Читать книгу Advanced Level of Dental Resins - Material Science & Technology - Ralf Janda - Страница 3

Оглавление

Contents

Contents

Preface - 2nd Ed. Advanced Level

Preface - 1st Ed. Advanced Level

Preface - Book Series

Literature/Trademarks/Other

Introduction

Abbreviations

Terms and Definitions

1 Chemistry/Polymer Chemistry

2 Radiometry

Resin Materials in Dentistry

1 Introduction

2 Modern Dental Resins

Matrix Resins

1 Introduction

2 Functional Groups and Monomer Links

3 Polyreactions

3.1 Polymerization Reactions

3.1.1 Free Radical Polymerization

3.1.1.1 Oxygen Inhibition

3.1.2 Cationic Polymerization

3.1.3 Anionic Polymerization

3.1.4 Ring-Opening Polymerization

3.1.5 Thiol-Ene Polymerization

3.1.6 Technical Polymerization Processes

3.2 Polycondensation

3.3 Polyaddition

4 Matrix Resins According to Links

4.1 Carbon-Carbon Link

4.1.1 Acrylates and Methacrylates

4.1.2 Other Important C-C-Linked Polymers

4.1.2.1 Polyethylene

4.1.2.2 Polypropylene

4.1.2.3 Polyvinyl chloride

4.1.2.4 Polytetrafluoroethylene

4.1.2.5 Polyvinyl acetate

4.1.2.6 Polystyrene

4.1.2.7 Synthetic Rubbers

4.2 Ester Link

4.2.1 Saturated Polyesters

4.2.2 Unsaturated Polyesters

4.2.3 Polycarbonates

4.3 Amide Link

4.4 Urethane Link

4.5 Ether Link

4.5.1 Polyphenylene oxide (PPO)/Polyphenylene ether (PPE)

4.5.2 Poly(aryl-ether-ether-ketone) (PEEK)

4.5.3 Polyoxymethylene (POM)

4.5.4 Epoxide Polymers (EP)

4.6 Siloxane Link

4.7 Sulfone Link

5 Structures and Properties of Monomers and Oligomers

5.1 Acrylates and Methacrylates

5.2 Other Monomers

5.3 Degree of Conversion (DC)

5.3.1 Degree of Conversion of Methacrylate-Based Composites

5.3.2 Degree of Conversion of Silorane-Based Composites

5.3.3 Degree of Conversion of Anionic Polymerization

5.3.4 Degree of Conversion of Polyaddition and Polycondensation

6 Structures and Properties of Polymers

6.1 Types of Chemical Bonds/Forces

6.2 Primary Polymer Structures

6.3 Secondary Polymer Structures

6.4 Tertiary Polymer Structures

6.5 Thermoplastics

6.6 Elastomers

6.7 Duromers

6.8 Interpenetrating Polymer Networks

6.9 Polymer Blends

7 Chemical Reactions of Polymers

7.1 Grafting

7.2 Cross-Linking of Polymers and Vulcanization

7.3 Layering/Incremental Technique and Repair of Resin Composites

Initiators and Catalysts

1 Introduction

2 Initiators

2.1 Thermal/Heat Initiators

2.2 Redox Initiators

2.2.1 Peroxide/Amine-Based Redox Initiators

2.2.2 Barbituric Acid-Based Redox Initiators

2.2.3 Sulfinic Acid-Based Redox Initiators

2.3 Photoinitiators

2.3.1 Conventional Radical Photoinitiators

2.3.2 Tailor-Made Radical Photoinitiators

2.3.3 Cationic Photoinitiators

2.3.4 Radical/Cationic Hybrid Photoinitiators

3 Synergists

4 Catalysts

Fillers

1 Introduction

2 General Effects of Fillers on Material Properties

3 Effect of Refractive Index on Optical Properties

4 Effect of Filler Shape on Mechanical Properties

5 Particle Reinforcement and Material Properties

6 Fiber Reinforcement and Material Properties

7 Organic Fillers

7.1 Adhesion Organic Filler/Resin Matrix

8 Inorganic Fillers

8.1 Adhesion Inorganic Filler/Resin Matrix

8.1.1 Adhesion of Inorganic Filler/Organic Matrix by Silanization

8.1.2 Other Surface Treatments for Adhesion Inorganic Filler/Organic Matrix

Pigments and Dyes

1 Introduction

2 Pigments

3 Dyes

Additives

1 Introduction

2 Stabilizers

3 Antioxidants

4 UV-Stabilizers

5 Plasticizers

Physical and Chemical Properties of Polymers - General Aspects

1 Introduction

2 Physical Properties

3 Chemical Properties

4 Ageing Processes/Depolymerization

Material Testing/Standards

1 Introduction

2 Parameters of Material Testing

3 Standards

4 Some Standard Tests

4.1 Methods to Test Mechanical Properties

4.1.1 Flexural Strength and Modulus of Elasticity

4.1.2 Tensile/Tear Strength and Modulus of Elasticity

4.1.3 Compressive Strength

4.1.4 Impact Strength

4.1.4.1 Izod Impact Strength

4.1.4.2 Charpey Impact Strength

4.1.5 Hardness Tests

4.1.5.1 Brinell Hardness

4.1.5.2 Knoop Hardness

4.1.5.3 Rockwell Hardness

4.1.5.4 Shore Hardness

4.1.5.5 Vickers Hardness

4.2 Chemical Properties

4.3 Other Physical Properties

4.3.1 Color Stability

4.3.2 X-Ray Opacity

4.4 Adhesion Testing

4.4.1 Micro-Tensile Bond Strength (µTBS) Test

4.4.2 Shear Bond Strength (SBS) Test

4.5 Statistics

Toxicology/Clinics/Standards

1 Introduction

2 Toxicology

2.1 Toxic Events

2.2 Toxicity Tests

