Photorefractive Materials for Dynamic Optical Recording

Photorefractive Materials for Dynamic Optical Recording
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A comprehensive and up-to-date reference on holographic recording   Photorefractive Materials for Dynamic Optical Recording offers a comprehensive overview of the physics, technology, and characterization of photorefractive materials that are used for optical recording. The author, a noted expert on the topic, offers an exploration of both transient and permanent holographic information storage methods. The text is written in clear terms with coherent explanations of the different methods that allows for easy access to the most appropriate method for a specific need. The book provides an analysis of the fundamental properties of the materials and explores the dynamic recording of a spatial electric charge distribution and the associated spatial electric field distribution. The text also includes information on the characterization of photorefractive materials using holographic and nonholographic optical methods and electrical techniques, reporting a large number of actual experimental results on a variety of materials. This important resource: Offers an in-depth source of information on the physics and technology of all relevant holographic recording methods Contains text written by a pioneer in the field—Jaime Frejlich's research defined the field of dynamic holographic recording Presents a one-stop resource that covers all phenomena and methods Includes a review of the practical applications of the technology Written for materials scientists, solid state physicists, optical physicists, physicists in industry, and engineering scientists, Photorefractive Materials for Dynamic Optical Recording offers a comprehensive resource on the topic from the groundbreaking expert in the field.

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Jaime Frejlich. Photorefractive Materials for Dynamic Optical Recording

Table of Contents

List of Tables

List of Illustrations

Guide

Pages

Photorefractive Materials for Dynamic Optical Recording. Fundamentals, Characterization, and Technology

