Hydrogeology

Hydrogeology
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HYDROGEOLOGY Hydrogeology: Principles and Practice provides a comprehensive introduction to the study of hydrogeology to enable the reader to appreciate the significance of groundwater in meeting current and future environmental and sustainable water resource challenges. This new edition has been thoroughly updated to reflect advances in the field since 2014 and includes over 350 new references. The book presents a systematic approach to understanding groundwater starting with new insights into the distribution of groundwater in the Earth’s upper continental crust and the role of groundwater as an agent of global material and elemental fluxes. Following chapters explain the fundamental physical and chemical principles of hydrogeology, and later chapters feature groundwater field investigation techniques in the context of catchment processes, as well as chapters on groundwater quality and contaminant hydrogeology, including a section on emerging contamination from microplastic pollution. Unique features of the book are chapters on the application of environmental isotopes and noble gases in the interpretation of aquifer evolution, and a discussion of regional characteristics such as topography, compaction and variable fluid density on geological processes affecting past, present and future groundwater flow regimes. The last chapter discusses future challenges for groundwater governance and management for the long-term sustainability of groundwater resources, including the role of managed aquifer recharge, and examines the linkages between groundwater and climate change, including impacts on cold-region hydrogeology. Given the drive to net-zero carbon emissions by 2050, the interaction of groundwater in the exploitation of energy resources, including renewable resources and shale gas, is reviewed. Throughout the text, boxes and a set of colour plates drawn from the authors’ teaching and research experience are used to explain special topics and to illustrate international case studies ranging from transboundary aquifers and submarine groundwater discharge to the hydrogeochemical factors that have influenced the history of malting and brewing in Europe. The appendices provide conversion tables and useful reference material, and include review questions and exercises, with answers, to help develop the reader’s knowledge and problem-solving skills in hydrogeology. This highly informative and accessible textbook is essential reading for undergraduate and graduate students primarily in earth sciences, environmental sciences and physical geography with an interest in hydrogeology or groundwater topics. The book will also find use among practitioners in hydrogeology, soil science, civil engineering and landscape planning who are involved in environmental and resource protection issues requiring an understanding of groundwater.

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Kevin M. Hiscock. Hydrogeology

Table of Contents

List of Tables

List of Illustrations

Guide

Pages

Fresh Water to Drink

Hydrogeology. Principles and Practice

List of colour plates

List of boxes

Preface to the third edition

Preface to the second edition

Preface to the first edition

Acknowledgements

Symbols and abbreviations

About the companion website

1 Introduction. 1.1 Scope of this book

1.2 What is hydrogeology?

1.3 Early examples of groundwater exploitation

Box 1.1 The aqueducts of Rome

1.4 History of hydrogeology

Box 1.2 Groundwater on Mars?

1.5 The water cycle

1.5.1 Groundwater occurrence in the upper continental crust

1.5.2 Groundwater‐related tipping points

1.5.3 Groundwater discharge to the oceans

1.5.4 Global groundwater material and elemental fluxes

1.5.5 Human influence on the water cycle

1.6 Global groundwater resources

Box 1.3 The North‐west Sahara Aquifer System and the Ouargla Oasis, Algeria

1.6.1 Global groundwater abstraction

Box 1.4 Groundwater depletion from global irrigated crop production and trade

1.6.2 Global groundwater depletion and sea level rise

1.7 Groundwater resources in developed countries

1.7.1 Groundwater abstraction in the United Kingdom

1.7.1.1 Management and protection of groundwater resources in the United Kingdom

1.7.2 Groundwater abstraction in Europe

1.7.2.1 European Union Water Framework Directive

1.7.3 Groundwater abstraction in North America

1.7.3.1 Management and protection of groundwater resources in the United States

1.7.4 Groundwater abstraction in China

Box 1.5 Groundwater Development of the Quaternary Aquifer of the North China Plain

