Читать книгу Functional Metal-Organic Frameworks - Lida Hashemi, Ali Morsali - Страница 3

1 Chapter 1Figure 1.1 Representation of CPs building blocks, synthesis and dimensionality.Figure 1.2 Depiction of MOF-5 (Zn₄O(BDC)₃) as one of the most well-known MOFs. M...Figure 1.3 Three strategies for functionalization of MOFs.Figure 1.4 Function–structure and function–application properties of functional ...Figure 1.5 Different application of functional or multi-functional MOF-based mat...Figure 1.6 Classification of organic functional groups which are applied in synt...Figure 1.7 Common coordinating functional groups in the structure of FMOFs.Figure 1.8 Functional groups as guest-interactive sites inside the structure of ...

2 Chapter 2Figure 2.1 Application of dmen-Mg₂(dobpdc) in selective capture-release of carbo...Figure 2.2 Application of [Cd(ATAIA)].4H₂O in detection of TNP. (a) Schematic re...Figure 2.3 3 dimensional framework of bio-MOF-1 along the c crystallographic dir...Figure 2.4 Application of [Zn₂(TPOM)(NH₂–BDC)₂]∙4H₂O in detection of Cr(III) ion...Figure 2.5 Application of NH₂-MIL-125 (Ti) and -MIL-125 (Ti) in oil denitrogena...Figure 2.6 Possible catalytic mechanism by amine function in Knoevenagel reactio...Figure 2.7 Application of UiO-66-NH₂ in removal of harmful gases. Removal and de...Figure 2.8 Application of UiO-66-NH₂ in aqueous media detection of NO(g). (a) Pr...Figure 2.9 Application of MIL-88(Fe)-NH₂ in photocatalytic degradation of Cr(VI)...

3 Chapter 3Figure 3.1 Application of TMU-4, TMU-5 and TMU-6 in knoevenagel reaction. (a) De...Figure 3.2 Application of RhB@TMU-5 composite in 2D detection of picric acid. (a...Figure 3.3 Application of TMU-5 in oil adsorptive denitrogenation. (a) Possible ...Figure 3.4 Representation of applied ligand, functional pores and 3D frameworks ...Figure 3.5 Photoisomeriation characterization of Cu₂(F₂AzoBDC)₂(dabco). (a) Stru...Figure 3.6 Application of IRMOF-74 in on-command cargo release of dye molecules....Figure 3.7 Application of azo-MOF in photo-responsive capture-release of Ar and ...Figure 3.8 Structural strict hindrance in [Cu₂(AzoBPDC)₂(BiPy)] and [Cu₂(NDC)₂(A...Figure 3.9 Representation of the non-functional and azo functionalized ligands a...Figure 3.10 Two ways to introduce azo-functionalized molecules into MOFs. (a) Az...Figure 3.11 Structural combination of azine and azo pillar spacers.

4 Chapter 4Figure 4.1 Resonance forms of imidazolium ring with carbene formation and metala...Figure 4.2 Representation of possible interactions between metal ion and carbeni...Figure 4.3 Applied synthesis approaches for construction of NHC–metal centers in...Figure 4.4 Application of (I-)Meim-UiO-66 in cycloaddition reaction of CO₂ with ...Figure 4.5 Application of ZnL–Pd in Sonogashira cross-coupling reaction. (a) Son...Figure 4.6 Application of In-L is selective removal of anionic dyes. (a) 3D stru...Figure 4.7 Application of Fe-MOF, Im@Fe-MOF and Im-Fe-MOF in proton conductivity...Figure 4.8 Effects of the number of imidazolium rings on the structure [29].Figure 4.9 Application of ZJU-56-0.20 in two-photon adsorption. (a) Structure of...Figure 4.10 Electron excitation process in materials by single and multiphoton a...Figure 4.11 Application of [Zn(p-CPBPY)(HBTC)]∙H₂O in UV light detection. (a) th...Figure 4.12 Charge separated surface of a MOF-framework based on 1,1’-bis(3,5-di...Figure 4.13 The ligand used for construction of zwitterionic MOF for CO₂ adsorpt...

