Читать книгу Quantum Mechanics, Volume 3 - Claude Cohen-Tannoudji - Страница 57
2-a. Fermion distribution function
ОглавлениеAs the occupation number only takes the values 0 and 1, the first bracket in expression (17) is equal to [e–β(ei – μ)]; as for the other modes (k ≠ i) contribution, in the second bracket, it has already been computed when we determined the partition function. We therefore obtain:
(18)
Multiplying both the numerator and denominator by 1 + e–β (ei – μ) allows reconstructing the function Z in the numerator, and, after simplification by Z, we get:
We find again the Fermi-Dirac distribution function (§ 1-b of Complement CXIV):
(20)
This distribution function gives the average population of each individual state |ui〉 with energy e; its value is always less than 1, as expected for fermions.
The average value at thermal equilibrium of any one-particle operator is now readily computed by using (19) in relation (15).