Читать книгу Flame Retardants - Johannes Karl Fink - Страница 4

1 Chapter 1Figure 1.1 HET acid.Figure 1.2 Dechlorane Plus.Figure 1.3 Chlordene.Figure 1.4 Tris(1,3-dichloroisopropyl) phosphate.Figure 1.5 Components in Firemaster® (40).Figure 1.6 Tris(2-chloroethyl) phosphate.Figure 1.7 1,3-Hydrogen shift (42).Figure 1.8 1,3,5-Tris(2,3-dibromopropyl)-2,4,6-trioxohexahydrotriazine.Figure 1.9 2,4,6-Tris(2,4,6-tribromophenoxy)-1,3,5-triazine.Figure 1.10 Pentabromodiphenyl ether.Figure 1.11 Resorcinol bis(diphenyl phosphate).Figure 1.12 Synthesis of N,N’-Bis[di-(2,6-xylenoxy)phosphinyl]piperazine.Figure 1.13 Synthesis of a cyclic phosphazene molecule (55).Figure 1.14 Phosphaphenanthrene compound (TAD).Figure 1.15 Synthesis of poly(4,4’-diaminodiphenyl methane phenyl dichloroph...Figure 1.16 Synthesis of DOPO-N.Figure 1.17 Synthesis of a halogen-free flame retardant (DTB) (64).Figure 1.18 Dioxa borolanyl oxides.Figure 1.19 Tetraethylammonium bis-(tetrabromopyrocatecholato)-borate.Figure 1.20 2,4,6-Tris(4-boronic-2-thiophene)-1,3,5-triazine.Figure 1.21 Synthesis of 2,4,6-tris-(4-boronphenoxy)-(1,3,5)-triazine (74)....Figure 1.22 Thermogravimetric curve of 2,4,6-tris-(4-boronphenoxy)-(1,3,5)-t...Figure 1.23 Thermal conductivity viz. temperature (76).Figure 1.24 LOI values viz. temperature (76).Figure 1.25 Phytic acid.Figure 1.26 Synthesis of an azo-boron compound (86).Figure 1.27 Synthesis of an azo-boron compound (87).Figure 1.28 Calcium lignosulfonate.Figure 1.29 Synthesis of phosphorus- and boron-containing isosorbides (88)....Figure 1.30 Synthesis of hexakis(4-boronic acid-phenoxy)-cyclophosphazene (8...Figure 1.31 Synthetic routes of a DOPO-based diamine and a cardanol-based be...Figure 1.32 Synthesis of HSPCTP (101).Figure 1.33 Synthesis of a phosphaphenanthrene-based flame retardant (105)....Figure 1.34 Synthesis of [(1,1,3,3-tetramethyl-1,3-disilazanediyl)di-2,1-eth...Figure 1.35 Synthesis of a macromolecular charring agent (109).Figure 1.36 Synthesis of an intumescent flame retardant (113).Figure 1.37 Hexaphenoxycyclotriphosphazene.Figure 1.38 β-Cyclodextrin.Figure 1.39 Tannic acid.Figure 1.40 Hex(4-carboxylphenoxy)cyclotriphosphazene.Figure 1.41 Synthesis of bis-9,10-dihydro-9-oxa-10-phosphaphenan-threne-10-o...Figure 1.42 Structure of bio-based polyphosphonate (143).Figure 1.43 Polymerization of the ionic monomer (148).Figure 1.44 Phenethyl-bridged DOPO (155).Figure 1.45 Phenylphosphinic acid.Figure 1.46 2-((6-Oxidodibenzo[c,e][1,2]oxaphosphinin-6-yl)methoxy)ac-ryloxy...Figure 1.47 Dopamine.Figure 1.48 Synthesis of hexabromocyclododecane.Figure 1.49 Nitrogen-containing compounds.Figure 1.50 Some bound additives.Figure 1.51 Bicyclo[2.2.2]oct-5-ene-2,3-dicarboxylic acid, 1-methyl-4-(1-met...Figure 1.52 10-(2’,5’-dihydroxyphenyl)-9,10-Dihydro-9-oxa-10-phos-phaphenant...Figure 1.53 DOPO-dicyandiamide compounds (215).Figure 1.54 Compounds for flame retardant resin composition.

2 Chapter 2Figure 2.1 Synthesis of a diphenolic acid-based biphosphate (11).Figure 2.2 Benzoxazine monomer with triazine structure (15).Figure 2.3 Flame retardant compounds.Figure 2.4 Synthesis of DTA (18).Figure 2.5 The synthesis of ATZ (22).

