Оглавление
Группа авторов. Handbook of Aggregation-Induced Emission, Volume 3
Table of Contents
List of Tables
List of Illustrations
Guide
Pages
Handbook of Aggregation‐Induced Emission. Volume 3 Emerging Applications
List of Contributors
Preface to Handbook of Aggregation‐Induced Emission
Preface to Volume 3: Applications
1 AIE‐active Emitters and Their Applications in OLEDs
1.1 Introduction
1.2 Conventional Aggregation‐induced Emissive Emitters
1.2.1 Blue Aggregation‐induced Emissive Emitters
1.2.2 Green Aggregation‐induced Emissive Emitters
1.2.3 Red Aggregation‐induced Emissive Emitters
1.2.4 Aggregation‐induced Emission‐active Emitters‐Based White OLED
1.3 High Exciton Utilizing Efficient Aggregation‐induced Emissive Materials
1.3.1 Aggregation‐induced Phosphorescent Emissive Emitters
1.3.2 Aggregation‐induced Delayed Fluorescent Emitters
1.3.3 Hybridized Local and Charge Transfer Materials Aggregation‐induced Emissive Emitters
1.4 Conclusion and Outlook
Acknowledgments
References
2 Circularly Polarized Luminescence of Aggregation‐induced Emission Materials
2.1 Introduction of Circularly Polarized Luminescence
2.2 Small Organic Molecules
2.3 Macrocycles and Cages
2.4 Metal Complexes and Clusters
2.5 Supramolecular Systems
2.6 Polymers
2.7 Liquid Crystals
2.8 Conclusions and Outlook
References
3 AIE Polymer Films for Optical Sensing and Energy Harvesting
3.1 Introduction
3.2 Working Mechanism of AIEgens
3.3 AIE‐doped Polymer Films for Optical Sensing
3.3.1 Mechanochromic AIE‐doped Polymer Films
3.3.2 Thermochromic AIE‐doped Polymer Films
3.3.3 Vapochromic AIE‐doped Polymer Films
3.4 AIE‐doped Polymer Films for Energy Harvesting
3.5 Conclusions
Acknowledgments
References
4 Aggregation‐induced Electrochemiluminescence
4.1 Introduction: From Electrochemiluminescence to AI‐ECL
4.1.1 Mechanisms of AI‐ECL
4.2 Classification and Properties of AI‐ECL luminophores
4.2.1 Metal Transition Complexes
4.2.2 Polymers and Polymeric Nanoaggregates
4.2.3 Organic Molecules
4.2.4 Hybrid and Functional Materials
4.3 Applications and Outlooks
References
5 Mechanoluminescence Materials with Aggregation‐Induced Emission
5.1 Introduction
5.2 Mechanoluminescence of Organic Molecules Not Mentioned AIE
5.3 ML–AIE Materials
5.4 Summary and Outlook
Acknowledgments
References
6 Dynamic Super‐resolution Fluorescence Imaging Based on Photo‐switchable Fluorescent Spiropyran
6.1 Introduction
6.2 Materials and Methods. 6.2.1 Materials
6.2.2 The Preparation of PSt‐b‐PEO Block Copolymer Micelles
6.2.3 Super‐resolution Microscope
6.2.4 Super‐resolution Imaging
6.3 Super‐resolution Imaging of Block Copolymer Self‐assembly
6.4 Optimization of Spatial Resolution
6.5 Temporal Resolution
6.6 Dynamic Super‐resolution Imaging
6.7 Conclusion and Prospection
Acknowledgment
References
7 Visualization of Polymer Microstructures :
7.1 Introduction
7.2 Synthetic Polymers
7.2.1 Polymer Self‐assembly
7.2.2 Polymerization Reaction
7.2.3 Physical Process Visualization
7.2.3.1 Glass Transition Temperature
7.2.3.2 Solubility Parameter
7.2.3.3 Crystallization
7.2.3.4 Microphase Separation
7.2.4 Stimuli Response
7.2.4.1 Heat Response
7.2.4.2 Humidity Response
7.2.4.3 Other Response
