Nanotechnology-Enhanced Food Packaging

Nanotechnology-Enhanced Food Packaging
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Nanotechnology-Enhanced Food Packaging Timely overview of functional food packaging made with nanotechnology and nanomaterials In Nanotechnology-Enhanced Food Packaging , a distinguished group of researchers delivers a comprehensive and insightful introduction to the application of nanomaterials in food packaging. This edited volume covers recent innovations—as well as future perspectives—in the industry and offers a complete overview of different types of nanomaterials used in food packaging. The book also discusses the use of nanoparticles in the development of active and functional food packaging and the related environmental and toxicological aspects. Featuring one-of-a-kind contributions from leaders in the field, Nanotechnology-Enhanced Food Packaging provides real-world solutions to food packaging challenges and considers the legislative and economic implications of new technologies. Among the new developments in nanotechnology-enhanced food packaging covered by the book are: Thorough introduction to biopolymers in food packaging systems and nanostructures based on starch, their preparation, processing, and applications in packaging Comprehensive explorations of chitosan-based nanoparticles and their applications in the food industry Practical discussions of active packaging systems based on metal oxide nanoparticles and an overview of higher barrier packaging using nano-additives In-depth examinations of the characterization techniques for nanostructures in food packaging Perfect for materials scientists, food technologists, and polymer chemists, Nanotechnology-Enhanced Food Packaging also belongs on the bookshelves of plastics technologists and allied professionals in the food industry.

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Группа авторов. Nanotechnology-Enhanced Food Packaging

