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Recent Advances in Polyphenol Research
Читать книгу Recent Advances in Polyphenol Research - Группа авторов - Страница 1
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Страница 1
Table of Contents
List of Tables
List of Illustrations
Guide
Pages
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1 Achieving Complexity at the Bottom Through the Flavylium Cation‐Based Multistate : A Comprehensive Kinetic and Thermodynamic Study
1.1 Introduction
1.2 Flavylium Cation as a Metamorphosis Generator
1.3 Extending the Multistate of Anthocyanins and Related Compounds to the Basic Region
1.3.1 Reverse pH Jumps from Pseudo‐equilibrium Followed by Stopped Flow UV‐visible Spectroscopy
1.3.2 Reverse pH Jumps from Equilibrium
1.4 The Kinetic Processes
1.4.1 Heavenly Blue Anthocyanin
1.4.2 2‐Hydroxyflavylium Derivatives and Flavanones
1.4.3 6,8 Rearrangements
1.4.3.1 Unveiling the 6,8 Rearrangement Through Host‐Guest Complexation
1.5 Conclusions and Perspectives
References
Endnotes
2 Proanthocyanidin Oligomers with Doubly Linked (A‐Type) Interflavan Connectivity : Structure and Synthesis
2.1 Introduction
2.2 Structure
2.3 Synthetic Studies
2.3.1 Hypothetical Biosynthetic Routes
2.3.2 Retrosynthesis
2.3.3 Oxidative Conversion from B‐type PAs (Route I)
2.3.4 Approaches via an Acyclic Precursor (Route II)
2.3.5 Annulation Approach (Route III)
2.3.6 Total Synthesis
2.3.6.1 Synthesis of Diinsininol Aglycon (45)
2.3.6.2 Synthesis of Procyanidin A2 (3)
2.3.6.3 Synthesis of (+)‐Cinnamtannin B1 (62)
2.3.6.4 Synthesis of Selligueain A (63)
2.3.6.5 Synthesis of Procyanidin A2 (3)
2.4 Conclusion
References
3 Answering the Call of the Wild: Polyphenols in Traditional Therapeutic Practice
3.1 Introduction
3.2 The Wildcrafting Tradition
3.3 How Wildcrafted Edible Plants Differ from Agricultural Commodities
3.4 Animal Mimickry/Zoopharmacognosy
3.5 Probing the Mechanisms Behind Polyphenol‐rich Traditional Medicines Bioactivity
3.5.1 Phlorotannins in Alaskan Seaweeds/Marine Algae
3.5.2 Isolating Phytoactive Principles from the Mediterranean Region
3.5.3 Drug Discovery in Cooperation with Traditional Healers in Botswana
3.5.4 Antidiabetic Mechanisms of Wild Tundra Berries
3.6 Commercialization Prospects for Wildcrafted Polyphenol‐rich Plants
3.7 Acknowledgements
References
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