7.3 Biological Polymers
7.3.1 DNA Synthesis
7.3.2 DNA Sequence
7.3.3 Protein Conformation
7.3.4 Protein Fibrillation
7.3.5 Other Process
7.4 Summary and Perspective
Acknowledgments
References
8 Self‐assembly of Aggregation‐induced Emission Molecules into Micelles and Vesicles with Advantageous Applications
8.1 General Background of Micelles and Vesicles
8.2 AIE Micelles. 8.2.1 General Strategies Leading to AIE Micelles
8.2.1.1 Incorporating Tetraphenylethylene (TPE) Unit into Single‐Chained Surfactants
8.2.1.2 Incorporating Tetraphenylethylene (TPE) Unit into Gemini Surfactants
8.2.1.3 Incorporating Platinum Complex into Amphiphiles
8.2.1.4 Polymeric AIE Micelles
8.2.1.4.1 Incorporating Hydrophobic AIEgens into the Hydrophilic Polymers
8.2.1.4.2 Incorporating AIEgens into Amphiphilic Block Copolymers
8.2.1.5 Coassembled AIE Micelles
8.2.2 Applications of AIE Micelles
8.2.2.1 Untargeted Bioimaging
8.2.2.2 Targeted Bioprobing
8.2.2.3 Micellar Theranostics
8.2.2.4 Sensing
8.2.2.5 Visualization of Physical Chemistry Process
8.3 AIE Vesicles
8.3.1 AIE Vesicles Based on Synthetic Amphiphiles. 8.3.1.1 Synthetic Ionic AIE Amphiphiles
8.3.1.2 Synthetic Nonionic AIE Amphiphiles
8.3.1.3 Synthetic Nonamphiphilic AIE Molecules
8.3.2 Supramolecular AIE Vesicles
8.3.2.1 AIE Vesicles Directed by Host–Guest Chemistry
8.3.2.2 AIE Vesicles Based on Electrostatic Interactions
8.3.2.3 AIE Vesicles Based on Coordination Interactions
8.3.3 Applications of AIE Vesicles. 8.3.3.1 Cell Models
8.3.3.2 Bioimaging
8.3.3.3 Theranostics
8.3.3.4 Light‐harvesting
8.3.3.5 Other Applications
8.4 Summary and Outlooks
References
9 Vortex Fluidics‐mediated Fluorescent Hydrogels with Aggregation‐induced Emission Characteristics
9.1 Introduction
9.2 Tunning the Size and Property of AIEgens, a New Approach to Create FL Hydrogels with Superior Properties
9.3 AIEgens for Characterization of Hydrogels
9.4 Conclusion
References
10 Design and Preparation of Stimuli‐responsive AIE Fluorescent Polymers‐based Probes for Cells Imaging
10.1 Introduction
10.2 Design and Preparation Strategies for AIE–SRP Probes
10.2.1 Mechanism of AIE–SRP Probes
10.2.2 Stimuli‐Responsive Polymers
10.2.2.1 Thermal‐Sensitive Polymers
10.2.2.2 pH‐Sensitive Polymers
10.2.2.3 Photo‐Sensitive polymers
10.2.2.4 Protein‐Sensitive Polymers
10.2.3 AIE Dyes
10.2.4 Combination of Stimuli‐Sensitive Polymer and AIE Dyes. 10.2.4.1 Chemical Synthesis
10.2.4.1.1 Modification of AIE Dyes
10.2.4.1.2 Structure of AIE–SRP Probes
10.2.4.1.2.1 End‐Functionalized AIE–SRP Probes
10.2.4.1.2.2 Side‐Chain AIE–SRP Probes
10.2.4.1.2.3 Main‐Chain AIE–SRP Probes
10.2.4.1.2.4 Other Polymers
10.2.4.2 Physical Blending
10.3 Application of AIE–SRP Probes
10.3.1 Thermal‐Sensitive Application
10.3.2 pH‐Sensitive Application
10.3.3 Photo‐Sensitive Application
10.3.4 Protein‐Sensitive Application
10.3.5 MultiSensitive Application
10.4 Summary and Prospect
Acknowledgements
References
11 AIE: New Strategies for Cell Imaging and Biosensing
11.1 Introduction
11.2 Cellular Imaging
11.2.1 Cytoplasma Membrane Imaging
11.2.2 Mitochondria Imaging
11.2.3 Lysosome Imaging
11.2.4 Lipid Droplet Imaging
11.2.5 Nucleus Imaging
11.3 Biosensing
