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3.2.3.2 Nanoclusters as Catalysts
ОглавлениеMetal nanoclusters have also been found to be good catalysts. Metal clusters retain their activity for extended periods of time and over a range of substrates. Gold nanoclusters have also exhibited catalytic activity for the low temperature oxidation of carbon monoxide, even though bulk gold is inactive. Nanoparticles supported on polymers have been found to catalyze hydrogenations and carbon-carbon coupling reactions. Colloids of bi- and tri-metallic nanoclusters have been shown to be active and selective catalysts in the Suzuki cross-coupling, Pauson-Khand, and hydrogenation reactions.