Photovoltaics from Milliwatts to Gigawatts

Photovoltaics from Milliwatts to Gigawatts
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An essential guide through the rapid evolution of PV technology Photovoltaics from Milliwatts to Gigawatts: Understanding Market and Technology Drivers toward Terawatts covers the history of silicon based PV, from the earliest discoveries to present and future practice. Divided into 9 chapters, the book includes the following topics: Early History; The 1973 Oil crisis and the drive for alternative energies; The emergence in the 1980’s of the off grid PV market, the significant small scale PV consumer market and the establishment of a manufacturing industry; Advantages of silicon for solar cells; The evolution of PV installations; The history of the incentive programme for PV; Difficulties of alternative technologies in challenging silicon dominance; Current status of the silicon manufacturing technology and The future. Key features: An authoritative first-hand account of an emerging technology from laboratory to global significance for electricity generation by an industry expert. Provides a framework for policy makers on future trends in the PV industry. Examines the lessons learnt from the interaction of research laboratories, major industry and government. Signposts the route to future high efficiency silicon solar cells giving new researchers a background for further development. Highlights the critical success factors for the emerging alternative manufacturing technologies. An essential PV guide aimed at researchers and students in electrical engineering and physical sciences through the rapid evolution of PV technology to commercial viability and the challenges ahead for increased performance, efficiency and global deployment.

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Tim Bruton. Photovoltaics from Milliwatts to Gigawatts

Table of Contents

List of Tables

List of Illustrations

Guide

Pages

Photovoltaics from Milliwatts to Gigawatts. Understanding Market and Technology Drivers toward Terawatts