Table of Contents

List of Tables

List of Illustrations

Guide

Pages

Nanotechnology-Enhanced Food Packaging

Preface

1 Introduction to Nanotechnology-Enhanced Food Packaging Industry

1.1 Introduction

1.2 Nanotechnology Applications in Food Processing

1.2.1 Nanotechnology Applications in Preserving Meat Density, Taste, and Presentation

1.2.2 Nanotechnology Applications for Maintaining the Food Nutrient Value

1.3 Nanotechnology Functions for Preserving or Shelf Life

1.4 Nanotechnology in Food Packaging

1.4.1 Usages of Nanosensors in Pathogen and Adulterant Detection in the Food Industry

1.4.2 Nanotechnology Applications in Food Safety Issues

1.4.3 Bio-Based Nano-packaging in Food Industry

1.5 Nanocoating Applications in Food Industry

1.6 Nanocoats Used in Food Manufacturing

1.7 Importance of Nanolamine in Food Business

1.8 Antimicrobial Films Used in Food Industry

1.9 Nano-scavenging Oxygen Film Used in Food or Eating Substances

1.10 UV-Proof Processing of Foods Using Nanometal Oxides

1.11 Nano-intelligent Food Labeling

1.12 Nanotechnology-Aided Freshness and Spoilage Indicators

1.13 Nanotechnology-Aided Oxygen Indicators in Food Industry

1.14 Application of Nanotechnology in Product Identification and Anti-counterfeiting

1.15 Usages of Nanotechnology in Traceability and Active Tags in Food and Drug Industry

1.16 Conclusions

References

2 An Overview of Biopolymers in Food Packaging Systems

2.1 Introduction

2.2 Main Polymers Isolated from Biomass. 2.2.1 Casein and Whey

2.2.2 Cellulose and Derivatives

2.2.3 Chitin and Chitosan

2.2.4 Collagen and Gelatin

2.2.5 Soybean and Derivatives

2.2.5.1 Soy Protein

2.2.5.2 Soybean Soluble Polysaccharide

2.2.5.3 Soybean Fiber and Derivatives

2.2.6 Starch and Derivatives

2.3 Main Polymers Obtained by Microbial Production

2.4 Main Biodegradable Polymers Chemically Synthesized

2.5 Conclusions

Conflicts of Interest

Acknowledgments

References

Note

3 Nanostructures Based on Starch, Their Preparation, Processing, and Application in Packaging

3.1 Introduction

3.1.1 Starch Nanoparticles and Nanocrystals

3.1.2 Starch Nanomaterials in Food Packaging

3.1.3 Starch Nanomaterials as Carriers of Bioactive Molecules

3.1.4 Perspectives and Outlook

References

4 Cellulose Nanostructures and Its Application as Effective Food Packaging Systems

4.1 Introduction

4.2 Source of Cellulose

4.3 Cellulose Structure

4.4 Properties of Cellulose

4.5 Nanocellulose

4.5.1 Types of Nanocellulose

4.5.1.1 Cellulose Nanofibrils

4.5.1.2 Cellulose Nanofibers

4.5.1.3 Cellulose Nanowhiskers

4.5.1.4 Cellulose Nanoballs

4.5.1.5 Cellulose Nanocrystals

4.5.2 Properties of Nanocellulose

4.5.2.1 Mechanical Properties

4.5.2.2 Barrier Properties

4.5.2.3 Water Vapor Properties

4.5.2.4 Other Properties

4.5.3 Synthesis of Nanocellulose

4.5.3.1 Electrospinning

4.5.3.2 Extrusion

4.5.3.3 Casting

4.5.3.4 Paper Making Process Using Filtration

4.5.3.5 Coating Process

4.6 Nanocellulose as Packaging Material

4.7 Comparison of Nanocellulose and Cellulose

4.8 Disadvantages of Using Nanocellulose in Food Packaging

4.9 Conclusions

References

5 Chitosan-Based Nanoparticles and Their Applications in Food Industry

5.1 Introduction

5.2 Chitosan. 5.2.1 Chitosan Precursor: Chitin Origins

5.2.1.1 Terrestrial Sources

5.2.1.2 Aquatic Sources

5.2.1.3 Microbiological Sources

5.2.2 Chemical Composition and Properties

5.2.2.1 Structural Properties

5.2.2.2 Physicochemical Properties

5.2.2.3 Diverse Properties

5.2.3 Preparation Methods and Manufacturing

5.2.4 Chitosan Modifications

5.2.5 Overview of Chitosan Applications. 5.2.5.1 Food and Beverage Industry

5.2.5.2 Aquaculture