1.8 Groundwater resources in developing countries

Box 1.6 Groundwater resources potential in Africa

Box 1.7 Groundwater quality and depletion in the Indo‐Gangetic Basin

Further reading

References

2 Physical hydrogeology. 2.1 Introduction

2.2 Porosity

2.3 Hydraulic conductivity

2.4 Isotropy and homogeneity

2.5 Aquifers, aquitards and aquicludes

2.6 Darcy’s Law

Box 2.1 Application of Darcy’s Law to simple hydrogeological situations

2.6.1 Hydraulic properties of fractured rocks

Box 2.2 Laminar and turbulent flows

2.6.2 Karst aquifer properties

2.6.3 Sinkholes and land subsidence

2.7 Groundwater potential and hydraulic head

2.8 Interpretation of hydraulic head and groundwater conditions. 2.8.1 Groundwater flow direction

2.8.2 Water table and potentiometric surface maps

Box 2.3 Flow nets and the tangent law

Box 2.4 Potentiometric surface map of the London Basin

2.8.3 Types of groundwater conditions

Box 2.5 History of groundwater exploitation in the Chalk aquifer of the London Basin

Box 2.6 Relationship between geology, geomorphology and groundwater in the Qu’Appelle Valley, Saskatchewan

2.9 Transmissivity and storativity of confined aquifers

2.9.1 Release of water from confined aquifers

Box 2.7 Land subsidence in the Central Valley, California

Box 2.8 Land subsidence in the Tehran Plain, Iran

2.10 Transmissivity and specific yield of unconfined aquifers

2.11 Equations of groundwater flow

2.11.1 Steady‐state saturated flow

2.11.2 Transient saturated flow

2.11.3 Transient unsaturated flow

2.12 Analytical solution of one‐dimensional groundwater flow problems

Box 2.9 Examples of analytical solutions to one‐dimensional groundwater flow problems

2.13 Groundwater flow patterns

2.14 Classification of springs and intermittent streams

Box 2.10 Regional‐scale groundwater flow in the Lincolnshire Limestone aquifer, England

Box 2.11 Large‐scale groundwater flow in the Great Artesian Basin, Australia

Box 2.12 The thermal springs of Bath, England

2.15 Transboundary aquifer systems

Box 2.13 The transboundary Guarani Aquifer System

2.16 Submarine groundwater discharge

Box 2.14 Submarine groundwater discharge on the west coast of Ireland

2.17 Groundwater resources of the world

2.18 Hydrogeological environments of the United Kingdom

2.18.1 Sedimentary rocks

2.18.2 Metamorphic rocks

2.18.3 Igneous rocks

Further reading

References

3 Groundwater and geological processes. 3.1 Introduction

3.2 Geological processes driving fluid flow

3.3 Topography‐driven flow in the context of geological processes

3.4 Compaction‐driven fluid flow

Box 3.1 Determining porosity and sediment compressibility from drill core and well data

3.5 Variable‐density driven fluid flow. 3.5.1 Salinity gradients leading to variable‐density flow

Box 3.2 Compaction‐ and topography‐driven fluid flow in the Gulf of Mexico Basin

3.5.2 Hydrothermal systems driven by variable‐density flow

Box 3.3 Hot springs along permeable fault zones in the Great Basin, Western USA

3.6 Regional groundwater flow systems driven predominantly by variable‐density flow

3.6.1 Fluctuating sea‐level and its impact on the distribution of groundwater salinity in coastal areas

3.6.2 Brines in continental aquifers

3.7 Regional groundwater flow systems driven predominantly by shifting topography and stress changes

3.7.1 Mountain building and erosion

3.7.2 Impact of glaciations on regional hydrogeology

Box 3.4 Reversal of regional groundwater flow patterns forced by ice‐sheet waxing and waning in the Williston Basin, Western Canada

