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Xiaoping Sun
Organic Mechanisms
Читать книгу Organic Mechanisms - Xiaoping Sun - Страница 1
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Table of Contents
List of Tables
List of Illustrations
Guide
Pages
Страница 7
Страница 8
Страница 9
Страница 10
ABOUT THE COMPANION WEBSITE
1 FUNDAMENTAL PRINCIPLES 1.1 REACTION MECHANISMS AND THEIR IMPORTANCE
1.2 ELEMENTARY (CONCERTED) AND STEPWISE REACTIONS
1.3 MOLECULARITY
1.3.1 Unimolecular Reactions
1.3.2 Bimolecular Reactions
1.4 KINETICS 1.4.1 Rate‐Laws for Elementary (Concerted) Reactions
Unimolecular reactions
Bimolecular reactions
1.4.2 Reactive Intermediates and the Steady‐State Assumption
1.4.3 Rate‐Laws for Stepwise Reactions
1.5 THERMODYNAMICS 1.5.1 Enthalpy, Entropy, and Free Energy
1.5.2 Reversible and Irreversible Reactions
1.5.3 Chemical Equilibrium
1.6 THE TRANSITION STATE 1.6.1 The Transition State and Activation Energy
1.6.2 The Hammond Postulate
1.6.3 The Bell–Evans–Polanyi Principle
1.7 ELECTRONIC EFFECTS AND HAMMETT EQUATION 1.7.1 Electronic Effects of Substituents
1.7.2 Hammett Equation
1.8 THE MOLECULAR ORBITAL THEORY 1.8.1 Formation of Molecular Orbitals from Atomic Orbitals
1.8.2 Molecular Orbital Diagrams
1.8.3 Resonance Stabilization
1.8.4 Frontier Molecular Orbitals
1.9 ELECTROPHILES/NUCLEOPHILES VERSUS ACIDS/BASES
1.9.1 Common Electrophiles
1.9.2 Common Nucleophiles
1.10 ISOTOPE LABELING
1.11 ENZYMES: BIOLOGICAL CATALYSTS
1.12 THE GREEN CHEMISTRY METHODOLOGY
PROBLEMS
REFERENCES
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