5.2.5.3 Pharmacy and Cosmetics

5.2.5.4 Dentistry

5.3 Nanoforms of Chitosan

5.3.1 Chitosan Nanocomposites

5.3.2 Chitosan Nanocarriers

5.3.3 Preparation Methods. 5.3.3.1 Ionic Gelation Method

5.3.3.2 Reverse Micellar Method

5.3.3.3 Emulsion-Based Solvent Evaporation Method

5.3.3.4 Coprecipitation Method

5.3.4 Characterization Techniques. 5.3.4.1 UV–Visible Spectroscopy (Spectroscopic Analysis)

5.3.4.2 Electron Microscopy (EM)

5.3.4.3 Dynamic Light Scattering (DLS)

5.3.4.4 Zeta Potential (ZP)

5.3.5 Overview of Applications

5.3.5.1 Tissue Engineering

5.3.5.2 Water Treatment

5.3.5.3 Agriculture

5.3.5.4 Drug Delivery

5.4 Chitosan-Based Nanoforms Applications in Food Industry. 5.4.1 Opportunities in Food Processing

5.4.1.1 Chitosan-Based Nanoparticles: Enhancing Food Taste and Appearance

5.4.1.2 Chitosan-Based Nanoparticles: Maintaining Nutritional Value

5.4.2 Opportunities in Food Packaging

5.4.2.1 Chitosan Nanoforms Functionality as Food Packaging Materials

5.4.2.2 Chitosan-Based Nanoparticles Toxicity and Fate in Human Body

5.5 Updated Regulations in Application of Chitosan-Based Nanoparticles in Food

References

6 Nutrients-Based Nanocarriers and Its Application in Packaging Systems

6.1 Lipid-Based Nanocarrier

6.1.1 Nanoemulsions

6.1.2 Nanoliposomes

6.1.3 Solid Lipid Nanoparticles (SLNps)

6.1.4 Nanostructured Lipid Carriers (NLCs)

6.2 Carbohydrate-Based Nanocarriers

6.2.1 Starch Nanoparticles (SNPs) and Nanocrystals (SNCs)

6.2.2 Chitosan Nanoparticles

6.2.3 Alginate Nanoparticles

6.3 Protein-Based Nanocarriers

6.4 Applications of Nanocarriers in Active and Bioactive Food Packaging

6.5 Outlooks and Perspectives

References

7 Active Packaging Systems Based on Metal and Metal Oxide Nanoparticles

List of Abbreviations

7.1 Introduction

7.2 Metal and Metal Oxide Nanoparticles Used in Active Food Packaging

7.3 Methods of Production of Metal and Metal Oxide Nanoparticles

7.3.1 Physical Synthesis

7.3.2 Chemical Synthesis

7.3.3 Biological Synthesis

7.4 Incorporation of Metal and Metal Oxide Nanoparticles into Food Packaging Materials

7.4.1 Extrusion

7.4.2 Casting

7.4.3 Physical Vapor Deposition

7.4.4 Electrospinning

7.5 Effect of Metal and Metal Oxide Nanoparticles on Active Packaging Properties

7.5.1 Structure

7.5.2 Morphology

7.5.3 Mechanical Properties

7.5.4 Barrier Properties

7.5.5 Antimicrobial Activity

7.5.5.1 Silver Nanoparticles

7.5.5.2 Zinc Oxide Nanoparticles

7.5.5.3 Copper and Copper Oxide Nanoparticles

7.5.5.4 Titanium Dioxide Nanoparticles

7.5.5.5 Gold Nanoparticles

7.5.5.6 Other Nanoparticle Systems

7.5.6 Scavenger Properties

7.5.7 Photocatalytic Properties

7.5.8 Optical Properties

7.6 Migration of Nanoparticles

7.6.1 Food Safety and Regulations

7.6.2 Regulation

7.7 Environmental Impact of Active Food Packaging Materials. 7.7.1 Biodegradability

7.7.2 Recyclability

7.7.3 Life Cycle Assessment

7.8 Conclusions and Future Trends

Acknowledgments

References

8 Fabrication of Intelligent Packaging Systems Using Nano-Indicators and Sensors

8.1 Introduction of Intelligent Packaging

8.2 Nanoparticle-Based Temperature Indicators

8.2.1 Silver Nanoparticle-Based TTI

8.2.2 Gold Nanoparticle-Based TTIs

8.2.3 Polydiacetylene/Silica Nanocomposite-Based TTI

8.2.4 Nanofiber-Based TTIs

8.3 Nanomaterial-Based Humidity Sensors

8.3.1 ZnO Nanoparticle-Based Humidity Sensors

8.3.2 Other Metallic Nanoparticle-Based Humidity Sensors

8.3.3 Polymeric Nanocomposite-Based Humidity Sensors

8.4 Nanomaterial-Based pH Indicators and Sensors

8.5 Nanoparticle-Based O2 Indicators

8.6 Nanomaterial-Based CO2 Sensors

8.7 Nanomaterial-Based Freshness Sensors

8.7.1 Freshness Sensors Based on Detection of Biogenic Amines

