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LECTURE I
§ 4. The Refraction of Light. Total Reflection

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For more than a thousand years no step was taken in optics beyond this law of reflection. The men of the Middle Ages, in fact, endeavoured, on the one hand, to develop the laws of the universe à priori out of their own consciousness, while many of them were so occupied with the concerns of a future world that they looked with a lofty scorn on all things pertaining to this one. Speaking of the natural philosophers of his time, Eusebius says, 'It is not through ignorance of the things admired by them, but through contempt of their useless labour, that we think little of these matters, turning our souls to the exercise of better things.' So also Lactantius—'To search for the causes of things; to inquire whether the sun be as large as he seems; whether the moon is convex or concave; whether the stars are fixed in the sky, or float freely in the air; of what size and of what material are the heavens; whether they be at rest or in motion; what is the magnitude of the earth; on what foundations is it suspended or balanced;—to dispute and conjecture upon such matters is just as if we chose to discuss what we think of a city in a remote country, of which we never heard but the name.'

As regards the refraction of light, the course of real inquiry was resumed in 1100 by an Arabian philosopher named Alhazen. Then it was taken up in succession by Roger Bacon, Vitellio, and Kepler. One of the most important occupations of science is the determination, by precise measurements, of the quantitative relations of phenomena; the value of such measurements depending greatly upon the skill and conscientiousness of the man who makes them. Vitellio appears to have been both skilful and conscientious, while Kepler's habit was to rummage through the observations of his predecessors, to look at them in all lights, and thus distil from them the principles which united them. He had done this with the astronomical measurements of Tycho Brahe, and had extracted from them the celebrated 'laws of Kepler.' He did it also with Vitellio's measurements of refraction. But in this case he was not successful. The principle, though a simple one, escaped him, and it was first discovered by Willebrord Snell, about the year 1621.

Less with the view of dwelling upon the phenomenon itself than of introducing it in a form which will render subsequently intelligible to you the play of theoretic thought in Newton's mind, the fact of refraction may be here demonstrated. I will not do this by drawing the course of the beam with chalk on a black board, but by causing it to mark its own white track before you. A shallow circular vessel (RIG, fig. 4), half filled with water, rendered slightly turbid by the admixture of a little milk, or the precipitation of a little mastic, is placed with its glass front vertical. By means of a small plane reflector (M), and through a slit (I) in the hoop surrounding the vessel, a beam of light is admitted in any required direction. It impinges upon the water (at O), enters it, and tracks itself through the liquid in a sharp bright band (O G). Meanwhile the beam passes unseen through the air above the water, for the air is not competent to scatter the light. A puff of smoke into this space at once reveals the track of the incident-beam. If the incidence be vertical, the beam is unrefracted. If oblique, its refraction at the common surface of air and water (at O) is rendered clearly visible. It is also seen that reflection (along O R) accompanies refraction, the beam dividing itself at the point of incidence into a refracted and a reflected portion.4


Fig. 4.


The law by which Snell connected together all the measurements executed up to his time, is this: Let A B C D (fig. 5) represent the outline of our circular vessel, A C being the water-line. When the beam is incident along B E, which is perpendicular to A C, there is no refraction. When it is incident along m E, there is refraction: it is bent at E and strikes the circle at n. When it is incident along m' E there is also refraction at E, the beam striking the point n'. From the ends of the two incident beams, let the perpendiculars m o, m' o' be drawn upon B D, and from the ends of the refracted beams let the perpendiculars p n, p' n' be also drawn. Measure the lengths of o m and of p n, and divide the one by the other. You obtain a certain quotient. In like manner divide m' o' by the corresponding perpendicular p' n'; you obtain precisely the same quotient. Snell, in fact, found this quotient to be a constant quantity for each particular substance, though it varied in amount from one substance to another. He called the quotient the index of refraction.


