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CHAP. II.
DIVISIBILITY—POROSITY—DENSITY—COMPRESSIBILITY—ELASTICITY—DILATABILITY.

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(10.) Besides the qualities of magnitude and impenetrability, there are several other general properties of bodies contemplated in mechanical philosophy, and to which we shall have frequent occasion to refer. Those which we shall notice in the present chapter are,

1. Divisibility.

2. Porosity—Density.

3. Compressibility—Elasticity.

4. Dilatability.

(11.) Divisibility.—Observation and experience prove that all bodies of sensible magnitude, even the most solid, consist of parts which are separable. To the practical subdivision of matter there seems to be no assignable limit. Numerous examples of the division of matter, to a degree almost exceeding belief, may be found in experimental enquiries instituted in physical science; the useful arts furnish many instances not less striking; but, perhaps, the most conspicuous proofs which can be produced, of the extreme minuteness of which the parts of matter are susceptible, arise from the consideration of certain parts of the organised world.

(12.) The relative places of stars in the heavens, as seen in the field of view of a telescope, are marked by fine lines of wire placed before the eye-glass, and which cross each other at right angles. The stars appearing in the telescope as mere lucid points without sensible magnitude, it is necessary that the wires which mark their places should have a corresponding tenuity. But these wires being magnified by the eye-glass would have an apparent thickness, which would render them inapplicable to this purpose, unless their real dimensions were of a most uncommon degree of minuteness. To obtain wire for this purpose, Dr. Wollaston invented the following process:—A piece of fine platinum wire, ab, is extended along the axis of a cylindrical mould, AB, fig.1. Into this mould, at A, molten silver is poured. Since the heat necessary for the fusion of platinum is much greater than that which retains silver in the liquid form, the wire ab remains solid, while the mould AB is filled with the silver. When the metal has become solid by being cooled, and has been removed from the mould, a cylindrical bar of silver is obtained, having a platinum wire in its axis. This bar is then wire-drawn, by forcing it successively through holes C, D, E, F, G, H, diminishing in magnitude, the first hole being a little less than the wire at the beginning of the process. By these means the platinum ab is wire-drawn at the same time and in the same proportion with the silver, so that whatever be the original proportion of the thickness of the wire ab to that of the mould AB, the same will be the proportion of the platinum wire to the whole at the several thicknesses C, D, &c. If we suppose the mould AB to be ten times the thickness of the wire ab, then the silver wire, throughout the whole process, will be ten times the thickness of the platinum wire which it includes within it. The silver wire may be drawn to a thickness not exceeding the 300th of an inch. The platinum will thus not exceed the 3000th of an inch. The wire is then dipped in nitric acid, which dissolves the silver, but leaves the platinum solid. By this method Dr. Wollaston succeeded in obtaining wire, the diameter of which did not exceed the 18000th of an inch. A quantity of this wire, equal in bulk to a common die used in games of chance, would extend from Paris to Rome.

(13.) Newton succeeded in determining the thickness of very thin laminæ of transparent substances by observing the colours which they reflect. A soap bubble is a thin shell of water, and is observed to reflect different colours from different parts of its surface. Immediately before the bubble bursts, a black spot may be observed near the top. At this part the thickness has been proved not to exceed the 2,500,000th of an inch.

The transparent wings of certain insects are so attenuated in their structure that 50,000 of them placed over each other would not form a pile a quarter of an inch in height.

(14.) In the manufacture of embroidery it is necessary to obtain very fine gilt silver threads. To accomplish this, a cylindrical bar of silver, weighing 360 ounces, is covered with about two ounces of gold. This gilt bar is then wire-drawn, as in the first example, until it is reduced to a thread so fine that 3400 feet of it weigh less than an ounce. The wire is then flattened by passing it between rollers under a severe pressure, a process which increases its length, so that about 4000 feet shall weigh one ounce. Hence, one foot will weigh the 4000th part of an ounce. The proportion of the gold to the silver in the original bar was that of 2 to 360, or 1 to 180. Since the same proportion is preserved after the bar has been wire-drawn, it follows that the quantity of gold which covers one foot of the fine wire is the 180th part of the 4000th of an ounce; that is the 720,000th part of an ounce.