3.8 Coupling and relative importance of processes driving fluid flow

Further reading

References

4 Chemical hydrogeology. 4.1 Introduction

4.2 Properties of water

4.3 Chemical composition of groundwater

Box 4.1 Concentration units used in hydrochemistry

4.4 Sequence of hydrochemical evolution of groundwater

Box 4.2 Hydrochemical characteristics of British spa waters

Box 4.3 Influence of groundwater chemistry on the history of malting and brewing in Europe

Box 4.4 Hydrochemical evolution in the Floridan aquifer system

4.5 Groundwater sampling and graphical presentation of hydrochemical data

4.6 Concept of chemical equilibrium

4.6.1 Kinetic approach to chemical equilibrium

Box 4.5 Active concentration

4.6.2 Energetic approach to chemical equilibrium

4.7 Carbonate chemistry of groundwater

Box 4.6 Acid–base reactions

Box 4.7 Carbonate chemistry of the Jurassic limestones of the Cotswolds, England

Box 4.8 Solubility product and saturation index

4.8 Adsorption and ion exchange

Box 4.9 Cation exchange in the Lower Mersey Basin Permo‐Triassic sandstone aquifer, England

4.9 Redox chemistry

4.10 Groundwater in crystalline rocks

Box 4.10 Redox processes in the Lincolnshire Limestone aquifer, England

Box 4.11 Microbially mediated denitrification

Box 4.12 Hydrogeochemical characteristics of the Carnmenellis Granite, Cornwall, England

4.11 Geochemical modelling

Further reading

References

5 Environmental isotope hydrogeology. 5.1 Introduction

5.2 Stable isotope chemistry and nomenclature

5.3 Stable isotopes of water

5.4 Stable isotopes of nitrogen and sulphur

5.4.1 Nitrogen stable isotopes

5.4.2 Sulphur stable isotopes

5.5 Age dating of groundwater

5.5.1 Law of radioactive decay

5.5.2 14C dating

5.5.3 36Cl dating

5.5.4 Tritium dating

5.5.5 3H/3He dating

5.6 Noble gases

Box 5.1 Fluid flow along faults in the Lower Rhine Embayment, Germany

Further reading

References

6 Groundwater and catchment processes. 6.1 Introduction

6.2 Water balance equation

6.3 Precipitation and evapotranspiration

6.3.1 Precipitation measurement

6.3.2 Evapotranspiration measurement and estimation

6.4 Soil water and infiltration

6.4.1 Soil moisture content and soil water potential

6.4.2 Calculation of drainage and evaporation losses

6.4.3 Infiltration theory and measurement

6.5 Recharge estimation

6.5.1 Borehole hydrograph method

6.5.2 Soil moisture budget method

6.5.3 Chloride budget method

Box 6.1 Application of the chloride budget method to the Quaternary sand aquifer of Senegal, West Africa

6.5.4 Temperature profile methods

Box 6.2 Application of temperature‐depth profiles to calculate vertical specific discharge across an aquitard

6.6 Stream gauging techniques

6.6.1 Velocity area methods. 6.6.1.1 Surface floats

6.6.1.2 Current metering

6.6.1.3 Acoustic Doppler current profiler

Box 6.3 Rating curve adjustment

Example of rating curve adjustment for channel storage

Example of rating curve adjustment for channel slope

6.6.2 Dilution gauging

6.6.3 Ultrasonic, electromagnetic and integrating float methods

6.6.4 Slope‐area method

6.6.5 Weirs and flumes

6.7 Hydrograph analysis

6.7.1 Quickflow and baseflow separation

6.7.2 Unit hydrograph theory

Box 6.4 Derivation of unit hydrographs of various durations

6.8 Surface water – groundwater interaction

6.8.1 Temperature‐based methods of detection

6.8.2 Simulating river flow depletion. 6.8.2.1 Analytical solutions

6.8.2.2 Catchment resource modelling

Box 6.5 Computation of the rate and volume of stream depletion by boreholes and wells

