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Table of Contents

Оглавление

Cover

Title Page

Copyright

Preface

1 Halogen Bonding: An Introduction 1.1 Introduction 1.2 Historical Perspective 1.3 Crystallographic Studies 1.4 Computational Studies 1.5 Materials 1.6 Conclusion Acknowledgments References Note

2 Thermodynamics of Halogen Bonding in Solution 2.1 Introduction 2.2 Molecular Halogens and Interhalogens 2.3 N‐Halo and N‐Halonium Compounds 2.4 Haloalkynes 2.5 Haloarenes 2.6 Halogenated Heterocycles 2.7 Haloalkanes and Haloalkenes 2.8 Summary and Outlook References

3 Recognition with Macrocycles and Interlocked Systems 3.1 Introduction 3.2 Recognition by XB Macrocyclic Hosts 3.3 XB Interlocked Hosts for Recognition and Sensing 3.4 Foldamer Architectures for Recognition 3.5 Summary and Conclusions References

4 The Three‐Center Halogen Bond 4.1 Introduction 4.2 Three‐Center Halogen Bond 4.3 Synthetic Applications 4.4 Three‐Center Halogen Bonds in Supramolecular Chemistry 4.5 Summary and Conclusions References

5 Spectroscopy of Halogen Bonding in Solution 5.1 Introduction 5.2 Vibrational Spectroscopy 5.3 UV–vis Spectroscopy 5.4 NMR Spectroscopy 5.5 ESR Spectroscopy 5.6 Summary and Conclusions Acknowledgments References

10  6 Anion Transport in Lipid Bilayer Membranes Using Halogen Bonds 6.1 Introduction 6.2 Macrocyclic Systems 6.3 Small Molecules 6.4 Halogen Bonding Ion Channels 6.5 Discussion and Perspectives 6.6 Summary Acknowledgments References

11  7 Catalysis by Molecular Iodine 7.1 Introduction 7.2 Proposed Activation Mechanisms 7.3 Applications in Catalysis 7.4 Summary and Conclusions References

12  8 Halogen Bonding in Organocatalysis 8.1 Introduction 8.2 Organic Reactions Involving XB as Primary Interaction 8.3 Reactions Involving XB as Secondary Interaction 8.4 Conclusion References

13  9 Halogen Bonding in Electrochemistry 9.1 Introduction 9.2 Methods 9.3 Electrochemistry for Crystal Engineering: Mixed Valence Crystal Structures 9.4 Redox Switching in Homogeneous Solution 9.5 Interfacial Halogen Bonding 9.6 Activation of Covalent Bonds 9.7 Conclusions References

14  10 Halogen Bonds in Biomolecular Engineering 10.1 Introduction to Biomolecular Engineering and Halogen Bonds 10.2 Halogen Bonds in Nucleic Acids 10.3 Halogen Bonds in Peptides and Proteins 10.4 Conclusions and Perspectives Acknowledgments References

15  11 The Chalcogen Bond in Solution: Synthesis, Catalysis and Molecular Recognition 11.1 Introduction 11.2 Chalcogen Bonding in Synthesis 11.3 Chalcogen Bonding in Catalysis 11.4 Chalcogen Bonding in Molecular Recognition 11.5 Conclusions Acknowledgments References

16  Index

17  End User License Agreement

Halogen Bonding in Solution

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