5 Chapter 5Figure 5.1 Combination of chemical properties of N-heterocyclic azine functions.Figure 5.2 Application of ZJU-5 in acetylene storage. (a) Structure H₄PDDI ligan...Figure 5.3 Application of ZJNU-43, ZJNU-44 and ZJNU-45 in CO₂ capture. (a) Struc...Figure 5.4 Depiction of applied structures by Chen and coworkers in methane stor...Figure 5.5 The idea of synthesis of UTSA-110 with optimized porosity and high de...Figure 5.6 Application of bio-MF-11 in CO₂ capture. (a) Co(II)-adeninate-acetate...Figure 5.7 Application of Eu(III)-pdc in photoluminescence detection of Cu(II) i...Figure 5.8 Application of Zn-TATB (2) in colorimetric detection of N,N’-dimethyl...Figure 5.9 Application of TMU-34 in colorimetric detection of chloroform. (a) 3D...Figure 5.10 Application of UiO-66(dhtz) in detection of oxidizing gases. (a) Int...Figure 5.11 Application of TMU-34(-2H) in ion detection. (a) Effect of the solve...Figure 5.12 Application of [(WS₄Cu₄)I₂(dptz)₃] 3DMF in solvatochromism. (a) The ...Figure 5.13 Illustration of crystal structure of [Gd₂Mn₃(PZTC)₄(H₂O)₁₂]·5H₂O [67...Figure 5.14 Illustration of some groups of ligands with similar coordinating con...Figure 5.15 Illustration of two groups of ligands for discussion about the roles...Figure 5.16 Combination of some ligands with straight chain with carboxy or N-do...

6 Chapter 6Figure 6.1 Application of Cr₃(BTC)₂ in selective O₂ capture and release. (a) Cry...Figure 6.2. Application of Cr-BTT in selective O₂ capture and release. (a) Cryst...Figure 6.3. Application of Co-BTTri and Co-BDTriP in selective O₂ capture. (a) S...Figure 6.4. Application of TIF-1 in conjugate addition reaction. (a) Formation o...Figure 6.5. Application of Sm-MOF in excited-state intramolecular proton transfe...Figure 6.6. Synthesis, coordination mode, and formulae for 3D energetic [Cu(atrz...Figure 6.7. Application of [M(N₃)₂(atrz)]_n (M = Co 1, Cd 2) as energetic materia...Figure 6.8. Comparison of general properties of heterocyclic azoles [58].Figure 6.9. Coordination modes of heterocyclic azole N-based functions.Figure 6.10. Similarity between carboxylate and pyrazolate coordination modes in...Figure 6.11. Similarity between carboxylate and pyrazolate coordination modes in...Figure 6.12. From left to right: an alkyl−alkyl imidazolium cation; an imidazole...

7 Chapter 7Figure 7.1. Possible interaction between azoxy functionalized framework and Pb(I...Figure 7.2. Application of Eu-L2 and Tb-L2 in metal ion detection. (a) structure...Figure 7.3. Representation of oxadiazole, thiadiazole, and selenadiazole ligands...Figure 7.4. Application of Zn–H, Zn–OH and Zn–NH₂ in CO₂ adsorption. (a) Schemat...Figure 7.5. Possible host–guest interactions between CO₂ molecules and hydroxy f...Figure 7.6. The role of free hydroxy function in activation of epoxy ring in CO₂...Figure 7.7. H₂BDC based ligand for construction of MOFs based on hard-soft chemi...Figure 7.8. Structure of MOF-5, MOF-74, UiO-66 and UiO-66(SH)₂. In the UiO-66(SH...Figure 7.9. Protection of H₂BDC-(OH)₂ by acetoxy groups and deprotection of H₂BD...Figure 7.10. Application of Zr-btdc in gas adsorption. (a) Structural representa...Figure 7.11. Application of FJI-H12 in Hg(II) removal. (a) Structure of FJI-H12....Figure 7.12. Adsorption of Hg ions on thiol sites of Zr-DMBD [54].Figure 7.13. Application of ASMOF-5 in Pd(II) detection. (a) Crystal structure o...Figure 7.14. (a) Schematic illustration of the degradation of Cr(VI) by thiol-co...Figure 7.15. Photophysical properties of UiO-66-(SO₃H)₂, UiO-66-(SH)₂ and UiO-66...Figure 7.16. Application of UiO-66(SO₃H)₂ in proton conductivity. (a) Synthesis ...Figure 7.17. Application of PSM-1 and PSM-2 in proton conductivity. (a) Synthesi...Figure 7.18. Application of MIL-101-Cr-SO₃Ag in selective uptake of ethylene. (a...Figure 7.19. Application of MIL-101-SO₃H in removal of cationic dyes. Effect of ...Figure 7.20. Light-enhanced acid-catalytic reaction over MIL-101-SO₃H, in which ...Figure 7.21. Proposed acetalization reaction mechanism and determination of firs...