8.7.2 Freshness Sensors Based on Detection of Biogenic Sulfides

8.7.3 Freshness Sensors Based on Detection of ATP Degradation Products

8.8 Conclusions and Perspectives

References

9 Nanostructure-Based Edible Coatings as a Function of Food Preservation

9.1 Nanotechnology in Food Packaging: Principles and Applications

9.2 Edible Coatings

9.2.1 Chemical Characteristics of Edible Coatings

9.2.2 Methods to Apply Edible Coatings

9.2.3 Materials Used in the Edible Coatings

9.2.4 Incorporation of Nanomaterials in Edible Coatings

9.3 Safety of Nanocomposite for Application of Edible Coatings

9.4 Nanotechnology Regulation

9.5 Final Considerations and Outlook

References

10 An Overview of Higher Barrier Packaging Using Nanoadditives

10.1 Introduction

10.2 Gas and Moisture Permeability Through Polymer Packaging Materials

10.2.1 Permeability of Oxygen and Carbon Dioxide

10.2.2 Permeability of Moisture

10.3 Nanoadditives for Improving Barrier Properties

10.4 Methods to Prepare High Barrier Packaging Materials

10.4.1 Polymer Nanocomposites

10.4.2 Coating

10.4.3 Layer-by-Layer Assembly

10.5 Barrier Improvement by Reinforcement of Polymer Nanocomposites with Inorganic Nanoadditives

10.5.1 Metal and Metal Oxides Nanomaterials

10.5.1.1 Zinc

10.5.1.2 Magnesium

10.5.1.3 Silica

10.5.1.4 Titanium

10.5.1.5 Copper

10.5.1.6 Aluminum Oxide

10.5.2 Nanoclays

10.5.3 Carbon-Based Nanomaterials

10.6 Barrier Improvement of Biopolymers by Reinforcement with Organic Nanoadditives

10.6.1 Cellulose

10.6.2 Starch

10.6.3 Chitosan

10.6.4 Zein

10.6.5 Gelatin

Whey Protein Isolates

10.6.7 Soy Protein Isolates

10.7 Conclusion

References

11 Nanostructure-Based Multilayer Food Packaging Films

11.1 Introduction

11.2 Requirements of Food Packaging Systems

11.3 Multilayer Packaging Films

11.4 Structure and Functions of Multilayer Film Packaging

11.5 Nanotechnology-Based Multilayer Films

11.6 Preparation of Nano-Based Multilayer Films

11.6.1 Layer-by-Layer (LbL) Nanoassembly

11.6.2 Electrohydrodynamic Processing (EHDP)

11.6.3 Multilayer Coextrusion Technique

11.7 Practical Applications of Multilayer Films/Coatings for Packaging of Food

11.8 Conclusion and Future Outlook

References

12 Characterization Techniques for Nanostructures in Food Packaging

12.1 Introduction

12.2 Nanoparticles

12.3 Role of Nanoparticles in Packaging Applications

12.4 Nanocomposite in Food Packaging

12.5 Methods for the Development of Nanocomposites

12.6 Various Nanoparticles Employed in Packaging

12.6.1 Nanoclay

12.6.2 Titanium Dioxide

12.6.3 Zinc Oxide Nanoparticles

12.6.4 Graphene-Based Nanomaterials

12.6.5 Silver Nanoparticles

12.7 Issues Associated with the Nanoparticle Incorporation

12.8 Characterization of Nanoparticles in the Packaging Materials

12.8.1 FTIR

12.8.2 Electron Microscopic Techniques

12.8.2.1 Scanning Electron Microscopy

12.8.2.2 Transmission Electron Microscopy

12.8.3 Thermal Analysis of the Packaging Material Containing Nanoparticles

12.8.4 X-Ray Photoelectron Spectroscopy

12.8.5 XRD

12.8.6 ICPMS

12.8.7 Raman Spectroscopy

12.9 Conclusions

References

13 Biodegradability Assessment of Biopolymer-Based Films

13.1 Introduction

13.2 Commercial and Renewable Biodegradable Polymers and Plasticizers

13.2.1 Thermoplastic Starch (TPS)

13.2.2 Polylactic Acid (PLA)

13.2.3 Polyhydroxyalkanoates (PHAs)

13.2.4 Plasticizers

13.3 Biodegradation Mechanism

13.4 Biodegradation of Biopolymers with Additives

13.5 Considerations

References

14 Nanobiotechnology in Food Preservation and Molecular Perspective

14.1 Introduction

14.2 Nanobiotechnology Aspects in Food Preservation and Food Packaging