11.3.1 Ions
11.3.2 Lipids and Carbohydrates
11.3.3 Amino Acids, Proteins, and Enzymes
11.3.4 Nucleic Acids and Pathogens
11.4 Conclusion
References
12 AIE-based Systems for Imaging and Image-guided Killing of Pathogens
12.1 Introduction
12.2 Bacteria Imaging Based on AIEgens
12.2.1 Broad‐spectrum Bacterial Imaging and Identification
12.2.2 Gram Positive and Gram Negative Bacteria Distinguishing
12.2.3 Long‐term Bacterial Tracking
12.2.4 Live and Dead Bacteria Discrimination Based on AIEgens
12.3 Bacteria‐targeted Imaging and Ablation Based on AIEgens
12.3.1 Surfactant‐structure Based AIEgens for Bacterial Elimination
12.3.2 Photodynamic Therapy for Bacterial Elimination
12.3.2.1 Vancomycin‐bacteria Interaction Mediated Photodynamic Ablation
12.3.2.2 Positive‐charged AIE PS for Bacteria Ablation
12.3.2.3 Metabolic Labeling‐mediated Imaging and Photodynamic Ablation
12.3.3 AIEgen with Antimicrobial Agents for Bacteria Elimination
12.3.4 Biodegradable Biocides for Bacteria Elimination
12.4 Bacterial Susceptibility Evaluation and Antibiotics Screening
12.5 Sensors for Bacterial Detection Based on AIEgens. 12.5.1 Fluorescent Sensor Arrays
12.5.2 Biosensors Constructed by Electrospun Fibers
12.5.3 Micromotors for Bacterial Detection
12.6 Conclusions and Perspectives
References
13 AIEgen‐based Trackers for Cancer Research and Regenerative Medicine
13.1 Introduction
13.2 AIEgens for Long‐term Cancer Cell Tracking. 13.2.1 AIEgen‐based Long‐term Cell Trackers with Emission in the Visible Range
13.2.2 AIEgen‐based Long‐term Cell Trackers with Near‐infrared (NIR) Emission
13.2.3 AIEgen‐based Long‐term Cell Trackers with Multiphoton Absorption
13.2.4 AIEgen‐based Hybrid or Multifunctional Systems for Cell Tracking
13.3 AIEgens for Stem Cell‐based Regenerative Medicine and Regeneration‐related Process
13.3.1 AIEgen‐based Trackers for Adipose‐derived Stem Cells
13.3.2 AIEgen‐based Trackers for Bone Marrow Stem Cells
13.3.3 AIEgen‐based Trackers for Embryo‐related Cells
13.3.4 AIEgens for Monitoring Biological Process in Regenerative Medicine
13.3.5 AIEgen‐based Nanocomplexes in Regenerative Medicine
13.4 Conclusion
Acknowledgment
References
14 AIE‐active Fluorescence Probes for Enzymes and Their Applications in Disease Theranostics
14.1 Introduction
14.2 AIE‐active Fluorescence Probes for Enzymes and Their Applications in Disease Theranostics. 14.2.1 AIE‐active Fluorescence Probes for Alkaline Phosphatase
14.2.2 AIE‐active Fluorescence Probes for Caspases
14.2.3 AIE‐active Fluorescence Probes for Cathepsin B
14.2.4 AIE‐active Fluorescence Probes for β‐Galactosidase
14.2.5 AIE‐active Fluorescence Probes for γ‐Glutamyltranspeptidase
14.2.6 AIE‐active Fluorescence Probes for Reductases
14.2.6.1 AIE‐active Fluorescence Probes for AzoR
14.2.6.2 AIE‐active Fluorescence Probes for NQO1
14.2.6.3 AIE‐active Fluorescence Probes for NTR
14.2.6.4 AIE‐active Fluorescence Probes for CYP450 Reductase
14.2.7 AIE‐active Fluorescence Probes for Chymase
14.2.8 AIE‐active Fluorescence Probes for Esterase
14.2.8.1 AIE‐active Fluorescence Probes for CaE
14.2.8.2 AIE‐active Fluorescence Probes for Lipase
14.2.9 AIE‐active Fluorescence Probes for Histone Deacetylase
