Читать книгу Advanced Level of Dental Resins - Material Science & Technology - Ralf Janda - Страница 3
ОглавлениеContents
Contents
Preface - 2nd Ed. Advanced Level
Preface - 1st Ed. Advanced Level
Preface - Book Series
Literature/Trademarks/Other
Introduction
Abbreviations
Terms and Definitions
Resin Materials in Dentistry
Matrix Resins
2 Functional Groups and Monomer Links
3.1.1 Free Radical Polymerization
3.1.4 Ring-Opening Polymerization
3.1.5 Thiol-Ene Polymerization
3.1.6 Technical Polymerization Processes
4 Matrix Resins According to Links
4.1.1 Acrylates and Methacrylates
4.1.2 Other Important C-C-Linked Polymers
4.1.2.4 Polytetrafluoroethylene
4.5.1 Polyphenylene oxide (PPO)/Polyphenylene ether (PPE)
4.5.2 Poly(aryl-ether-ether-ketone) (PEEK)
5 Structures and Properties of Monomers and Oligomers
5.1 Acrylates and Methacrylates
5.3.1 Degree of Conversion of Methacrylate-Based Composites
5.3.2 Degree of Conversion of Silorane-Based Composites
5.3.3 Degree of Conversion of Anionic Polymerization
5.3.4 Degree of Conversion of Polyaddition and Polycondensation
6 Structures and Properties of Polymers
6.1 Types of Chemical Bonds/Forces
6.2 Primary Polymer Structures
6.3 Secondary Polymer Structures
6.4 Tertiary Polymer Structures
6.8 Interpenetrating Polymer Networks
7 Chemical Reactions of Polymers
7.2 Cross-Linking of Polymers and Vulcanization
7.3 Layering/Incremental Technique and Repair of Resin Composites
Initiators and Catalysts
2.2.1 Peroxide/Amine-Based Redox Initiators
2.2.2 Barbituric Acid-Based Redox Initiators
2.2.3 Sulfinic Acid-Based Redox Initiators
2.3.1 Conventional Radical Photoinitiators
2.3.2 Tailor-Made Radical Photoinitiators
2.3.3 Cationic Photoinitiators
2.3.4 Radical/Cationic Hybrid Photoinitiators
Fillers
2 General Effects of Fillers on Material Properties
3 Effect of Refractive Index on Optical Properties
4 Effect of Filler Shape on Mechanical Properties
5 Particle Reinforcement and Material Properties
6 Fiber Reinforcement and Material Properties
7 Organic Fillers
7.1 Adhesion Organic Filler/Resin Matrix
8 Inorganic Fillers
8.1 Adhesion Inorganic Filler/Resin Matrix
8.1.1 Adhesion of Inorganic Filler/Organic Matrix by Silanization
8.1.2 Other Surface Treatments for Adhesion Inorganic Filler/Organic Matrix
Pigments and Dyes
1 Introduction
2 Pigments
3 Dyes
Additives
1 Introduction
2 Stabilizers
3 Antioxidants
4 UV-Stabilizers
5 Plasticizers
Physical and Chemical Properties of Polymers - General Aspects
1 Introduction
2 Physical Properties
3 Chemical Properties
4 Ageing Processes/Depolymerization
Material Testing/Standards
1 Introduction
2 Parameters of Material Testing
3 Standards
4 Some Standard Tests
4.1 Methods to Test Mechanical Properties
4.1.1 Flexural Strength and Modulus of Elasticity
4.1.2 Tensile/Tear Strength and Modulus of Elasticity
4.1.3 Compressive Strength
4.1.4 Impact Strength
4.1.4.1 Izod Impact Strength
4.1.4.2 Charpey Impact Strength
4.1.5 Hardness Tests
4.1.5.1 Brinell Hardness
4.1.5.2 Knoop Hardness
4.1.5.3 Rockwell Hardness
4.1.5.4 Shore Hardness
4.1.5.5 Vickers Hardness
4.2 Chemical Properties
4.3 Other Physical Properties
4.3.1 Color Stability
4.3.2 X-Ray Opacity
4.4 Adhesion Testing
4.4.1 Micro-Tensile Bond Strength (µTBS) Test
4.4.2 Shear Bond Strength (SBS) Test
4.5 Statistics
Toxicology/Clinics/Standards
1 Introduction
2 Toxicology
2.1 Toxic Events
2.2 Toxicity Tests
2.3 Toxicity of Some Raw Materials for Dental Resins
2.3.1 (Meth)acrylic Monomers
2.3.2 (Meth)acrylate-Based Dental Resins - Other Components
2.4 Toxicity of Dental Resins - Evaluation and Summary
2.4.1 (Meth)acrylate-Based Dental Resins
2.4.2 Polysiloxanes and Polyethers
3 Standards for Laboratory Testing
4 Standards for Clinical Testing
Denture Base Resins
1 Introduction
2 Classification and Properties
3 Principal Processing Methods