Preface

1 The Photovoltaics: The Birth of a Technology and Its First Application. 1.1 Introduction

1.2 Sunlight and Electricity. 1.2.1 The Early Years

1.2.2 The Breakthrough to Commercial Photovoltaic Cells

1.2.3 Hiatus

1.2.4 The First Successful Market: Satellites

1.3 Photovoltaics Demonstrates Success

1.3.1 First Commercial Operation

1.3.2 Continuing Research for Space

1.3.3 Solar Cell Manufacturing

1.4 Gallium Arsenide and III–V Alloys for Space

1.4.1 Single‐Junction GaAs Solar Cells

1.4.2 Multijunction Solar Cells for Space

1.5 Summary

References

2 The Beginnings of a Terrestrial Photovoltaics Industry. 2.1 Introduction

2.2 The 1973 Oil Crisis

2.3 The Way Ahead for Terrestrial Photovoltaics Technology

2.3.1 Basic Silicon Photovoltaic Manufacturing Process

2.3.2 The Flat Plate Solar Array Project

2.3.2.1 Solar‐Grade Silicon

2.3.2.2 Silicon‐Sheet Wafers and Ribbons

2.3.2.3 High‐Efficiency Solar Cells

2.3.2.4 Process Development

2.3.2.5 Engineering Sciences and Reliability

2.3.2.6 Module Encapsulation

2.3.2.7 Cost Goals

2.4 Rise of the US Photovoltaic Manufacturing Industry

2.5 Developments in Europe

2.6 The Transition in Cell Technology from Space to Terrestrial Applications

2.7 Alternatives to Silicon for Solar Cells

2.8 Summary

References

3 The Early Photovoltaic Global Market and Manufacturers. 3.1 Introduction

3.2 Off‐Grid Professional Market. 3.2.1 Navigation Aids

3.2.2 Microwave Repeater Stations

3.2.3 Cathodic Protection

3.2.4 Other Applications

3.2.5 Early Grid‐Connected Application

3.3 Off‐Grid Domestic Market

3.3.1 Solar Home Systems

3.3.2 Water Pumping

3.3.3 Consumer Electronics

3.4 Summary

References

4 Silicon Technology Development to 2010. 4.1 Introduction

4.2 Technologies Supplying the Global Market

4.3 Advantages of Silicon as a Solar Cell Material

4.3.1 Readily Available

4.3.2 Elemental Semiconductor

4.3.3 Nontoxic

4.3.4 Self‐Passivating Oxide

4.3.5 Synergy with the Global Semiconductor Industry

4.4 Silicon Solar Cell Design Features

4.5 Silicon Solar Cell Manufacturing from 1980 to 1990

4.5.1 Silicon Feedstock

4.5.2 Crystallisation

4.5.3 Wafering

4.5.4 Antireflection Coating

4.6 Solar Cell Development to 2000

4.6.1 CZ Cell Development

4.6.2 Multicrystalline Silicon Processing

4.6.3 Integration of Mono‐ and Multicrystalline Silicon Processes

4.6.4 Other Process Technology Changes

4.7 Module Technology

4.8 Summary

References

5 Evolution of Photovoltaic Systems. 5.1 Introduction

5.2 The Off‐Grid Market

5.3 The Decentralised Grid‐Connected Market

5.3.1 The Research Phase: 1974–1989

5.3.2 The Demonstration Phase: 1989–2000

5.3.3 The Commercial Phase: 2000–2019

5.3.3.1 Achievement of Grid Parity

5.3.3.2 Resolution of the Silicon Feedstock Supply

5.4 Utility‐Scale Grid‐Connected Photovoltaic Systems

5.5 Novel Applications

5.6 Summary

References

6 History of Incentives for Photovoltaics. 6.1 The Chicken and Egg Problem

6.2 Capital Subsidies on System Purchase

6.3 Feed‐in‐Tariffs

6.4 Power Purchase Agreements and Other Incentives for Large‐Scale Systems

6.5 Summary

References

7 Difficulties of Alternative Technologies to Silicon. 7.1 Introduction

7.2 Sheet Silicon Processes

7.2.1 Direct Crystallisation of Silicon Sheet

7.2.1.1 Westinghouse Dendritic Web

7.2.1.2 Edge Defined Foil Growth

7.2.1.3 String Ribbon Technology

7.2.2 Cast Silicon Sheet

7.2.2.1 Hoxan Casting Process

7.2.2.2 Ribbon Growth on Substrate

7.2.2.3 Direct Wafer

7.2.2.4 Lift‐Off Wafer Technology

7.3 Thin‐Film Solar Cell Technologies

7.3.1 Copper Sulphide

7.3.2 Amorphous Silicon

7.3.2.1 Amorphous Silicon Manufacturing

7.3.2.2 Manufacture of the Amorphous Silicon Microcrystalline Silicon Tandem Cell

7.3.3 Thin‐Film Crystalline Silicon

7.3.4 Copper Indium Gallium Diselenide (CIGS)

7.3.4.1 CIGS Manufacturing

7.3.5 Cadmium Telluride

7.3.5.1 Cadmium Telluride Manufacturing

7.3.6 Dye‐Sensitised Solar Cells

7.3.7 Polymer (Organic) Solar Cells

7.3.8 Perovskite Solar Cells

7.4 Concentrator Technologies

7.5 Summary

References

8 Current Status of Crystalline Silicon Manufacturing and Future Trends. 8.1 Introduction

8.2 Approaches to High‐Efficiency Silicon Solar Cells on p Type Silicon Wafers

8.2.1 LGBC Solar Cells

8.2.2 Selective Emitters

8.2.3 PERL and PERC Solar Cells

8.2.4 Industrial Manufacture of PERC Cells

8.2.5 Bifacial Module Technology

8.2.6 Light‐Induced Degradation

8.3 Solar Cells with n Type Silicon

8.3.1 SHJ Solar Cells

8.3.2 IBC‐SHJ Solar Cells

8.3.3 n Type IBC Cells Without Amorphous Silicon Passivation

8.4 The Future of Photovoltaic Technology: Toward Terrawatts

8.4.1 III–V Tandems on Silicon

8.4.2 Silicon Tandems Using Perovskites

8.5 Silicon Module Reliability

8.6 Summary

References

9 Lessons Learnt. 9.1 Introduction

9.2 Role of Governments

9.3 Role of the Research Community

9.4 Role of the Manufacturing Industry in Europe and the United States

9.5 Role of China as a Photovoltaics Manufacturing Base

9.6 Potential for Continued Market Growth

9.7 Future Technology Development

9.8 Final Analysis

References

Index. a

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From the rising of the sun to the place where it sets, the name of the Lord is to be praised.

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(Source Bell System Technical Journal)

Figure 1.9 Current–voltage curve for a Telstar cell at 28 °C at 100 mW/cm2[46]

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