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Cheanyeh Cheng
Enzyme-Based Organic Synthesis
Читать книгу Enzyme-Based Organic Synthesis - Cheanyeh Cheng - Страница 1
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Страница 1
Table of Contents
List of Tables
List of Illustrations
Guide
Pages
Страница 7
Страница 8
Страница 9
Страница 10
1 Introduction 1.1 Discovery and Nature of Enzyme
1.2 Enzyme Structure and Catalytic Function 1.2.1 Enzyme Structure
1.2.2 Catalytic Function
1.3 Cofactors and Coenzymes
1.4 Molecular Recognition and Enzyme Specificity
1.4.1 Substrate Specificity
1.4.2 Regiospecificity
1.4.3 Stereospecificity
1.5 Enzyme Classes and Nomenclature
1.6 Enzyme and Green Chemistry
1.7 The Winner of Year 2010: Greener Manufacturing of Sitagliptin Enabled by an Evolved Transaminase
1.8 The Winner of Year 2009: A Solvent‐Free Biocatalytic Process for Cosmetic and Personal Care Ingredients
References
2 Organic Synthesis with Oxidoreductases 2.1 Oxidation Reactions
2.1.1 Oxidation of Alcohols and Aldehydes
2.1.2 Hydroxylation of Alkanes
2.1.3 Hydroxylation of Aromatic Compounds
2.1.4 Dihydroxylation of Aromatic Compounds
2.1.5 Epoxidation
2.1.6 Sulfoxidation Reactions
2.1.7 Baeyer–Villiger Reactions
2.1.8 Peroxidation Reactions
2.2 Reduction Reactions 2.2.1 Reduction of Aldehydes and Ketones
2.2.2 Reduction of C═C Bonds
References
3 Organic Synthesis with Transferases 3.1 Transamination with Aminotransferases
3.2 Glycosyl‐transfer with glycosyltransferase
3.3 Phosphorylation with Kinases
3.4 Acetyl Group Transfer with Acetyltransferase
References
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