6.8.2.3 Global‐scale surface water‐groundwater modelling

Further reading

References

7 Groundwater investigation techniques. 7.1 Introduction

7.2 Measurement and interpretation of groundwater level data

7.2.1 Water‐level measurement

7.2.2 Well and borehole design and construction methods

7.2.3 Borehole hydrographs and barometric efficiency

7.2.3.1 Groundwater level fluctuations in the Bengal Basin Aquifer

7.2.4 Construction of groundwater level contour maps

7.3 Field estimation of aquifer properties. 7.3.1 Piezometer tests

7.3.2 Pumping tests

7.3.2.1 Thiem equilibrium method

7.3.2.2 Theis non‐equilibrium method

7.3.2.3 Cooper–Jacob straight‐line method

7.3.2.4 Recovery test method

Box 7.1 Interpretation of a constant discharge pumping test and recovery test

7.3.2.5 Principle of superposition of drawdown

7.3.2.6 Leaky, unconfined and bounded aquifer systems

7.3.3 Tracer tests

Box 7.2 Dye‐tracer test in the Chepstow Block Carboniferous limestone aquifer, south‐west England

7.3.4 Downhole geophysical techniques

Box 7.3 Single borehole dilution tracer test conducted at a Chalk aquifer site

Box 7.4 Convergent radial flow tracer test conducted at a sand and gravel aquifer site

7.3.4.1 Examples of downhole geophysical logging

7.3.5 Surface geophysical techniques

7.3.5.1 Seismic refraction survey method

7.3.5.2 Electrical resistivity survey method

7.3.5.3 Electromagnetic survey method

7.3.5.4 Gravity survey method

7.3.5.5 Examples of surface geophysical surveying

7.4 Remote sensing methods

7.5 Groundwater modelling

Box 7.5 Groundwater depletion in North‐West India

Box 7.6 Groundwater modelling of the Monturaqui‐Negrillar‐Tilopozo Aquifer, Chile

Further reading

References

8 Groundwater quality and contaminant hydrogeology. 8.1 Introduction

8.2 Water quality standards

Box 8.1 The ‘hard‐water story’

8.2.1 Water hardness

8.2.2 Irrigation water quality

8.3 Transport of contaminants in groundwater

8.3.1 Transport of non‐reactive dissolved contaminants

8.3.1.1 One‐dimensional solute transport equation

8.3.2 Transport of reactive dissolved contaminants

Box 8.2 Macrodispersion caused by layered heterogeneity

Box 8.3 Controlled field experiments to investigate transport of organic solutes

Box 8.4 Groundwater contamination by heavy metals in Nassau County, New York

8.3.3 Transport of non‐aqueous phase liquids

8.3.3.1 Hydrophobic sorption of non‐polar organic compounds

8.3.4 Effects of density and heterogeneity

8.4 Sources of groundwater contamination

8.4.1 Urban and industrial contaminants

Box 8.5 Mine water pollution

8.4.2 Municipal landfill wastes

8.4.3 Faecal, domestic and cemetery wastes

8.4.4 Microplastic contamination

8.4.5 Agricultural contaminants

Box 8.6 Nitrate contamination of the Jersey bedrock aquifer

8.4.6 Saline water intrusion in coastal aquifers

Box 8.7 Saltwater intrusion in the Llobregat Delta aquifer, Spain

8.4.7 Saline water intrusion on small oceanic islands

Further reading

References

9 Groundwater pollution remediation and protection. 9.1 Introduction

9.2 Groundwater pollution remediation techniques

9.2.1 Pump‐and‐treat

Box 9.1 Pump‐and‐treat system design using capture zone type curves

Box 9.2 Jet fuel clean‐up at Heathrow International Airport

9.2.2 Permeable reactive barriers

9.2.3 Monitored natural attenuation

Box 9.3In situ permeable reactive barrier for remediation of chlorinated solvents