The quantity of gold which covers one inch of this wire will be twelve times less than that which covers one foot. Hence, this quantity will be the 8,640,000th part of an ounce. If this inch be again divided into 100 equal parts, every part will be distinctly visible without the aid of microscopes. The gold which covers this small but visible portion is the 864,000,000th part of an ounce. But we may proceed even further; this portion of the wire may be viewed by a microscope which magnifies 500 times, so that the 500th part of it will thus become visible. In this manner, therefore, an ounce of gold may be divided into 432,000,000,000 visible parts, each of which will possess all the characters and qualities found in the largest masses of the metal. It will retain its solidity, texture, and colour; it will resist the same agents, and enter into combination with the same substances. If the gilt wire be dipped in nitric acid, the silver within the coating will be dissolved, but the hollow tube of gold which surrounded it will still cohere and remain suspended.

(15.) The organised world offers still more remarkable examples of the inconceivable subtilty of matter.

The blood which flows in the veins of animals is not, as it seems, an uniformly red liquid. It consists of flat discs of a red colour, floating in a transparent fluid called serum. In different species these discs differ both in figure and in magnitude. In man and all animals which suckle their young, they are perfectly circular or nearly so. In birds, reptiles, and fishes, they are of oval form. In the human species, the diameter of these discs is about the 3500th of an inch. Hence it follows, that in a drop of blood which would remain suspended from the point of a fine needle, there must be about 3,000,000 of such discs.

Small as these discs are, the animal kingdom presents beings whose whole bodies are still more minute. Animalcules have been discovered, whose magnitude is such, that a million of them do not exceed the bulk of a grain of sand; and yet each of these creatures is composed of members as curiously organised as those of the largest species; they have life and spontaneous motion, and are endued with sense and instinct. In the liquids in which they live, they are observed to move with astonishing speed and activity; nor are their motions blind and fortuitous, but evidently governed by choice, and directed to an end. They use food and drink, from which they derive nutrition, and are therefore furnished with a digestive apparatus. They have great muscular power, and are furnished with limbs and muscles of strength and flexibility. They are susceptible of the same appetites, and obnoxious to the same passions, the gratification of which is attended with the same results as in our own species. Spallanzani observes, that certain animalcules devour others so voraciously, that they fatten and become indolent and sluggish by over-feeding. After a meal of this kind, if they be confined in distilled water, so as to be deprived of all food, their condition becomes reduced; they regain their spirit and activity, and amuse themselves in the pursuit of the more minute animals, which are supplied to them; they swallow these without depriving them of life, for, by the aid of the microscope, the one has been observed moving within the body of the other. These singular appearances are not matters of idle and curious observation. They lead us to enquire what parts are necessary to produce such results. Must we not conclude that these creatures have heart, arteries, veins, muscles, sinews, tendons, nerves, circulating fluids, and all the concomitant apparatus of a living organised body? And if so, how inconceivably minute must those parts be! If a globule of their blood bears the same proportion to their whole bulk as a globule of our blood bears to our magnitude, what powers of calculation can give an adequate notion of its minuteness?

(16.) These and many other phenomena observed in the immediate productions of nature, or developed by mechanical and chemical processes, prove that the materials of which bodies are formed are susceptible of minuteness which infinitely exceeds the powers of sensible observation, even when those powers have been extended by all the aids of science. Shall we then conclude that matter is infinitely divisible, and that there are no original constituent atoms of determinate magnitude and figure at which all subdivision must cease? Such an inference would be unwarranted, even had we no other means of judging the question, except those of direct observation; for it would be imposing that limit on the works of nature which she has placed upon our powers of observing them. Aided by reason, however, and a due consideration of certain phenomena which come within our immediate powers of observation, we are frequently able to determine other phenomena which are beyond those powers. The diurnal motion of the earth is not perceived by us, because all things around us participate in it, preserve their relative position, and appear to be at rest. But reason tells us that such a motion must produce the alternations of day and night, and the rising and setting of all the heavenly bodies; appearances which are plainly observable, and which betray the cause from which they arise. Again, we cannot place ourselves at a distance from the earth, and behold the axis on which it revolves, and observe its peculiar obliquity to the orbit in which the earth moves; but we see and feel the vicissitudes of the seasons, an effect which is the immediate consequence of that inclination, and by which we are able to detect it.