3.1 Full and Partial Embedment
3.1.1 Pack and Press Technique
3.1.2 Injection Technique
3.1.3 Injection Molding
3.1.4 Pouring/Casting Technique
3.1.5 Melt and Press Technique
3.2 No Embedment
3.2.1 Light-Curing Resins
3.2.2 CAD/CAM Technique
3.3 Insulation of Plaster
4 Polymethyl (meth)acrylates
4.1 Powder/Liquid Products
4.1.1 Powder/Liquid Products - Formulation
4.1.1.1 Heat-Curing Products
4.1.1.2 Self-/Cold-Curing Products
4.1.1.3 Microwave-Curing Products
4.1.2 Powder/Liquid Products - Processing
4.1.2.1 Heat-/Microwave-Curing Products
4.1.2.2 Self-/Cold-Curing Products
4.2 One-Component Products
4.2.1 Polymerizable Products - Formulation and Processing
4.2.1.1 Light-Curing Products - Processing
4.2.1.2 Heat-/Microwave-Curing Products - Processing
4.2.2 Thermoplastic Products - Formulation and Processing
5 Other Denture Base Resins - Formulation and Processing
6 Fit of Dentures
7 Residual Monomer and Denture Intolerance
Resin Teeth
1 Introduction
2 Formulation and Production
3 Properties
4 Processing
Denture Reline Resins
1 Introduction
2 Indications and Requirements
3 Poly(meth)acrylate-Based Reline Materials
4 Polysiloxane-Based Reline Materials
Crown and Bridge Veneer Resins
1 Introduction
2 Classification, Formulation and Processing
2.1 Powder/Liquid Veneer Resins
2.2 One-Component Veneer Resins
3 Properties and Performance of Veneer Resins
3.1 Powder/Liquid Veneer Resins
3.2 One-Component Veneer Resins
Resins for Provisional/Temporary Crowns and Bridges
1 Introduction
2 Formulation and Processing
3 Properties
Resins for Crown Copings and Bridge Frames
Impression Materials
1 Introduction
2 Classification, Processing and Performance
3 Polysulfides
4 Polyethers
5 Polysiloxanes (Silicones)
Resin-Based Filling Composites
1 Introduction
2 Classification
3 Formulation
3.1 General Aspects and Overview
3.2 Microfill Filling Composites
3.3 Hybrid/Micro-Hybrid Filling Composites
3.4 Compomer Filling Composites
3.5 Ormocer Filling Composites
3.6 Nanoparticle Filling Composites
3.7 Silorane Filling Composites
3.8 Bulk-Fill Filling Composites
3.9 Giomer Filling Composites
3.10 Flowable Filling Composites
4 Properties and Performance
4.1 Flexural Strength and Flexural Modulus
4.2 Polymerization Shrinkage and Shrinkage Stress
4.3 Depth of Cure
4.4 Water Sorption, Solubility and Hygroscopic Expansion
4.5 Color Stability
4.6 X-Ray Opacity
4.7 Antibacterial Effects
5 Resins for Prophylaxis
Other Dental Polymers
Light-Curing Devices
1 Introduction
2 Light-Curing Devices for the Dental Practice
3 Light-Curing Devices for the Dental Laboratory
CAD/CAM Technology
1 Introduction
2 Intraoral Scanning
3 Grinding and Milling
4 3D Printing
Adhesion and Adhesives
1 Introduction
2 Theoretical Aspects of Adhesion
2.1 Surface Pretreatment
2.2 Adhesive Bond
2.3 Mechanical Bond
2.4 Chemical Bond
2.5 Geometrical Design of Bonding Surfaces
3 Special Surface Pretreatment Techniques
3.1 Silicatization Processes
3.1.1 Pyrolytic Silicatization
3.1.2 Tribochenical Silicatization
4 Metal/Resin Bond
5 Ceramic/Resin Bond
6 Resin/Resin Bond
7 Hard Tooth Tissues/Resin Bond
7.1 Mechanism of Resin/Enamel-Dentin Bond
7.2 Etchants and Etching Process
7.3 Classification
7.4 Formulation
7.5 Total-Etch Adhesives
7.5.1 3-Step Adhesives
7.5.2 2-Step Adhesives
7.6 Self-Etch Adhesives
7.6.1 2-Step Adhesives
7.6.2 1-Step Adhesives
7.7 Requirements and Properties
7.8 Creation of Dentin Bond - Smear and Hybrid Layer
7.8.1 Total-Etch Technique - Smear Layer Removal
7.8.2 Self-Etch Technique - Smear Layer Fixation and Hybrid Layer Creation
7.8.3 Adverse Effects on the Adhesive/Dentin Bonding Zone
7.9 Biocompatibility
8 Resin-Based Luting Composites
8.1 Conventional Luting Resin Composites
8.2 Self-Etch Luting Resin Composites
8.3 Self-Adhesive Luting Resin Composites
9 Bacterial Adhesion to Resins
Curriculum Vitae
Literature
Index