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Of Atmospherical Air.

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The first species of air that offers itself to our consideration is that of the atmosphere, which appears to consist of a mixture of two kinds of air, of different and opposite qualities, viz, dephlogisticated and phlogisticated, in the proportion of about one third of the former to two thirds of the latter. It is by means of the former of these two ingredients that it is capable of supporting flame and animal life.

This composition of atmospherical air is proved by several substances absorbing the dephlogisticated air, and leaving the phlogisticated. All these processes have been termed phlogistic, because the effect is not produced but by substances supposed to contain phlogiston in a volatile state; and by the affinity between phlogiston and the dephlogisticated part of the air, the one is separated from the other. Of these processes are the calcination of metals, a mixture of iron-filings and sulphur, liver of sulphur, the burning of phosphorus, and the effluvia of flowers.

In some cases, however, it is not so clear that any thing is emitted from the substance that produces this effect; for water deprived of all air will absorb the dephlogisticated part of the atmospherical in preference to the phlogisticated part.

As the purity of atmospherical air, or its fitness for respiration, depends upon the proportion of the dephlogisticated air that it contains, any of the above-mentioned processes will suffice to determine it. The more any given quantity of air is diminished by any of them, the purer it was before the diminution. But this effect is produced the most quickly by a mixture of nitrous air, or firing inflammable air in it, being almost instantaneous.

In order to measure the purity of air, it is convenient to take more of the nitrous or inflammable air than is necessary to saturate the dephlogisticated air it contains. Equal quantities of each best answer the purpose. Supposing a given quantity of atmospherical air to be mixed with an equal quantity of nitrous air, and the residuum to be 1.1 measure, the proportion of dephlogisticated and phlogisticated air in it may be found by the following arithmetical operation, it being here taken for granted that one measure of pure dephlogisticated air will saturate two measures of pure nitrous air.

2.0 viz. one of each.

1.1 the residuum.

——

3)0.9 the quantity that has disappeared.

0.3 the dephlogisticated air contained

in the measure of the air examined.

And this substracted from 1 leaves .7 for the proportion of phlogisticated air in it.

Heads of Lectures on a Course of Experimental Philosophy: Particularly Including Chemistry

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