater and Water Quality

17.3 Inorganic Substances and Their Effect on Palatability and Household Uses. 17.3.1 Aluminum

17.3.2 Calcium

17.3.3 Magnesium

17.3.4 Chlorides

17.4 The Philosophy of Setting Standards for Drinking Water (Proportions and Concentrations of Water Components)

17.5 Detection of Polychlorinated Biphenyls

17.6 The Future Development of Water Analysis

17.7 Conclusion

References

18. Qualitative and Quantitative Analysis of Water

18.1 Introduction

18.2 Sources of Water

18.3 Water Quality

18.3.1 Physical Parameters

18.3.2 Chemical Parameters

18.3.3 Biological Parameters

18.3.4 Water Quality Index

18.4 Factors Affecting the Quality of Surface Water

18.5 Quantitative Analysis of the Organic Content of the Wastewater

18.5.1 Biochemical Oxygen Demand

18.5.1.1 DO Profile Curve in BOD Test

18.5.1.2 Significance of BOD Test

18.5.1.3 Nitrification in BOD Test

18.5.2 Chemical Oxygen Demand

18.5.3 Theoretical Oxygen Demand (ThOD)

18.6 Treatment of Wastewater

18.6.1 Primary Treatment Method

18.6.1.1 Pre-Aeration

18.6.1.2 Flocculation

18.6.2 Secondary Treatment

18.6.2.1 Aerobic Biological Process

18.6.2.2 Anaerobic Biological Treatment

18.6.2.3 Activated Sludge Process

18.6.3 Tertiary Treatment

18.6.3.1 Nutrients Removal

18.6.3.1.1 Aeration

18.6.3.1.2 Biological Nitrification and Denitrification

18.6.3.1.2.1 NITRIFICATION

18.6.3.1.2.2 DENITRIFICATION

18.6.3.2 Phosphorus Removal

18.6.3.3 Ion-Exchange Process

18.6.3.4 Membrane Process

18.6.3.5 Disinfection

18.6.3.6 Coagulation

18.7 Instrumental Analysis of Wastewater Parameters

18.7.1 Hardness

18.7.2 Alkalinity

18.7.3 pH

18.7.4 Turbidity

18.7.5 Total Dissolved Solids

18.7.6 Total Organic Carbon

18.7.7 Color

18.7.8 Atomic Absorption Spectroscopy

18.7.9 Inductive Coupled Plasma–Mass Spectroscopy

18.7.10 Gas Chromatography With Mass Spectroscopy

18.8 Methods for Qualitative Determination of Water

18.8.1 Weight Loss Method

18.8.2 Karl Fischer Method

18.8.3 Fourier Transform Infrared Spectroscopy Method

18.8.4 Nuclear Magnetic Resonance Spectroscopy Method

18.9 Conclusion

References

19. Nanofluids for Water Treatment

19.1 Introduction

19.2 Types of Nanofluids Used in the Treatment of Water

19.2.1 Zero-Valent Metal Nanoparticles. 19.2.1.1 Silver Nanoparticles (AgNPs)

19.2.1.2 Iron Nanoparticles

19.2.1.3 Zinc Nanoparticles

19.2.2 Metal Oxides Nanoparticles. 19.2.2.1 Tin Dioxide (TiO2) Nanoparticles

19.2.2.2 Zinc Oxide Nanoparticles (ZnO NPs)

19.2.2.3 Iron Oxides Nanoparticles

19.2.3 Carbon Nanotubes

19.2.4 Nanocomposite Membranes

19.2.5 Modes of Action of These Nanofluids. 19.2.5.1 Carbon-Based Nano-Adsorbents (CNTs) for Organic Expulsion

19.2.5.2 Heavy Metal Removal

19.2.5.3 Metal-Based Nano-Adsorbents

19.2.5.4 Polymeric Nano-Adsorbents

19.2.5.5 Nanofiber Membranes

19.2.5.6 Some Applications of Nanofluids in the Treatment of Water

19.2.5.7 Informatics and AI Nanofluid-Enhanced Water Treatment

19.3 Conclusion and Recommendation to Knowledge

References

Index

Also of Interest

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44. Eskandarpour, N., Sereshti, H., Electrospun polycaprolactam-manganese oxide fiber for headspace-solid phase microextraction of phthalate esters in water samples. Chemosphere, 191, 36, 2018.

45. He, J., Lv, R., Zhan, H., Wang, H., Cheng, J., Lu, K., Wang, F., Preparation and evaluation of molecularly imprinted solid-phase micro-extraction fibers for selective extraction of phthalates in an aqueous sample. Anal. Chim. Acta, 674, 53, 2010.

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