(17.) So it is in the present case. Although we are unable by direct observation to prove the existence of constituent material atoms of determinate figure, yet there are many observable phenomena which render their existence in the highest degree probable, if not morally certain. The most remarkable of this class of effects is observed in the crystallisation of salts. When salt is dissolved in a sufficient quantity of pure water, it mixes with the water in such a manner as wholly to disappear to the sight and touch, the mixture being one uniform transparent liquid like the water itself, before its union with the salt. The presence of the salt in the water may, however, be ascertained by weighing the mixture, which will be found to exceed the original weight of the water by the exact amount of the weight of the salt. It is a well-known fact, that a certain degree of heat will convert water into vapour, and that the same degree of heat does not produce the same effect upon salt. The mixture of salt and water being exposed to this temperature, the water will gradually evaporate, disengaging itself from the salt with which it has been combined. When so much of the water has evaporated, that what remains is insufficient to keep in solution the whole of the salt, a part of the latter thus disengaged from the water will return to the solid state. The saline constituent will not in this case collect in irregular solid molecules; but will exhibit itself in particles of regular figure, terminated by plane surfaces, the figure being always the same for the same species of salt, but different for different species. These particles are called crystals. There are several circumstances in the formation of these crystals which merit attention.

If one of them be detached from the others, and the progress of its formation observed, it will be found gradually to increase, always preserving its original figure. Since its increase must be caused by the continued accession of saline molecules, disengaged by the evaporation of the water, it follows that these molecules must be so formed, that by attaching themselves successively to the crystal, they maintain the regularity of its bounding planes, and preserve their mutual inclinations unvaried.

Suppose a crystal to be taken from the liquid during the process of crystallisation, and a piece broken from it so as to destroy the regularity of its form: if the crystal thus broken be restored to the liquid, it will be observed gradually to resume its regular form, the atoms of salt successively dismissed by the vaporising water filling up the irregular cavities produced by the fracture. Hence it follows, that the saline particles which compose the surface of the crystal, and those which form the interior of its mass, are similar, and exert similar attractions on the atoms disengaged by the water.

All these details of the process of crystallisation are very evident indications of a determinate figure in the ultimate atoms of the substances which are crystallised. But besides the substances which are thus reduced by art to the form of crystals, there are larger classes which naturally exist in that state. There are certain planes, called planes of cleavage, in the directions of which natural crystals are easily divided. These planes, in substances of the same kind, always have the same relative position, but differ in different substances. The surfaces of the planes of cleavage are quite invisible before the crystal is divided; but when the parts are separated, these surfaces exhibit a most intense polish, which no effort of art can equal.

We may conceive crystallised substances to be regular mechanical structures formed of atoms of a certain figure, on which the figure of the whole structure must depend. The planes of cleavage are parallel to the sides of the constituent atoms; and their directions, therefore, form so many conditions for the determination of their figure. The shape of the atoms being thus determined, it is not difficult to assign all the various ways in which they may be arranged, so as to produce figures which are accordingly found to correspond with the various forms of crystals of the same substance.

(18.) When these phenomena are duly considered and compared, little doubt can remain that all substances susceptible of crystallisation, consist of atoms of determinate figure. This is the case with all solid bodies whatever, which have come under scientific observation, for they have been severally found in or reduced to a crystallised form. Liquids crystallise in freezing, and if aëriform fluids could by any means be reduced to the solid form, they would probably also manifest the same effect. Hence it appears reasonable to presume, that all bodies are composed of atoms; that the different qualities with which we find different substances endued, depend on the magnitude and figure of these atoms; that these atoms are indestructible and immutable by any natural process, for we find the qualities which depend on them unchangeably the same under all the influences to which they have been submitted since their creation; that these atoms are so minute in their magnitude, that they cannot be observed by any means which human art has yet contrived; but still that magnitudes can be assigned which they do not exceed.

