U Can: Chemistry I For Dummies

U Can: Chemistry I For Dummies
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Hren Chris. U Can: Chemistry I For Dummies

Introduction

About This Book

Foolish Assumptions

Beyond the Book

Where to Go from Here

Part I

Chapter 1. Looking at Numbers Scientifically

Using Exponential and Scientific Notation to Report Measurements

Multiplying and Dividing in Scientific Notation

Using Scientific Notation to Add and Subtract

Distinguishing between Accuracy and Precision

Identifying Significant Figures

Doing Arithmetic with Significant Figures

Chapter 2. Using and Converting Units

Familiarizing Yourself with Base Units and Metric System Prefixes

Looking at Density

Using Conversion Factors

Working with the Factor Label Method

Chapter 3. Breaking Down Atoms into Their Subatomic Particles

The Atom: Protons, Electrons, and Neutrons

A Brief History of the Atom

Deciphering Chemical Symbols: Atomic and Mass Numbers

Accounting for Isotopes Using Atomic Masses

Chapter 4. Surveying the Periodic Table of the Elements

Organizing the Periodic Table

Putting Electrons in Their Places: Electron Configurations

Predicting Properties and Valence Electrons from Periodic Trends

Forming Ions

Measuring the Amount of Energy (or Light) an Excited Electron Emits

Part II

Chapter 5. Building Bonds

Pairing Charges with Ionic Bonds

Forming Sodium Chloride

Ionic Salts

Sharing Electrons with Covalent Bonds

Drawing the Structural Formulas of Molecules

Occupying and Overlapping Molecular Orbitals

Polarity: Sharing Electrons Unevenly

Shaping Molecules: VSEPR Theory and Hybridization

Wondering About Water and Intermolecular Forces

Chapter 6. Naming Compounds and Writing Formulas

Labeling Ionic Compounds and Writing Their Formulas

Getting a Grip on Ionic Compounds with Polyatomic Ions

Naming Covalent Compounds and Writing Their Formulas

Addressing Acids

Mixing the Rules for Naming and Formula Writing

Beyond the Basics: Naming Organic Carbon Chains

Chapter 7. Understanding the Many Uses of the Mole

The Mole Conversion Factor: Avogadro’s Number

Doing Mass and Volume Mole Conversions

Determining Percent Composition

Calculating Empirical Formulas

Using Empirical Formulas to Find Molecular Formulas

Chapter 8. Getting a Grip on Chemical Equations

Translating Chemistry into Equations and Symbols

Understanding How Reactions Occur

Balancing Chemical Equations

Recognizing Reactions and Predicting Products

Canceling Spectator Ions: Net Ionic Equations

Chapter 9. Putting Stoichiometry to Work

Using Mole-Mole Conversions from Balanced Equations

Putting Moles at the Center: Conversions Involving Particles, Volumes, and Masses