Copyright

List of Figures

List of Tables

Preface

Acknowledgments

Part I Fundamentals

Introduction

1 Electro‐Optic Effect

1.1 Light Propagation in Crystals

1.1.1 Wave Propagation in Anisotropic Media

1.1.2 General Wave Equation

1.1.3 Index Ellipsoid

1.2 Tensorial Analysis

1.3 Electro‐Optic Effect

1.4 Perovskite Crystals

1.5 Sillenite Crystals

1.5.1 Index Ellipsoid

1.5.1.1 Index Ellipsoid with Applied Electric Field

1.5.2 Other Cubic Noncentrosymmetric Crystals

1.5.3 Lithium Niobate

1.5.4 KDP‐()

1.5.5 Bismuth Tellurium Oxide‐ (BTeO)

1.6 Concluding Remarks

2 Photoactive Centers and Photoconductivity

2.1 Photoactive Centers: Deep and Shallow Traps

2.1.1 Cadmium Telluride

2.1.2 Sillenite‐Type Crystals

2.1.2.1 Doped Sillenites

2.1.3 Lithium Niobate

2.1.4 Bismuth Telluride Oxide:

2.2 Luminescence

2.3 Photoconductivity

2.3.1 Localized States: Traps and Recombination Centers

2.3.2 Theoretical Models

2.3.2.1 One‐Center Model

2.3.2.1.1 Steady State Under Uniform Illumination: Low Irradiance

2.3.2.1.2 Steady State Under Uniform Illumination: High Irradiance

2.3.2.2 Two‐Center/One‐Charge Carrier Model

2.3.2.2.1 Steady State Under Uniform Illumination

2.3.2.3 Dark Conductivity and Dopants

2.4 Photovoltaic Effect

2.4.1 Photovoltaic Crystals

2.4.1.1 Lithium Niobate and Other Ferroelectric Crystals

2.4.1.2 Some Photovoltaic Nonferroelectric Materials

2.4.1.2.1 Bismuth Tellurium Oxide and Sillenites

2.4.2 Light Polarization‐Dependent Photovoltaic Effect

2.5 Nonlinear Photovoltaic Effect

2.5.1 Light‐Induced Absorption and Nonlinear Photovoltaic Effects

2.5.2 Deep and Shallow Centers

2.6 Light‐Induced Absorption or Photochromic Effect

2.6.1 Transmittance with Light‐Induced Absorption

2.7 Dember or Light‐Induced Schottky Effect

2.7.1 Dember and Photovoltaic Effects

Notes

Part II Holographic Recording. Introduction

3 Recording a Space‐Charge Electric Field

3.1 Index‐of‐Refraction Modulation

3.2 General Formulation

3.2.1 Rate Equations

3.2.2 Solution for Steady‐State

3.3 First Spatial Harmonic Approximation

3.3.1 Steady‐State Stationary Process

3.3.1.1 Diffraction Efficiency

3.3.1.2 Hologram Phase Shift

3.3.2 Time‐Evolution Process: Constant Modulation

3.4 Steady‐State Nonstationary Process: Running Holograms

3.4.1 Running Holograms with Hole‐Electron Competition

3.4.1.1 Mathematical Model

3.4.1.1.1 Coupled Equations

3.4.1.1.2 Neglecting Coupling

3.4.1.1.3 Steady‐State Stationary Limit

3.4.1.1.4 Hologram Erasure

3.5 Photovoltaic Materials

3.5.1 Uniform Illumination:

3.5.2 Interference Pattern of Light

3.5.2.1 Influence of Donor Density

4 Volume Hologram with Wave Mixing

4.1 Coupled Wave Theory: Fixed Grating

4.1.1 Diffraction Efficiency

4.1.2 Out of Bragg Condition

4.2 Dynamic Coupled Wave Theory

4.2.1 Combined Phase‐Amplitude Stationary Gratings

4.2.1.1 Fundamental Properties

4.2.1.2 Irradiance

4.2.2 Pure Phase Grating

4.2.2.1 Time Evolution

4.2.2.1.1 Undepleted Pump Approximation

4.2.2.1.2 Response Time with Feedback

4.2.2.2 Stationary Hologram

4.2.2.2.1 Diffraction

Unshifted holograms

Phase‐shifted holograms

4.2.2.3 Steady‐State Nonstationary Hologram with Wave‐Mixing and Bulk Absorption

4.2.2.3.1 Diffraction Efficiency

4.2.2.3.2 Output Beams Phase‐Shift

4.2.2.4 Gain and Stability in Two‐Wave Mixing

4.3 Phase Modulation

4.3.1 Phase Modulation in Dynamically Recorded Gratings

4.3.1.1 Phase Modulation in the Signal Beam

4.3.1.1.1 Unshifted Hologram

4.3.1.1.2 Shifted Hologram

4.3.1.2 Output Phase Shift

4.3.1.2.1 Exercise

4.4 Four‐Wave Mixing

4.5 Conclusions

5 Anisotropic Diffraction

5.1 Coupled‐Wave with Anisotropic Diffraction

5.2 Anisotropic Diffraction and Optical Activity

5.2.1 Diffraction Efficiency with Optical Activity,

5.2.2 Output Polarization Direction

6 Stabilized Holographic Recording. 6.1 Introduction

6.2 Mathematical Formulation

6.2.1 Stabilized Stationary Recording

6.2.1.1 Stable Equilibrium Condition

6.2.2 Stabilized Recording of Running (Nonstationary) Holograms

6.2.2.1 Stable Equilibrium Condition

6.2.2.2 Speed of the Fringe‐Locked Running Hologram

6.2.3 Self‐Stabilized Recording with Arbitrarily Selected Phase Shift

6.3 Self‐Stabilized Recording in Actual Materials

6.3.1 Self‐Stabilized Recording in Sillenites

6.3.2 Self‐Stabilized Recording in

6.3.2.1 Holographic Recording without Constraints

6.3.2.1.1 Space‐Charge Electric Field Build‐up

6.3.2.1.2 Hologram Phase Shift

6.3.2.1.3 Diffraction Efficiency with Wave Mixing

6.3.2.2 Self‐Stabilized Recording

6.3.2.2.1 Effect of Light Polarization

6.3.2.2.2 Glassplate‐Stabilized Recording

Part III Materials Characterization. Introduction

7 General Electrical and Optical Techniques

7.1 Electro‐Optic Coefficient

7.2 Light‐Induced Absorption

7.3 Dark Conductivity

7.4 Photoconductivity

7.4.1 Photoconductivity in Bulk Material