It is proper, however, to observe here, that the various theorems of mechanical science do not rest upon any hypothesis concerning these atoms as a basis. These theorems are not inferred from this or any other supposition, and therefore their truth would not be in anywise disturbed, even though it should be established that matter is physically divisible in infinitum. The basis of mechanical science is observed facts, and, since the reasoning is demonstrative, the conclusions have the same degree of certainty as the facts from which they are deduced.

(19.) Porosity.—The volume of a body is the quantity of space included within its external surfaces. The mass of a body, is the collection of atoms or material particles of which it consists. Two atoms or particles are said to be in contact, when they have approached each other until arrested by their mutual impenetrability. If the component particles of a body were in contact, the volume would be completely occupied by the mass. But this is not the case. We shall presently prove, that the component particles of no known substance are in absolute contact. Hence it follows that the volume consists partly of material particles, and partly of interstitial spaces, which spaces are either absolutely void and empty, or filled by some substance of a different kind from the body in question. These interstitial spaces are called pores.

In bodies which are constituted uniformly throughout their entire dimensions, the component particles and the pores are uniformly distributed through the volume; that is, a given space in one part of the volume will contain the same quantity of matter and the same quantity of pores as an equal space in another part.

(20.) The proportion of the quantity of matter to the magnitude is called the density. Thus if of two substances, one contain in a given space twice as much matter as the other, it is said to be “twice as dense.” The density of bodies is, therefore, proportionate to the closeness or proximity of their particles; and it is evident, that the greater the density, the less will be the porosity.

The pores of a body are frequently filled with another body of a more subtle nature. If the pores of a body on the surface of the earth, and exposed to the atmosphere, be greater than the atoms of air, then the air may pervade the pores. This is found to be the case with many sorts of wood which have an open grain. If a piece of such wood, or of chalk, or of sugar, be pressed to the bottom of a vessel of water, the air which fills the pores will be observed to escape in bubbles and to rise to the surface, the water entering the pores, and taking its place.

If a tall vessel or tube, having a wooden bottom, be filled with quicksilver, the liquid metal will be forced by its own weight through the pores of the wood, and will be seen escaping in a silver shower from the bottom.

(21.) The process of filtration, in the arts, depends on the presence of pores of such a magnitude as to allow a passage to the liquid, but to refuse it to those impurities from which it is to be disengaged. Various substances are used as filtres; but, whatever be used, this circumstance should always be remembered, that no substance can be separated from a liquid by filtration, except one whose particles are larger than those of the liquid. In general, filtres are used to separate solid impurities from a liquid. The most ordinary filtres are soft stone, paper, and charcoal.

(22.) All organised substances in the animal and vegetable kingdoms are, from their very natures, porous in a high degree. Minerals are porous in various degrees. Among the silicious stones is one called hydrophane, which manifests its porosity in a very remarkable manner. The stone, in its ordinary state, is semi-transparent. If, however, it be plunged in water, when it is withdrawn it is as translucent as glass. The pores, in this case, previously filled with air, are pervaded by the water, between which and the stone there subsists a physical relation, by which the one renders the other perfectly transparent.

Larger mineral masses exhibit degrees of porosity not less striking. Water percolates through the sides and roofs of caverns and grottoes, and being impregnated with calcareous and other earths, forms stalactites, or pendant protuberances, which present a curious appearance.

(23.) Compressibility.—That quality, in virtue of which a body allows its volume to be diminished without diminishing its mass, is called compressibility. This effect is produced by bringing the constituent particles more close together, and thereby increasing the density and diminishing the pores. This effect may be produced in several ways; but the name “compressibility” is only applied to it when it is caused by the agency of mechanical force, as by pressure or percussion.

All known bodies, whatever be their nature, are capable of having their dimensions reduced without diminishing their mass; and this is one of the most conclusive proofs that all bodies are porous, or that the constituent atoms are not in contact; for the space by which the volume may be diminished must, before the diminution, consist of pores.

(24.) Elasticity.—Some bodies, when compressed by mechanical agency, will resume their former dimensions with a certain energy when relieved from the operation of the force which has compressed them. This property is called elasticity; and it follows, from this definition, that all elastic bodies must be compressible, although the converse is not true, compressibility not necessarily implying elasticity.