Limiting Your Reagents

Counting Your Chickens after They’ve Hatched: Percent Yield Calculations

Part III

Chapter 10. Understanding States of Matter in Terms of Energy

Describing States of Matter and Their Phase Changes

Changing States of Matter

Classifying Pure Substances and Mixtures

Nice Properties You’ve Got There

Taking a Look at Energy and Temperature

Measuring Energy

Figuring Out Phase Diagrams

Chapter 11. Warming Up to Thermochemistry

Understanding the Basics of Thermodynamics

Working with Specific Heat Capacity and Calorimetry

Absorbing and Releasing Heat: Endothermic and Exothermic Reactions

Summing Heats with Hess’s Law

Chapter 12. Obeying Gas Laws

Working with the Kinetic Molecular Theory

Measuring and Converting Pressure

Boyle’s Law: Playing with Pressure and Volume

Charles’s Law and Absolute Zero: Looking at Volume and Temperature

Gay-Lussac’s Law: Examining Pressure and Temperature

Combining Pressure, Temperature, and Volume into One Law

Dealing with Amounts: Avogadro’s Law and the Ideal Gas Law

Mixing It Up with Dalton’s Law of Partial Pressures

Diffusing and Effusing with Graham’s Law

Chapter 13. Dissolving into Solutions

Seeing Different Forces at Work in Solubility

Concentrating on Molarity and Percent Solutions

Changing Concentrations by Making Dilutions

Altering Solubility with Temperature

Chapter 14. Playing Hot and Cold: Colligative Properties

Portioning Particles: Molality and Mole Fractions

Too Hot to Handle: Elevating and Calculating Boiling Points

How Low Can You Go? Depressing and Calculating Freezing Points

Determining Molecular Masses with Boiling and Freezing Points

Chapter 15. Working with Acids and Bases

Getting to Know Acids and Bases

Acids and Bases at the Atomic Level

Measuring Acidity and Basicity: pH, pOH, and KW

Dissociating with Strong and Weak Acids

Chapter 16. Achieving Neutrality with Titrations and Buffers

Using Indicators and Titration to Figure Out Molarity

Maintaining Your pH with Buffers

Measuring Salt Solubility with Ksp

Part IV

Chapter 17. Exploring Rates and Equilibrium

Measuring Rates

Focusing on Factors that Affect Rates

Measuring Equilibrium

Chapter 18. Accounting for Electrons in Redox

Oxidation Numbers: Keeping Tabs on Electrons

Balancing Redox Reactions under Acidic Conditions

Balancing Redox Reactions under Basic Conditions

Chapter 19. Galvanizing Yourself to Do Electrochemistry

Identifying Anodes and Cathodes

Calculating Electromotive Force and Standard Reduction Potentials

Coupling Current to Chemistry: Electrolytic Cells

Chapter 20. Doing Chemistry with Atomic Nuclei

Decaying Nuclei in Different Ways

Measuring Rates of Decay: Half-Lives

Making and Breaking Nuclei: Fusion and Fission

Part V

Chapter 21. Ten Tips for Acing a Chemistry Test

Don’t Cram

Figure Out What Is Probably on the Test

Allocate Your Study Time Wisely

Know the Basics

Do Example Problems

Be Confident

Spend Time with the Numbers

Know Your Resources

Eat and Sleep

Don’t Get Discouraged

Chapter 22. Ten Chemistry Formulas You Should Remember

The Combined Gas Law

Dalton’s Law of Partial Pressures

The Dilution Equation

Rate Laws

The Equilibrium Constant

Free Energy Change

Constant-Pressure Calorimetry

Hess’s Law

pH, pOH, and KW

KA and KB

Chapter 23. Ten Annoying Exceptions to Chemistry Rules

Hydrogen Isn’t an Alkali Metal

The Octet Rule Isn’t Always an Option

Some Electron Configurations Ignore the Orbital Rules

One Partner in a Coordinate Covalent Bond Giveth Electrons; the Other Taketh

All Hybridized Orbitals Are Created Equal

Use Caution When Naming Compounds with Transition Metals

You Must Memorize Polyatomic Ions

Liquid Water Is Denser Than Ice

No Gas Is Truly Ideal

Common Names for Organic Compounds Hearken Back to the Old Days

Chapter 24. Ten (Or So) Great Chemists

Amedeo Avogadro

Niels Bohr

Marie Curie

John Dalton

Michael Faraday

Antoine Lavoisier

Dmitri Mendeleev

Linus Pauling

Ernest Rutherford

Glenn Seaborg

That Third-Grader Experimenting with Vinegar and Baking Soda

Chapter 25. Ten Serendipitous Discoveries in Chemistry

Taking the Measure of Volume

Keeping Rubber Solid

Right- and Left-Handed Molecules

Finding a Shortcut to Color: Artificial Dye

Dreaming Up the Ring Structure

Discovering Radioactivity

Finding Really Slick Stuff: Teflon

Stick ’Em Up! Sticky Notes

Growing Hair

Speaking of Sweet Somethings

Glossary

About the Authors

Отрывок из книги

In many cases, when students think back to their time in high school or college chemistry, they don’t think of the class fondly (unless perhaps they’re science majors). A lot of people think chemistry is too abstract, too mathematical, too removed from their real lives.

One of the biggest challenges you encounter with chemistry is that you’re forced to work with numbers that have meaning behind them, maybe for the first time. You’re no longer simply doing a math problem with abstract values. Instead, these numbers represent physical quantities, so they’re associated with things like units, measurements, and chemical formulas.

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✔ Precision: Precision, which we discuss more in the next section, describes how close repeated measurements are to one another, regardless of how close those measurements are to the actual value. The bigger the difference between the largest and smallest values of a repeated measurement, the less precision you have.

The two most common measurements related to accuracy are error and percent error:

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