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Methodologies in Amine Synthesis
Читать книгу Methodologies in Amine Synthesis - Группа авторов - Страница 1
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Страница 1
Table of Contents
List of Tables
List of Illustrations
Guide
Pages
Methodologies in Amine Synthesis Challenges and Applications
Страница 8
Preface
1 Substitution‐type Electrophilic Amination Using Hydroxylamine‐Derived Reagents
1.1 Introduction
1.2 Cu‐Catalyzed Reactions
1.3 Electrophilic Amination Reactions Catalyzed by Other Transition Metals
1.4 Electrophilic Amination with Hydroxylamine‐derived Metallanitrenes
1.5 Transition‐Metal‐Free Electrophilic Amination Reactions
1.6 Conclusion
References
2 Remote Functionalizations Using Nitrogen Radicals in H‐Atom Transfer (HAT) Reactions
2.1 Introduction
2.2 Intramolecular 1,5‐H‐Atom Transfer (1,5‐HAT)
2.3 Photoinduced Strategies 2.3.1 Reductive Strategies
2.3.1.1 1,5‐HAT via Iminyl Radicals
2.3.1.2 1,5‐HAT via Amidyl and Sulfamidyl Radicals
2.3.2 Oxidative Strategies 2.3.2.1 1,5‐HAT via Iminyl Radicals
2.3.2.2 1,5‐HAT via Amidyl and Sulfamidyl Radicals
2.3.3 Photoinduced Bond Homolysis
2.4 Thermal Strategies
2.5 Summary and Conclusions
References
3 Radical‐Based C—N Bond Formation in Photo/Electrochemistry
3.1 Introduction
3.2 C—N Bond Formation via N‐radical Species Addition
3.2.1 Radical Addition to C—C Double/Triple Bonds 3.2.1.1 Amidyl Radical Addition
3.2.1.2 Hydrazonyl Radical Addition
3.2.1.3 Aminium Radical Cation Addition
3.2.2 Radical Species Addition to Aromatic Rings
3.3 Amination via N‐atom Nucleophilic Addition
3.3.1 Aromatic C(sp
2
)—H Bond Amination
3.3.2 Olefinic C(sp
2
)—H Bond Amination
3.3.3 Activated C(sp
3
)—H Bond Amination
3.3.3.1 Benzylic C(sp
3
)—H Bond Amination
3.3.3.2 N‐α‐C(sp
3
)—H Bond Amination
3.4 Amination via Radical Cross‐coupling
3.4.1 Aryl C(sp
2
)—N Bond Formation via Radical Cross‐coupling
3.4.1.1 Aryl C(sp
2
)—N Bond Formation Using Diarylamines
3.4.1.2 Aryl C(sp
2
)—N Bond Formation Using Azoles
3.4.2 Other C—N Bond Formation via Radical Cross‐coupling
3.5 Summary and Conclusions
References
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