(25.) Dilatability.—This quality is the opposite of compressibility. It is the capability observed in bodies to have their volume enlarged without increasing their mass. This effect may be produced in several ways. In ordinary circumstances, a body may exist under the constant action of a pressure by which its volume and density are determined. It may happen, that on the occasional removal of that pressure, the body will dilate by a quality inherent in its constitution. This is the case with common air. Dilatation may also be the effect of heat, as will presently appear.

The several qualities of bodies which we have noticed in this chapter, when viewed in relation to each other, present many circumstances worthy of attention.

(26.) It is a physical law, of high generality, that an increase in the temperature, or degree of heat by which a body is affected, is accompanied by an increase of volume; and that a diminution of temperature is accompanied by a diminution of volume. The exceptions to this law will be noticed and explained in our treatise on Heat. Hence it appears that the reduction of temperature is an effect which, considered mechanically, is equivalent to compression or condensation, since it diminishes the volume without altering the mass; and since this is an effect of which all bodies whatever are susceptible, it follows that all bodies whatever have pores. (23.)

The fact, that the elevation of temperature produces an increase of volume, is manifested by numerous experiments.

(27.) If a flaccid bladder be tied at the mouth, so as to stop the escape of air, and be then held before a fire, it will gradually swell, and assume the appearance of being fully inflated. The small quantity of air contained in the bladder is, in this case, so much dilated by the heat, that it occupies a considerably increased space, and fills the bladder, of which it before only occupied a small part. When the bladder is removed from the fire, and allowed to resume its former temperature, the air returns to its former dimensions, and the bladder becomes again flaccid.

(28.) Let AB, fig.2. be a glass tube, with a bulb at the end A; and let the bulb A, and a part of the tube, be filled with any liquid, coloured so as to be visible. Let C be the level of the liquid in the tube. If the bulb be now exposed to heat, by being plunged in hot water, the level of the liquid C will rapidly rise towards B. This effect is produced by the dilatation of the liquid in the bulb, which filling a greater space, a part of it is forced into the tube. This experiment may easily be made with a common glass tube and a little port wine.

Thermometers are constructed on this principle, the rise of the liquid in the tube being used as an indication of the degree of heat which causes it. A particular account of these useful instruments will be found in our treatise on Heat.

(29.) The change of dimension of solids produced by changes of temperature being much less than that of bodies in the liquid or aeriform state, is not so easily observable. A remarkable instance occurs in the process of shoeing the wheels of carriages. The rim of iron with which the wheel is to be bound, is made in the first instance of a diameter somewhat less than that of the wheel; but being raised by the application of fire to a very high temperature, its volume receives such an increase, that it will be sufficient to embrace and surround the wheel. When placed upon the wheel it is cooled, and suddenly contracting its dimensions, binds the parts of the wheel firmly together, and becomes securely seated in its place upon the fellies.

(30.) It frequently happens that the stopper of a glass bottle or decanter becomes fixed in its place so firmly, that the exertion of force sufficient to withdraw it would endanger the vessel. In this case, if a cloth wetted with hot-water be applied to the neck of the bottle, the glass will expand, and the neck will be enlarged, so as to allow the stopper to be easily withdrawn.

(31.) The contraction of metal consequent upon change of temperature was applied some time ago in Paris to restore the walls of a tottering building to their proper position. In the Conservatoire des Arts et Métiers, the walls of a part of the building were forced out of the perpendicular by the weight of the roof, so that each wall was leaning outwards. M. Molard conceived the notion of applying the irresistible force with which metals contract in cooling, to draw the walls together. Bars of iron were placed in parallel directions across the building, and at right-angles to the direction of the walls. Being passed through the walls, nuts were screwed on their ends, outside the building. Every alternate bar was then heated by lamps, and the nuts screwed close to the walls. The bars were then cooled, and the lengths being diminished by contraction, the nuts on their extremities were drawn together, and with them the walls were drawn through an equal space. The same process was repeated with the intermediate bars, and so on alternately until the walls were brought into a perpendicular position.