14.2.10 AIE‐active Fluorescence Probes for MMP‐2
14.2.11 AIE‐active Fluorescence Probes for Furin
14.2.12 AIE‐active Fluorescence Probes for Trypsin
14.2.13 AIE‐active Fluorescence Probes for Telomerase
14.2.14 AIE‐active Fluorescence Probes for DPP‐4
14.3 Summary and Outlook
References
15 AIE Nanoprobes for NIR‐II Fluorescence In Vivo Functional Bioimaging
15.1 Introduction
15.2 NIR‐II Fluorescence Macroimaging In Vivo
15.3 NIR‐II Fluorescence Wide‐field Microscopic Imaging In Vivo
15.4 NIR‐II Fluorescence Confocal Microscopic Imaging In Vivo
15.5 Summary and Perspectives
Acknowledgments
References
16 In Vivo Phototheranostics Application of AIEgen‐based Probes
16.1 Introduction
16.2 AIE Fluorescent Probe with Photodynamic Therapy Function
16.3 AIE Photoacoustic Probe with Photothermal Therapy Function
16.4 Application of AIE Fluorescent Probe in Synergistic Therapy
16.5 AIE Fluorescent Probe with Immunotherapy Function
16.6 Conclusions and Perspectives
References
17 Red‐emissive AIEgens Based on Tetraphenylethylene for Biological Applications
17.1 Introduction
17.2 TPE‐based AIEgens with Dicyanovinyl Group. 17.2.1 Design of Red‐emissive AIEgens with Dicyanovinyl Group
17.2.2 Red‐emissive AIEgens as Photosensitizers
17.2.3 Photosensitization Enhancement of AIEgens with Dicyanovinyl Group
17.2.4 Self‐assembly of AIEgens with Dicyanovinyl Groups
17.3 Pyridinium‐based AIEgens
17.3.1 Photophysical Properties of Pyridinium‐based AIEgens
17.3.2 Bio‐sensing Applications of Pyridinium‐substituted Tetraphenylethylenes
17.3.3 Bacterial Imaging and Ablation
17.3.4 Imaging and Interrupting Mitochondria and Related Biological Processes with Pyridinium‐based AIEgens
17.4 Summary and Perspectives
References
18 Smart Luminogens for the Detection of Organic Volatile Contaminants
18.1 Introduction
18.2 Smart AIE Nanomaterials and their Sensing Applications for OVCs. 18.2.1 Organic Framework
18.2.2 Molecular Rotors
18.2.3 Other Small Molecule
18.3 Summary and Outlook
References
19 Bulky Hydrophobic Counterions for Suppressing Aggregation‐caused Quenching of Ionic Dyes in Fluorescent Nanoparticles
19.1 Introduction
19.2 Counterion Effect in Nanomaterials Based on Conventional Bright Fluorophores
19.3 Counterions and Aggregation‐induced Emission
19.3.1 Counterion Effect in AIE Dyes
19.3.2 Ionic AIE: Lighting Up Environment‐sensitive Ionic Dyes in Nanomaterials
19.4 Dye‐loaded Polymeric NPs and the Crucial Role of Bulky Counterions. 19.4.1 Principle
19.4.2 The Role of the Polymer
19.4.3 The Role of the Counterion
19.4.4 Dye Nature
19.4.5 Energy Transfer, Collective Behavior of Dyes and Biosensing
19.5 Conclusions
Acknowledgments
References
20 Fluorescent Silver Staining Based on a Fluorogenic Ag+ Probe with Aggregation‐induced Emission Properties
20.1 Introduction
20.2 Historical Background of Silver Staining
20.2.1 Silver Staining for Neurological Studies
20.2.2 Silver Staining from Neuroscience to Proteomics
20.3 Conventional Silver Staining Methods
20.4 Fluorogenic Probes for Ag+ Detection
20.5 Fluorogenic Silver Staining in Polyacrylamide Gel
20.6 Concluding Remarks
References
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