3 Chapter 3Figure 3.1 Synthesis of poly(sulfonyldiphenylene thiophenylphosphonate) (13)...Figure 3.2 Poly(2-hydroxy propylene spirocyclic pentaerythritol bisphosphona...Figure 3.3 Synthesis of a hyperbranched poly(amine) (16).Figure 3.4 Synthesis of 5-(benzylidene-amino)-isophthalic acid dimethyl este...Figure 3.5 PA6-COOH and 1,3-Bis(3-aminopropyl)tetramethyl disiloxane.Figure 3.6 Aldimine reaction (27).Figure 3.7 Synthesis of PCNFR (28).Figure 3.8 Synthesis of triglycidyl phosphate.

4 Chapter 4Figure 4.1 Smoke density (Dmaxg⁻¹) versus chlorine content (%) (19).Figure 4.2 Ammonium molybdophosphate.Figure 4.3 Phosphorus-containing polyol (38).Figure 4.4 Tetraethyl orthosilicate.Figure 4.5 Synthesis of monocardanyl phosphoric acid (44).Figure 4.6 Compounds for modification of nanocomposites (46).Figure 4.7 Metal-based organic complexes.

5 Chapter 5Figure 5.1 Tested flame retardants.Figure 5.2 Other flame retardants.

6 Chapter 6Figure 6.1 Tetrabromobisphenol A.

7 Chapter 7Figure 7.1 Pentabromobenzyl acrylate.Figure 7.2 Condensation of 1,2,6-Tribromophenol.Figure 7.3 Phosphine oxides.Figure 7.4 Bis(glycidyloxy)phenyl phosphine oxide.Figure 7.5 Diaminophenyl commpounds.Figure 7.6 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.Figure 7.7 Phosphorylation of poly(4-hydroxystyrene) (51).Figure 7.8 Phosphor-containing monomers (47).Figure 7.9 Spirocyclic pentaerythritol di(phosphoric acid monochloride) (56)...Figure 7.10 Melamine phosphate.Figure 7.11 Modified melamine-formaldehyde resin.Figure 7.12 Macromolecular nitrogen-phosphorus intumescent flame retardant (...Figure 7.13 Hexaphenoxycyclotriphosphazene.Figure 7.14 N-β-(Aminoethyl)-γ-aminopropyltrimethoxysilane.Figure 7.15 Tris(1-chloro-2-isopropyl) phosphate.Figure 7.16 Synthesis of a flame retardant polyol (78).Figure 7.17 Synthesis of HDPCP (86).Figure 7.18 2-[Anilino-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phen...Figure 7.19 Amino trimethylene phosphonic acid.Figure 7.20 Synthesis of bis((dimethoxyphosphoryl)methyl) phenyl phosphate (...Figure 7.21 Phosphorus-containing organosilicon compounds.Figure 7.22 Reactive flame retardants.Figure 7.23 Synthesis of 2,2-diethyl-1,3-propanediol phosphoryl melamine (10...Figure 7.24 N,N-Bis(2-hydroxyethyl acrylate) aminomethyl phosphonic acid die...Figure 7.25 Synthesis of diethyl-N,N-bis(2-hydroxyethyl) phosphoramide (114)...Figure 7.26 10-Hydroxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.

8 Chapter 8Figure 8.1 MKT-1 and MKT-2.Figure 8.2 Synthesis of DDPSi-FR (21).Figure 8.3 1,2,3,4-Butane tetracarboxylic acid.Figure 8.4 Citric acid.Figure 8.5 Sulfamic acid.Figure 8.6 LOI and flame retardant and aging (39). RTFOT: Rolling thin film ...Figure 8.7 3-Aminopropyl triethoxy silane.Figure 8.8 Oil absorption with different contents of silane coupling agent (...Figure 8.9 Bis(N,N-diethyl)(2-methoxyethoxy)methylphosphonamidate.Figure 8.10 (4-Methoxy)-phenoxy pentafluorocyclotriphosphazene.Figure 8.11 Phosphorus-containing molecules.Figure 8.12 N-Ethyl-2-methoxypyrrolinium bis(fluorosulfonyl)imide.Figure 8.13 Ethoxy(pentafluoro)cyclotriphosphazene.Figure 8.14 Poly[bis-(ethoxyethoxyethoxy)phosphazene].Figure 8.15 1,1,2,2-Tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether.