Оглавление
Группа авторов. Self-Healing Smart Materials
Table of Contents
List of Illustrations
List of Tables
Guide
Pages
Self-Healing Smart Materials and Allied Applications
Preface
1. Self-Healing Polymer Coatings
1.1 Introduction
1.2 Extrinsic Self-Healing Polymer Coatings
1.3 Intrinsic Self-Healing Polymer Coatings
1.4 Remote Activation of Self-Healing
1.5 Perspectives and Challenges
References
2. Smart Phenolics for Self-Healing and Shape Memory Applications
2.1 Introduction
2.2 Self-Healable Polybenzoxazines
2.3 Benzoxazine Resins for Shape Memory Applications
2.4 Conclusion
References
3. Self-Healable Elastomers
3.1 Introduction
3.2 Self-Healing in Elastomers
3.2.1 Self-Healing Mechanism
3.2.1.1 Heat Stimulated Self-Healing
3.2.1.2 Light Stimulated Self-Healing
3.2.1.3 Mechanochemical Self-Healing
3.2.1.4 Encapsulation
3.2.2 Characterization of Healing Process
3.3 Particular Cases in Different Elastomers. 3.3.1 Natural Rubber (NR)
3.3.2 Styrene Butadiene Rubber (SBR)
3.3.3 Polybutadiene Rubber
3.3.4 Bromobutyl Rubber
3.3.5 Silicones
3.3.6 Polyurethanes
References
4. Self-Healable Tires
4.1 Introduction
4.2 Self-Healable Rubber
4.3 Promising Strategy for Self-Healing Rubber-Based Material
4.4 Conclusion
References
5. Self-Healing Bacterial Cementitious Composites
5.1 Introduction
5.2 Biomineralization for Self-Healing
5.2.1 Bacteria as Self-Healing Agent
5.2.2 Bacterial Metabolic Pathway in Self-Healing
5.2.2.1 Urea Hydrolysis by Ureolytic Bacteria
5.2.2.2 Hydrolysis of CO2by Carbonic Anhydrase Producing Bacteria
5.2.2.3 Hydrolysis of Organic Acids
5.2.2.4 Dissimilatory Nitrate Reduction
5.2.2.5 Dissimilatory Sulfate Reduction
5.2.2.6 Ammonification
5.3 Strategies to Enhance the Performance of Bacterial Self-Healing
5.4 Evaluation of Factors Affecting Bacterial Self-Healing
5.4.1 Nutrient Suitability for Optimal Bacterial Growth
5.4.2 Viability and Activity of Encapsulated Spores
5.4.3 Evaluation of Encapsulation Material
5.4.4 Crack Healing Efficiency
5.4.5. Effects of Capsule Material and Bacteria on Concrete Properties
5.5 Conclusion, Future Prospective & Challenges
References
6. Self-Healable Solar Cells: Recent Insights and Challenges
6.1 Introduction
6.2 Functional Mechanism of Protection Approaches. 6.2.1 Self-Healable Polymeric Structure
6.2.2 Shape Memory Polymeric Structure
6.2.3 Self-Cleanable Polymeric Platforms
6.3 Advanced Self-Healable Polymeric Materials. 6.3.1 Self-Healable Polymers
6.3.2 Self-Healable Hydrogels
6.4 Shape Memory Materials
6.5 Self-Healable Solar Cells
6.6 Conclusions
References
7. Self-Healable Core–Shell Nanofibers
7.1 Introduction
7.2 Self-Healing Polymers in Fabrication of Core–Shell Nanofibers
7.3 Strategies for Core–Shell Nanofibers Fabrication
7.3.1.Capsule-Based Self-Healing
7.3.2.Vascular-Based Self-Healing
7.4 Methods of Fabrication of Self-Healing Core–Shell Nanofibers
7.4.1.Co-Electrospinning
7.4.2.Emulsion Electrospinning
7.4.3.Solution‐Blown
7.5 Self-Healing in Laminated Composite
7.6 Beneficial Self-Repairing Systems on Basis of Core–Shell Nanofibers
7.7 Conclusion
References
8. Intrinsic Self-Healing Materials
8.1 Introduction
8.2 Inverse Reactions and Chain Recombination
8.3 Reversible (Covalent) Bonds
8.3.1 Cycloadditions
8.3.2 Reversible Acylhydrazones
8.3.3 Disulfides
8.3.4 Alkoxyamines (Radicals)
8.3.5 Transesterification
8.4 Supramolecular Interactions
8.4.1 Hydrogen Bonds
8.4.2 π–π Interaction
8.4.3 Ionomers (Ballistic Stimulus)
8.4.4 Metallopolymers
8.5 Conclusion
References
9. Self-Healable Catalysis
9.1 Introduction
9.2 Self-Healable Catalysis Applications
9.2.1 Oxygen Evolution Catalysts
9.2.2 Specific Catalysis Applications of Self-Healing Property
9.3 Conclusion
References
10. Self-Healing Materials in Corrosion Protection
10.1 Introduction
10.2 Self-Healing Definition
10.3 Inhibition of the Corroded Regions Thanks to the Presence of Corrosion Inhibitive Pigments/Inhibitors
10.4 The Imprisonment and Physical Release of the Inhibitor
10.4.1 Ion-Exchange-Based Materials
10.4.2 Porous-Structure and Metal Oxide Materials
10.4.3 Conductive Polymers
10.4.4 Fibril Materials
10.4.5 Lamellar-Structure Materials
10.4.6 Other Containers
10.5 Healing Using Polymerizable Agents
10.6 Conclusion and Outlook
References
11. Self-Healable Conductive Materials
11.1 Introduction
11.2 Self-Healing Materials. 11.2.1 Elastomers
11.2.2. Reversible Materials
11.3 Self-Healing Conductive Materials. 11.3.1 Polymers
11.3.2 Capsules
11.3.3 Liquids
11.3.4 Composites
11.3.5 Coating
11.4 Conclusion
References
12. Self-Healable Artificial Skin
12.1 Introduction
12.2 Preparation and Properties of Artificial Skin
12.3 Applications of Electronic Skin
12.4 Conclusion
References
13. Self-Healing Smart Composites
13.1 Introduction
13.2 Self-Healing Mechanisms and its Classifications
13.2.1 Intrinsic Self-Repairing Materials
13.2.2 Extrinsic Self-Repairing Materials
13.3 Self-Healing of Thermoplastic Materials
13.4 Self-Healing of Thermosetting Materials
13.5 Conclusions and Future Study
References
14. Stimuli-Responsive Self-Healable Materials
14.1 Self-Healing Materials
14.2 Synthesis of S-H Materials
14.3 Types of S-H Materials
14.4 Need for Stimuli-Responsive Shape Memory (S-RSM) Materials
14.5 Stimuli-Responsive or Nonautonomous S-H Materials
14.5.1 Light Stimuli-Responsive S-H Materials
14.5.2 Thermal Stimuli-Responsive S-H Materials
14.5.3 Chemical Stimuli-Responsive S-H Materials
14.5.4 Electric/Magnetic Stimuli-Responsive S-H Materials
14.5.5 Multi-Stimuli Responsive S-H Material
14.6 Commercialization and Challenges
14.7 Conclusions
References
15. Mechanically-Induced Self-Healable Materials
15.1 Introduction
15.2 Mechanically-Induced Self-Healing Based on Gel
15.3 Mechanically-Induced Self-Healing Based on Crystals
15.4 Mechanically-Induced Self-Healing Based on Composites
15.5 Mechanically-Induced Self-Healing for Corrosion
15.5.1 Capsule-Based Self-Healing Approaches for Corrosion Protection
15.5.2 Fiber-Based Self-Healing Approaches for Corrosion Protection
15.6 Conclusion
References
16. Self-Healing Materials in Robotics
16.1 Introduction
16.2 Chemistry of Self-Healing (S-H) Materials
16.3 Working of Self-Healing (S-H) Material
16.4 Application of Self-Healing Robots
16.4.1 Self-Healing Electronics for Soft Robotics
16.4.2 Self-Healing Electrostatic Actuators
16.4.3 Self-Healing Skin for Robotics
16.5 Approaches to Self-Healing
16.6 Material Application and Damage Resilience Mechanism
16.7 Conclusion
References
17. Self-Healing Materials in Aerospace Applications