Fig. 5


In all cases where the light is incident from air upon the surface of a solid or a liquid, or, to speak more generally, when the incidence is from a less highly refracting to a more highly refracting medium, the reflection is partial. In this case the most powerfully reflecting substances either transmit or absorb a portion of the incident light. At a perpendicular incidence water reflects only 18 rays out of every 1,000; glass reflects only 25 rays, while mercury reflects 666 When the rays strike the surface obliquely the reflection is augmented. At an incidence of 40°, for example, water reflects 22 rays, at 60° it reflects 65 rays, at 80° 333 rays; while at an incidence of 89½°, where the light almost grazes the surface, it reflects 721 rays out of every 1,000. Thus, as the obliquity increases, the reflection from water approaches, and finally quite overtakes, the perpendicular reflection from mercury; but at no incidence, however great, when the incidence is from air, is the reflection from water, mercury, or any other substance, total.

Still, total reflection may occur, and with a view to understanding its subsequent application in the Nicol's prism, it is necessary to state when it occurs. This leads me to the enunciation of a principle which underlies all optical phenomena—the principle of reversibility.5 In the case of refraction, for instance, when the ray passes obliquely from air into water, it is bent towards the perpendicular; when it passes from water to air, it is bent from the perpendicular, and accurately reverses its course. Thus in fig. 5, if m E n be the track of a ray in passing from air into water, n E m will be its track in passing from water into air. Let us push this principle to its consequences. Supposing the light, instead of being incident along m E or m′ E, were incident as close as possible along C E (fig. 6); suppose, in other words, that it just grazes the surface before entering the water. After refraction it will pursue say the course E n″. Conversely, if the light start from n″, and be incident at E, it will, on escaping into the air, just graze the surface of the water. The question now arises, what will occur supposing the ray from the water to follow the course n‴ E, which lies beyond n″ E? The answer is, it will not quit the water at all, but will be totally reflected (along E x). At the under surface of the water, moreover, the law is just the same as at its upper surface, the angle of incidence (D E n‴) being equal to the angle of reflection (D E x).


Fig. 6


Total reflection may be thus simply illustrated:—Place a shilling in a drinking-glass, and tilt the glass so that the light from the shilling shall fall with the necessary obliquity upon the water surface above it. Look upwards through the water towards that surface, and you see the image of the shilling shining there as brightly as the shilling itself. Thrust the closed end of an empty test-tube into water, and incline the tube. When the inclination is sufficient, horizontal light falling upon the tube cannot enter the air within it, but is totally reflected upward: when looked down upon, such a tube looks quite as bright as burnished silver. Pour a little water into the tube; as the liquid rises, total reflection is abolished, and with it the lustre, leaving a gradually diminishing shining zone, which disappears wholly when the level of the water within the tube reaches that without it. Any glass tube, with its end stopped water-tight, will produce this effect, which is both beautiful and instructive.

Total reflection never occurs except in the attempted passage of a ray from a more refracting to a less refracting medium; but in this case, when the obliquity is sufficient, it always occurs. The mirage of the desert, and other phantasmal appearances in the atmosphere, are in part due to it. When, for example, the sun heats an expanse of sand, the layer of air in contact with the sand becomes lighter and less refracting than the air above it: consequently, the rays from a distant object, striking very obliquely on the surface of the heated stratum, are sometimes totally reflected upwards, thus producing images similar to those produced by water. I have seen the image of a rock called Mont Tombeline distinctly reflected from the heated air of the strand of Normandy near Avranches; and by such delusive appearances the thirsty soldiers of the French army in Egypt were greatly tantalised.

The angle which marks the limit beyond which total reflection takes place is called the limiting angle (it is marked in fig. 6 by the strong line E n″). It must evidently diminish as the refractive index increases. For water it is 48½°, for flint glass 38°41', and for diamond 23°42'. Thus all the light incident from two complete quadrants, or 180°, in the case of diamond, is condensed into an angular space of 47°22' (twice 23°42') by refraction. Coupled with its great refraction, are the great dispersive and great reflective powers of diamond; hence the extraordinary radiance of the gem, both as regards white light and prismatic light.

4

It will be subsequently shown how this simple apparatus may be employed to determine the 'polarizing angle' of a liquid.

5

From this principle Sir John Herschel deduces in a simple and elegant manner the fundamental law of reflection.—See Familiar Lectures, p. 236.

Six Lectures on Light. Delivered In The United States In 1872-1873

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