9.3 Groundwater pollution protection strategies in developed countries. 9.3.1 Groundwater vulnerability mapping and aquifer resource protection

Box 9.4 Monitored natural attenuation of a crude oil spill, Bemidji, Minnesota

9.3.2 Source protection zones

9.3.3 Risk assessment methods

9.3.4 Groundwater vulnerability assessment and mapping for the protection of carbonate (karstic) aquifers

9.3.5 Spatial planning and groundwater protection

Box 9.5 The Drastrup Project, north Jutland, Denmark

9.4 Groundwater protection strategies in developing countries

Box 9.6 Arsenic pollution of groundwater in southern Bangladesh

Further reading

References

10 Groundwater resources, governance and management. 10.1 Introduction

10.2 Groundwater resources schemes

10.2.1 Large‐scale groundwater development schemes

Box 10.1 Great Man‐made River Project

10.2.2 Regional‐scale groundwater development schemes

10.2.3 Managed aquifer recharge

10.2.3.1 Artificial storage and recovery schemes

Box 10.2 The North London Artificial Recharge Scheme

10.2.3.2 Riverbank filtration schemes

Box 10.3 Riverbank filtration at the Düsseldorf waterworks, River Rhine, Germany

10.2.4 Horizontal well schemes

10.3 Wetland hydrogeology

10.3.1 Impacts of groundwater exploitation on wetlands

Box 10.4 Impact of groundwater abstraction on Redgrave and Lopham Fen, East Anglia, England

Box 10.5 The Florida Everglades: a region under environmental stress

10.3.2 Hydrogeology of dune slacks

10.4 Climate change and groundwater resources

Box 10.6 History of climate change and groundwater impacts on human civilization in the Fertile Crescent

Box 10.7 Assessment of drought severity

10.4.1 Groundwater response time to climate change

10.4.2 Groundwater pumping and greenhouse gas emissions

10.4.3 Impact of climate change on cold‐region hydrogeology

10.4.4 Adaptation to climate change

Box 10.8 Climate change impacts on European groundwater resources

10.5 Groundwater and energy resources

10.5.1 Geothermal energy

10.5.2 Ground source heat pumps

10.5.3 Groundwater and shale gas exploration

10.6 Future challenges for groundwater governance and management

Further reading

References

Appendix 1 Conversion factors

Appendix 2 Properties of water in the range 0–100°C

Appendix 3 The geological timescale

Appendix 4 Symbols, atomic numbers and atomic weights

Appendix 5 Composition of seawater and rainwater. A5.1 Seawater composition

A5.2 Rainwater composition

References

Appendix 6 Values of W(u) for various values of u

Appendix 7 Values of q/Q and v/Qt corresponding to selected values of t/F for use in computing the rate and volume of stream depletion by wells and boreholes

Appendix 8 Complementary error function

Appendix 9 Drinking water quality standards and Lists I and II substances

Appendix 10 Review questions and exercises. Questions. A10.1 Hydrological cycle

A10.2 Physical hydrogeology, groundwater potential and Darcy's law

A10.3 Chemical hydrogeology

A10.4 Environmental isotope hydrogeology

A10.5 Stream gauging, infiltration measurements and groundwater recharge estimation

A10.6 Groundwater resources, pumping tests and stream depletion analysis

A10.7 Contaminant hydrogeology

Worked answers to exercises

A10.1 Hydrological cycle

A10.2 Physical hydrogeology, groundwater potential and Darcy's law

A10.3 Chemical hydrogeology

A10.4 Environmental isotope hydrogeology

A10.5 Stream gauging, infiltration measurements and groundwater recharge estimation

A10.6 Groundwater resources, pumping tests and stream depletion analysis

A10.7 Contaminant hydrogeology

References

Index

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Third Edition

Kevin M. Hiscock and Victor F. Bense

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4.11 Microbially mediated denitrification

4.12 Hydrogeochemical characteristics of the Carnmenellis Granite, Cornwall, England

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