Читать книгу Quantum Mechanics, Volume 3 - Claude Cohen-Tannoudji - Страница 79
1-b. Choice of the variational ket (or trial ket)
ОглавлениеLet us choose an arbitrary normalized quantum state |θ〉:
and call the associated creation operator. The N-particle variational kets we consider are defined by the family of all the kets that can be written as:
where |θ〉 can vary, only constrained by (6). Consider a basis {|θk〉} of the individual state space whose first vector is |θ1〉 = |θ〉. Relation (A-17) of Chapter XV shows that this ket is simply a Fock state whose only non-zero occupation number is the first one:
An assembly of bosons that occupy the same individual state is called a “Bose-Einstein condensate”.
Relation (8) shows that the kets are normalized to 1. We are going to vary |θ〉, and therefore , so as to minimize the average energy:
(9)