7.4.2 Alternating Current Technique

7.4.3 Wavelength‐Resolved Photoconductivity

7.4.3.1 Transverse Configuration

7.4.3.1.1 Undoped

7.4.3.1.2 V‐Doped BTO

7.4.3.2 Longitudinal Configuration

7.4.3.2.1 Undoped BTO

7.5 Photo‐Electric Conversion

7.5.1 Wavelength‐Resolved Photo‐Electric Conversion (WRPC)

7.5.1.1 Undoped BTO

7.6 Modulated Photoconductivity

7.6.1 Quantum Efficiency and Mobility‐Lifetime Product

7.7 Photo‐Electromotive‐Force Techniques (PEMF)

7.7.1 Speckle‐Photo‐Electromotive‐Force (SPEMF) Techniques

7.7.1.1 Speckle Pattern onto a Photorefractive Material: Stationary State

7.7.1.1.1 Vibrating Speckle Pattern

7.7.1.1.2 Photocurrent Components

7.7.1.1.3 Harmonic Terms

7.7.1.1.4 Experimental Setup

7.7.1.1.5 Electrodes on the Crystal Sensor

7.7.1.1.6 First Harmonic Term as a Function of

Note

8 Holographic Techniques. 8.1 Holographic Recording and Erasing

8.2 Direct Holographic Techniques

8.2.1 Energy Coupling

8.2.2 Diffraction Efficiency

8.2.2.1 Debye Length Dependence on Light Intensity

8.2.3 Holographic Sensitivity

8.2.3.1 Computing

8.3 Hologram Recording

8.4 Hologram Erasure

8.4.1 One Single Photoactive Center Involved

8.4.1.1 Bulk Absorption

8.4.2 Two (or More) Photoactive Centers (Localized States) Involved

8.4.2.1 Same Charge Carriers

8.4.2.2 Holes and Electrons on Different Photoactive Centers

8.5 Materials

8.5.1 Fe‐doped : Hologram Erasure under White Light Illumination

8.5.2 (BTO)

8.5.2.1 Undoped BTO under nm Illumination

8.5.2.2 :Pb (BTO:Pb)

8.5.2.2.1 BTO:Pb under nm Light

8.5.2.2.2 BTO:Pb Recorded with nm and nm Pre‐exposure

8.5.2.2.3 BTO:Pb Recorded with nm Illumination With and Without nm Pre‐exposure

8.5.2.3 :V (BTO:V)

8.5.2.3.1 Hologram Recording

8.5.2.3.2 Hologram Erasing

8.5.2.4 Holographic Relaxation in the Dark: Dark Conductivity

8.6 Phase Modulation Techniques

8.6.1 Holographic Sensitivity

8.6.2 Holographic Phase‐Shift Measurement

8.6.2.1 Wave‐Mixing Effects

8.6.3 Photorefractive Response Time

8.6.4 Selective Two‐Wave Mixing

8.6.4.1 Amplitude and Phase Effects in GaAs

8.6.5 Running Holograms

8.7 Holographic Photo‐Electromotive‐Force (HPEMF) Techniques

9 Self‐Stabilized Holographic Techniques

9.1 Holographic Phase Shift

9.2 Fringe‐Locked Running Holograms

9.2.1 Absorbing Materials

9.2.1.1 Low Absorption Approximation

9.2.2 Characterization of Materials

9.2.2.1 Measurements

9.2.2.1.1 Hologram Speed,

9.2.2.1.2 Diffraction Efficiency

9.2.2.2 Theoretical Fitting

9.3 Characterization of :Fe

Part IV Applications. Introduction

10 Vibrations and Deformations

10.1 Measurement of Vibration and Deformation

10.2 Experimental Setup

10.2.1 Reading of Dynamic Holograms

10.2.2 Optimization of Illumination

10.2.2.1 Target Illumination

10.2.2.2 Distribution of Light among Reference and Object Beams

10.2.3 Self‐Stabilization Feedback Loop

10.2.4 Vibrations

10.2.5 Deformation and Tilting

10.2.5.1 Applications of PEMF to Mechanical Vibration Measurements

11 Fixed Holograms. 11.1 Introduction

11.2 Fixed Holograms in

11.2.1 Simultaneous Recording and Compensation

11.2.1.1 Theory

11.2.1.2 Experiment: Simultaneous Recording and Compensating

12 Photoelectric Conversion

12.1 Photoelectric Conversion Efficiency: Dember and Photovoltaic Effects

Part V Appendix. Introduction

Appendix A Reversible Real‐Time Holograms

A.1 Naked‐Eye Detection

A.1.1 Diffraction

A.1.2 Interference

A.2 Instrumental Detection

Appendix B Diffraction Efficiency Measurement

B.1 Angular Bragg Selectivity

B.1.1 In‐Bragg Recording Beams

B.1.2 Probe Beam

B.2 Reversible Holograms

B.3 High Index‐of‐Refraction Material

Appendix C Effectively Applied Electric Field

Appendix D Physical Meaning of Some Parameters

D.1 Temperature

D.1.1 Debye Screening Length

D.1.1.1 Debye Length in Photorefractives

D.2 Diffusion and Mobility

Appendix E Photodiodes

E.1 Photovoltaic Regime

E.2 Photoconductive Regime

E.3 Operational Amplifier

Bibliography

Index

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Jaime Frejlich †

State University of Campinas

.....

Campinas‐SP, Brazil

Some practical applications including holographic real‐time measurement of out‐of‐plane mechanical vibration modes in 2D and in‐plane amplitude mechanical vibration using backscattered (“speckle” pattern) laser light are discussed in Part IV. Also, the possibility of using thin photorefractive crystal plate devices for photoelectric conversion is discussed in detail. As recording on photorefractive crystals is essentially reversible (recorded holograms may also be erased by the same light used for recording), we discuss here some fixing techniques that may even allow the production of permanent micro‐ and sub‐microscopic structures using different holographic techniques.

.....

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