(32.) Since there is a continual change of temperature in all bodies on the surface of the globe, it follows, that there is also a continual change of magnitude. The substances which surround us are constantly swelling and contracting, under the vicissitudes of heat and cold. They grow smaller in winter, and dilate in summer. They swell their bulk on a warm day, and contract it on a cold one. These curious phenomena are not noticed, only because our ordinary means of observation are not sufficiently accurate to appreciate them. Nevertheless, in some familiar instances the effect is very obvious. In warm weather the flesh swells, the vessels appear filled, the hand is plump, and the skin distended. In cold weather, when the body has been exposed to the open air, the flesh appears to contract, the vessels shrink, and the skin shrivels.

(33.) The phenomena attending change of temperature are conclusive proofs of the universal porosity of material substances, but they are not the only proofs. Many substances admit of compression by the mere agency of mechanical force.

Let a small piece of cork be placed floating on the surface of water in a basin or other vessel, and an empty glass goblet be inverted over the cork, so that its edge just meets the water. A portion of air will then be confined in the goblet, and detached from the remainder of the atmosphere. If the goblet be now pressed downwards, so as to be entirely immersed, it will be observed, that the water will not fill it, being excluded by the impenetrability of the air inclosed in it. This experiment, therefore, is decisive of the fact, that air, one of the most subtle and attenuated substances we know of, possesses the quality of impenetrability. It absolutely excludes any other body from the space which it occupies at any given moment.

But although the water does not fill the goblet, yet if the position of the cork which floats upon its surface be noticed, it will be found that the level of the water within has risen above its edge or rim. In fact, the water has partially filled the goblet, and the air has been forced to contract its dimensions. This effect is produced by the pressure of the incumbent water forcing the surface in the goblet against the air, which yields until it is so far compressed that it acquires a force able to withstand this pressure. Thus it appears that air is capable of being reduced in its dimensions by mechanical pressure, independently of the agency of heat. It is compressible.

That this effect is the consequence of the pressure of the liquid will be easily made manifest by showing that, as the pressure is increased, the air is proportionally contracted in its dimensions; and as it is diminished, the dimensions are on the other hand enlarged. If the depth of the goblet in the water be increased, the cork will be seen to rise in it, showing that the increased pressure, at the greater depth, causes the air in the goblet to be more condensed. If, on the other hand, the goblet be raised toward the surface, the cork will be observed to descend toward the edge, showing that as it is relieved from the pressure of the liquid, the air gradually approaches to its primitive dimensions.

(34.) These phenomena also prove, that air has the property of elasticity. If it were simply compressible, and not elastic, it would retain the dimensions to which it was reduced by the pressure of the liquid; but this is not found to be the result. As the compressing force is diminished, so in the same proportion does the air, by its elastic virtue, exert a force by which it resumes its former dimensions.

That it is the air alone which excludes the water from the goblet, in the preceding experiments, can easily be proved. When the goblet is sunk deep in the vessel of water, let it be inclined a little to one side until its mouth is presented towards the side of the vessel; let this inclination be so regulated, that the surface of the water in the goblet shall just reach its edge. Upon a slight increase of inclination, air will be observed to escape from the goblet, and to rise in bubbles to the surface of the water. If the goblet be then restored to its position, it will be found that the cork will rise higher in it than before the escape of the air. The water in this case rises and fills the space which the air allowed to escape has deserted. The same process may be repeated until all the air has escaped, and then the goblet will be completely filled by the water.