8 Chapter 8Figure 8.1. Coordination environment and crystal structure of isoreticular MFM-f...Figure 8.2. Application of isoreticular MFM-frameworks in gas adsorption. (a) Hi...Figure 8.3. Application of NJU-Bai49 in selective CO₂ adsorption. (a) [Sc₃(μ₃-O)...Figure 8.4. Application of NJU-Bai-17 in acetylene storage. (a) The X-ray crysta...Figure 8.5. Application of NJU-Bai-45 in methane storage. (a) Applied ligands in...Figure 8.6. Representation of the applied ligand in the structure of PCN-61 and ...Figure 8.7. Application of TMU-56 in Pb(II) removal. (a) Crystal structure of TM...Figure 8.8. Structural representation of NOTT-125 and possible interactions betw...Figure 8.9. (a) 3D framework of [Ln₂(bdpo)_1.5(DMA)₃(H₂O)]·5H₂O (b) H₄bdpo to Ln ...Figure 8.10. Application of TMU-32S-65% in Hg(II) removal. (a) L2-L ligand excha...Figure 8.11. Effect of introducing amide function in the main-chain of the MOF s...Figure 8.12. Effects of conformation of amide-function on the constructed compou...Figure 8.13. (a) Non-functional and amide-functionalized ligands for constructio...Figure 8.14. (a) Non-functional and amide-functionalized ligands for constructio...Figure 8.15. Host–guest interactions of urea. (a) Hydrogen bonding interaction b...Figure 8.16. Structural representation of [Zn₂(L1)₂(bipy)] (a) and [Zn₂(L1)₂(bpe...Figure 8.17. Structure of EDPU ligand (a), crystal structure of [Ni(EDPU)₂(H₂O)₂...Figure 8.18. Structure, applied ligands in synthesis of NU-601 (a) Application o...Figure 8.19. Application of urea decorated MOFs as hydrogen bond donor organocat...Figure 8.20. Effects of urea function in the main-chain on the structure of MOFs...Figure 8.21. Representation of urea and triazole functionalized ligands for cons...Figure 8.22. Structural change of [Zn₄O(L)₃(DMF)₂]_n after activation by CS₂ [86]...Figure 8.23. Significantly different characteristics between urea and squaramide...Figure 8.24. Application of UiO-67-Squar/bpdc in Friedel–Crafts reaction.Figure 8.25. Comparison between carbonyl based functions.

9 Chapter 9Figure 9.1 Application of Tb-BCB in detection of small organic molecules. (a) St...Figure 9.2 Application of Cu-cdip in gas adsorption. (a) Structure of the H₄cdip...Figure 9.3 Application of DUT-122 in organic solvent sensing. (a) Structure of D...Figure 9.4 Application of Eu-fdc in ratiometric temperature sensing. (a) Schemat...Figure 9.5 Carbonylation of sp³ atoms for construction of rigid and polar carbon...Figure 9.6 Coordination modes of the carboxylate ligands [10].Figure 9.7 Synthesis of [CuCl(BNA)₂]∙Cl(H₂O)₄through control over pH. (a) Struct...Figure 9.8 Post-synthesis CO₂insertion into the structure of UiO-67(dcppy). (a) ...Figure 9.9 Molecular Representations of NU-1000 (top) and Depictions of Solvent-...Figure 9.10 Synthesis of UiO-66-ox by Hupp and coworkers through solvent assiste...Figure 9.11 Application of UiO-66(COOH)₂in CO₂adsorption. (a) The UiO-66(Zr)-(CO...Figure 9.12 Inorganic nodes of some MOFs based on terphthalic acid linker. Combi...Figure 9.13 Structure of imide functionalized aromatic cores.Figure 9.15 Application of FJU-101 in methane storage. Nanosized cage (a) and 3D...Figure 9.16 Application of 1 and 1−Li⁺ in H₂ storage. (a) Crystal structure of 1...