2.3 Toxicity of Some Raw Materials for Dental Resins

2.3.1 (Meth)acrylic Monomers

2.3.2 (Meth)acrylate-Based Dental Resins - Other Components

2.4 Toxicity of Dental Resins - Evaluation and Summary

2.4.1 (Meth)acrylate-Based Dental Resins

2.4.2 Polysiloxanes and Polyethers

3 Standards for Laboratory Testing

4 Standards for Clinical Testing

Denture Base Resins

1 Introduction

2 Classification and Properties

3 Principal Processing Methods

3.1 Full and Partial Embedment

3.1.1 Pack and Press Technique

3.1.2 Injection Technique

3.1.3 Injection Molding

3.1.4 Pouring/Casting Technique

3.1.5 Melt and Press Technique

3.2 No Embedment

3.2.1 Light-Curing Resins

3.2.2 CAD/CAM Technique

3.3 Insulation of Plaster

4 Polymethyl (meth)acrylates

4.1 Powder/Liquid Products

4.1.1 Powder/Liquid Products - Formulation

4.1.1.1 Heat-Curing Products

4.1.1.2 Self-/Cold-Curing Products

4.1.1.3 Microwave-Curing Products

4.1.2 Powder/Liquid Products - Processing

4.1.2.1 Heat-/Microwave-Curing Products

4.1.2.2 Self-/Cold-Curing Products

4.2 One-Component Products

4.2.1 Polymerizable Products - Formulation and Processing

4.2.1.1 Light-Curing Products - Processing

4.2.1.2 Heat-/Microwave-Curing Products - Processing

4.2.2 Thermoplastic Products - Formulation and Processing

5 Other Denture Base Resins - Formulation and Processing

6 Fit of Dentures

7 Residual Monomer and Denture Intolerance

Resin Teeth

1 Introduction

2 Formulation and Production

3 Properties

4 Processing

Denture Reline Resins

1 Introduction

2 Indications and Requirements

3 Poly(meth)acrylate-Based Reline Materials

4 Polysiloxane-Based Reline Materials

Crown and Bridge Veneer Resins

1 Introduction

2 Classification, Formulation and Processing

2.1 Powder/Liquid Veneer Resins

2.2 One-Component Veneer Resins

3 Properties and Performance of Veneer Resins

3.1 Powder/Liquid Veneer Resins

3.2 One-Component Veneer Resins

Resins for Provisional/Temporary Crowns and Bridges

1 Introduction

2 Formulation and Processing

3 Properties

Resins for Crown Copings and Bridge Frames

Impression Materials

1 Introduction

2 Classification, Processing and Performance

3 Polysulfides

4 Polyethers

5 Polysiloxanes (Silicones)

Resin-Based Filling Composites

1 Introduction

2 Classification

3 Formulation

3.1 General Aspects and Overview

3.2 Microfill Filling Composites

3.3 Hybrid/Micro-Hybrid Filling Composites

3.4 Compomer Filling Composites

3.5 Ormocer Filling Composites

3.6 Nanoparticle Filling Composites

3.7 Silorane Filling Composites

3.8 Bulk-Fill Filling Composites

3.9 Giomer Filling Composites

3.10 Flowable Filling Composites

4 Properties and Performance

4.1 Flexural Strength and Flexural Modulus

4.2 Polymerization Shrinkage and Shrinkage Stress

4.3 Depth of Cure

4.4 Water Sorption, Solubility and Hygroscopic Expansion

4.5 Color Stability

4.6 X-Ray Opacity

4.7 Antibacterial Effects

5 Resins for Prophylaxis

Other Dental Polymers

Light-Curing Devices

1 Introduction

2 Light-Curing Devices for the Dental Practice

3 Light-Curing Devices for the Dental Laboratory

CAD/CAM Technology

1 Introduction

2 Intraoral Scanning

3 Grinding and Milling

4 3D Printing

Adhesion and Adhesives

1 Introduction

2 Theoretical Aspects of Adhesion

2.1 Surface Pretreatment

2.2 Adhesive Bond

2.3 Mechanical Bond

2.4 Chemical Bond

2.5 Geometrical Design of Bonding Surfaces

3 Special Surface Pretreatment Techniques

3.1 Silicatization Processes

3.1.1 Pyrolytic Silicatization

3.1.2 Tribochenical Silicatization

4 Metal/Resin Bond

5 Ceramic/Resin Bond

6 Resin/Resin Bond

7 Hard Tooth Tissues/Resin Bond

7.1 Mechanism of Resin/Enamel-Dentin Bond

7.2 Etchants and Etching Process

7.3 Classification

7.4 Formulation

7.5 Total-Etch Adhesives

7.5.1 3-Step Adhesives

7.5.2 2-Step Adhesives

7.6 Self-Etch Adhesives

7.6.1 2-Step Adhesives

7.6.2 1-Step Adhesives

7.7 Requirements and Properties

7.8 Creation of Dentin Bond - Smear and Hybrid Layer

7.8.1 Total-Etch Technique - Smear Layer Removal

7.8.2 Self-Etch Technique - Smear Layer Fixation and Hybrid Layer Creation

7.8.3 Adverse Effects on the Adhesive/Dentin Bonding Zone

7.9 Biocompatibility

8 Resin-Based Luting Composites

8.1 Conventional Luting Resin Composites

8.2 Self-Etch Luting Resin Composites

8.3 Self-Adhesive Luting Resin Composites

9 Bacterial Adhesion to Resins

Curriculum Vitae

Literature

Index

Advanced Level of Dental Resins - Material Science & Technology

Подняться наверх