(35.) Liquids are compressible by mechanical force in so slight a degree, that they are considered in all hydrostatical treatises as incompressible fluids. They are, however, not absolutely incompressible, but yield slightly to very intense pressure. The question of the compressibility of liquids was raised at a remote period in the history of science. Nearly two centuries ago, an experiment was instituted at the Academy del Cimento in Florence, to ascertain whether water be compressible. With this view, a hollow ball of gold was filled with the liquid, and the aperture exactly and firmly closed. The globe was then submitted to a very severe pressure, by which its figure was slightly changed. Now it is proved in geometry, that a globe has this peculiar property, that any change whatever in its figure must necessarily diminish its volume or contents. Hence it was inferred, that if the water did not issue through the pores of the gold, or burst the globe, its compressibility would be established. The result of the experiment was, that the water did ooze through the pores, and covered the surface of the globe, presenting the appearance of dew, or of steam cooled by the metal. But this experiment was inconclusive. It is quite true, that if the water had not escaped upon the change of figure of the globe, the compressibility of the liquid would have been established. The escape of the water does not, however, prove its incompressibility. To accomplish this, it would be necessary first to measure accurately the volume of water which transuded by compression, and next to measure the diminution of volume which the vessel suffered by its change of figure. If this diminution were greater than the volume of water which escaped, it would follow that the water remaining in the globe had been compressed, notwithstanding the escape of the remainder. But this could never be accomplished with the delicacy and exactitude necessary in such an experiment; and, consequently, as far as the question of the compressibility of water was concerned, nothing was proved. It forms, however, a very striking illustration of the porosity of so dense a substance as gold, and proves that its pores are larger than the elementary particles of water, since these are capable of passing through them.

(36.) It has since been proved, that water, and other liquids, are compressible. In the year 1761, Canton communicated to the Royal Society the results of some experiments which proved this fact. He provided a glass tube with a bulb, such as that described in (28), and filled the bulb and a part of the tube with water well purified from air. He then placed this in an apparatus called a condenser, by which he was enabled to submit the surface of the liquid in the tube to very intense pressure of condensed air. He found that the level of the liquid in the tube fell in a perceptible degree upon the application of the pressure. The same experiment established the fact, that liquids are elastic; for upon removing the pressure, the liquid rose to its original level, and therefore resumed its former dimensions.

(37.) Elasticity does not always accompany compressibility. If lead or iron be submitted to the hammer, it may be hardened and diminished in its volume; but it will not resume its former volume after each stroke of the hammer.

(38.) There are some bodies which maintain the state of density in which they are commonly found by the continual agency of mechanical pressure; and such bodies are endued with a quality, in virtue of which they would enlarge their dimensions without limit, if the pressure which confines them were removed. Such bodies are called elastic fluids or gases, and always exist in the form of common air, in whose mechanical properties they participate. They are hence often called aeriform fluids.

Those who are provided with an air-pump can easily establish this property experimentally. Take a flaccid bladder, such as that already described in (27.), and place it under the glass receiver of an air-pump: by this instrument we shall be able to remove the air which surrounds the bladder under the receiver, so as to relieve the small quantity of air which is inclosed in the bladder from the pressure of the external air: when this is accomplished, the bladder will be observed to swell, as if it were inflated, and will be perfectly distended. The air contained in it, therefore, has a tendency to dilate, which takes effect when it ceases to be resisted by the pressure of surrounding air.

(39.) It has been stated that the increase or diminution of temperature is accompanied by an increase or diminution of volume. Related to this, there is another phenomenon too remarkable to pass unnoticed, although this is not the proper place to dwell upon it: it is the converse of the former; viz. that an increase or diminution of bulk is accompanied by a diminution or increase of temperature. As the application of heat from some foreign source produces an increase of dimensions, so if the dimensions be increased from any other cause, a corresponding portion of the heat which the body had before the enlargement, will be absorbed in the process, and the temperature will be thereby diminished. In the same way, since the abstraction of heat causes a diminution of volume, so if that diminution be caused by any other means, the body will give out the heat which in the other case was abstracted, and will rise in its temperature.

Numerous and well-known facts illustrate these observations. A smith by hammering a piece of bar iron, and thereby compressing it, will render it red hot. When air is violently compressed, it becomes so hot as to ignite cotton and other substances. An ingenious instrument for producing a light for domestic uses has been constructed, consisting of a small cylinder, in which a solid piston moves air-tight: a little tinder, or dry sponge, is attached to the bottom of the piston, which is then violently forced into the cylinder: the air between the bottom of the cylinder and the piston becomes intensely compressed, and evolves so much heat as to light the tinder.

In all the cases where friction or percussion produces heat or fire, it is because they are means of compression. The effects of flints, of pieces of wood rubbed together, the warmth produced by friction on the flesh, are all to be attributed to the same cause.

A Treatise on Mechanics

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