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Depending on the type of molecule, both silicones and polyquats may build up on your hair. Dimethicone is one of the most difficult silicones to remove and multiple use of products with it can make your hair look dull and weighed down over time. Cyclomethicone, on the other hand, evaporates from hair like water and will not cause the same problems. Polyquats do not build up as much, but still require occasional washing with a polyquat-free shampoo.