17.1 Introduction
17.2 Classification of Self-Healing Materials
17.2.1 Intrinsic Mechanism
17.2.2 Extrinsic Mechanism
17.2.2.1 Microencapsulation
17.2.2.2 Microvascular Network
17.3 Self-Healing Materials in Aerospace Applications
17.3.1 Fiber Reinforced Polymers
17.3.2 Modified Epoxy
17.3.3 Ceramic Matrix Composites
17.4 Conclusion
References
18. Bio-Inspired Self-Healable Materials
18.1 Introduction
18.1.1 Self-Healable Materials and Coatings
18.1.1.1 The Process of Self-Healing Through the Exploitation of Micro-Capsule and Micro-Vascular Method
18.1.1.2 Self-Healing Process Through Reversible Covalent Bond Formation
18.1.1.3 Self-Healable Systems on the Basis of Supramolecular Self-Assembly
18.1.2 Mechanism of Self-Healing Materials
18.2 Repairing and Healing the Damage
18.3 A Systematic Biomimetic Approach
18.4 Self-Healable Materials: Case Studies
18.4.1 Regrowth of Limbs
18.4.2 The Mechanism of Bone Healing
18.4.3 Cutaneous Wound Healing
18.5 Applications of Bio-Inspired Self-Healable Materials—Examples. 18.5.1 Bio-Inspired Ionic Skin for Pressure Sensing
18.5.2 Self-Healable Synthetic Vascular Materials Concerning Internal Damage
18.5.3 Biobased Self-Healable Color Hydrogel
18.5.4 Bio-Inspired Support for Repairing Damaged Articular Cartilage
18.6 Conclusions and Outlook
References
19. Self-Healable Batteries
19.1 Introduction
19.2 Development of Self-Healing Materials
19.3 Self-Healing Batteries
19.3.1 Self-Healable Electrodes
19.3.2 Self-Healable Electrolytes
19.4 Conclusions
References
20. Self-Healing in Bleeding Composites
20.1 Introduction
20.2 Intrinsic and Extrinsic Self-Healing Materials and Their Repairing Approaches
20.3 Strategies of Self-Healing in Engineered Materials. 20.3.1 Materials With Bioinspired Self-Healing Mechanism
20.3.2 Self-Healing in Composite Materials Based on Biomimetic Approaches
20.3.3 Vascular Networks
20.4 Healing Agents, Comparison With Biological Phenomenon and Bleeding Mechanism in Self-Healing Composite Materials
20.4.1 Compartmentalization, Recovery After Yield and Reinforce Repair
20.5 Advantages and Disadvantages of Self-Repairing Bleeding Composite Materials
20.6 Conclusion
References
21. Self-Healing Polymers
21.1 Introduction
21.2 General Overview on Self-Healing Materials
21.3 Design of Self-Healing
21.3.1 Modes of Action of Self-Healing
21.3.2. Rearrangement of Surface Dynamics
21.3.3 Bringing the Surfaces Together
21.3.4 Wetness
21.3.5 Diffusion
21.4 Application of Self-Healing Materials
21.4.1. Properties of Self-Healing
21.4.2 Advancement in Self-Healing
21.4.3. Classification of Self-Healing
21.4.4 Healing Mechanism Types of Healing
21.4.4.1 Crack Filling Healing Process
21.4.4.2 Diffusion
21.4.4.3 Bond Reformation
21.4.4.4 Application
21.5 Specific Examples of Self-Healing Polymer. 21.5.1 Intrinsic Self-Healing
21.5.2 Extrinsic Self-Healing
21.5.3 One Capsule System
21.5.4 Self-Healing Based on Ring Opening Metathesis Polymerization
21.5.5 Solvent-Induced Self-Healing
21.5.6 Dual-Capsule Systems
21.5.6.1 Polydimethylsiloxane Condensation
21.5.6.2 Platinum-Catalyzed Hydrosilylation
21.5.6.3 Adaptive Resistant Effect
21.6 Conclusion and Recommendations
References
Index
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