14.3 Classification of Nanomaterials and Molecular Basis of Application

14.3.1 Nanoparticles

14.3.1.1 Silver-Based Nanoparticles

14.3.1.2 Titanium Dioxide (TiO2) Nanoparticles

14.3.1.3 Zinc Oxide (ZnO) Nanoparticles

14.3.2 Nanocomposites

14.3.2.1 Cellulose-Based Nanocomposites

14.3.2.2 Chitosan-Based Nanocomposites

14.3.2.3 Protein-Derived Bionanocomposites

14.3.2.4 Polylactic Acid Nanobiocomposites

14.3.3 Nanoclays

14.3.4 Nanoemulsions

14.3.5 Nanosensors

14.3.6 Nanostructures

14.4 Nanomaterials and Active and Intelligent Food Packaging Applications. 14.4.1 Active Packaging

14.4.2 Intelligent (“Smart”) Packaging

14.5 Nanomaterials and Postharvest Quality Parameters

14.5.1 Edible Coatings and Films in Food Packaging

14.5.2 Nanomaterials and the Potential against Postharvest Disease and Ethylene Production

14.6 Regulations and Safety Aspects

14.7 Conclusions and Outlook

References

15 Environmental and Toxicological Aspects of Nanostructures in Food Packaging

15.1 Introduction

15.2 Nanoparticles in Food Packaging. 15.2.1 Nanoclay

15.2.2 Nanosilver

15.2.3 Zinc Oxide (ZnO) NP

15.2.4 Titanium Dioxide (TiO2)

15.2.5 Silicon Dioxide (SiO2)

15.3 Toxicity Measurement of Nanoparticles Used in Food Industry

15.4 Nanotoxicity

15.4.1 Silver Nanoparticles (Ag NPs)

15.4.2 Titanium Nanoparticles (TiO2 NPs)

15.4.3 Silica Nanoparticle

15.4.4 Clay Nanoparticle

15.5 Migration Issues of Nanoparticles

15.6 Environmental Impacts of Nanoparticles

15.7 Conclusion

Acknowledgments

References

Index

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Edited by

Jyotishkumar Parameswaranpillai

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Nanoparticles can be used as some smart food packaging as a food safety tracking device or to avoid falsification. BioMerieux has developed the Food Expert ID® multi detection test for nano-monitoring responses to food scares. Nanobarcodes for individual objects or pellets were produced by the US Oxonica Inc., which must be interpreted using a modified microscope for anti-counterfeiting purposes. Commercially available nanobars are made of inert metals, such as nickel, platinum gold, and silver, by electroplating into templates that define the particle diameter, which then releases stripped nanorods from templates [1–4].

Radiofrequency recognition usually involves package stickers in food and drug or pharmaceutical industries. The brands are electronic radio-frequency sensor-based mechanisms used for transferring data from a tag connected to an object and automated recognition of the object. RFID is an improvement on previous manual tracking systems or bar codes. It is extremely robust and can work at extreme temperatures and pressures and can be detected over 100 m, and many tags can be played at the same time. Nanotechnology also allows for cost-effective RFID tags in sensor packaging. Smaller, more compact nano-enabling tags may be placed on thin labels [1–3, 55]. It is a fact that when concerning public health, an evaluation of the possible migration into food of packaging components and an evaluation of their potential danger are critical for a thorough risk assessment. However, very little research has been conducted so far on the impact of nanomaterials on absorption or possible association of food contact materials with nanomaterial-dependent food components [56]. Thin film transistor is the key part of RFID tags, and it can be embedded in food packages; a researcher came upon with cheaper printable thin film transistor made up of carbon nanotube-filled inks. It can be easily printed on papers and plastics [57].

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