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Table of Contents

1. What is Peat?

By the general term Peat, we understand the organic matter or vegetable soil of bogs, swamps, beaver-meadows and salt-marshes.

It consists of substances that have resulted from the decay of many generations of aquatic or marsh plants, as mosses, sedges, coarse grasses, and a great variety of shrubs, mixed with more or less mineral substances, derived from these plants, or in many cases blown or washed in from the surrounding lands.

2. The conditions under which Peat is formed.

In this country the production of Peat from fallen and decaying plants, depends upon the presence of so much water as to cover or saturate the vegetable matters, and thereby hinder the full access of air. Saturation with water also has the effect to maintain the decaying matters at a low temperature, and by these two causes in combination, the process of decay is made to proceed with great slowness, and the solid products of such slow decay, are compounds that themselves resist decay, and hence they accumulate.

In the United States there appears to be nothing like the extensive moors or heaths, that abound in Ireland, Scotland, the north of England, North Germany, Holland, and the elevated plains of Bavaria, which are mostly level or gently sloping tracts of country, covered with peat or turf to a depth often of 20, and sometimes of 40, or more, feet. In this country it is only in low places, where streams become obstructed and form swamps, or in bays and inlets on salt water, where the flow of the tide furnishes the requisite moisture, that our peat-beds occur. If we go north-east as far as Anticosti, Labrador, or Newfoundland, we find true moors. In these regions have been found a few localities of the Heather (Calluna vulgaris), which is so conspicuous a plant on the moors of Europe, but which is wanting in the peat-beds of the United States.

In the countries above named, the weather is more uniform than here, the air is more moist, and the excessive heat of our summers is scarcely known. Such is the greater humidity of the atmosphere that the bog-mosses—the so-called Sphagnums—which have a wonderful avidity for moisture, (hence used for packing plants which require to be kept moist on journeys), are able to keep fresh and in growth during the entire summer. These mosses decay below, and throw out new vegetation above, and thus produce a bog, especially wherever the earth is springy. It is in this way that in those countries, moors and peat-bogs actually grow, increasing in depth and area, from year to year, and raise themselves above the level of the surrounding country.

Prof. Marsh informs the writer that he has seen in Ireland, near the north-west coast, a granite hill, capped with a peat-bed, several feet in thickness. In the Bavarian highlands similar cases have been observed, in localities where the atmosphere and the ground are kept moist enough for the growth of moss by the extraordinary prevalence of fogs. Many of the European moors rise more or less above the level of their borders towards the centre, often to a height of 10 or 20 and sometimes of 30 feet. They are hence known in Germany as high moors (Hochmoore) to distinguish from the level or dishing meadow-moors, (Wiesenmoore). The peat-producing vegetation of the former is chiefly moss and heather, of the latter coarse grasses and sedges.

In Great Britain the reclamation of a moor is usually an expensive operation, for which not only much draining, but actual cutting out and burning of the compact peat is necessary.

The warmth of our summers and the dryness of our atmosphere prevent the accumulation of peat above the highest level of the standing water of our marshes, and so soon as the marshes are well drained, the peat ceases to form, and in most cases the swamp may be easily converted into good meadow land.

Springy hill-sides, which in cooler, moister climates would become moors, here dry up in summer to such an extent that no peat can be formed upon them.

As already observed, our peat is found in low places. In many instances its accumulation began by the obstruction of a stream. To that remarkable creature, the beaver, we owe many of our peat-bogs. These animals, from time immemorial, have built their dams across rivers so as to flood the adjacent forest. In the rich leaf-mold at the water's verge, and in the cool shade of the standing trees, has begun the growth of the sphagnums, sedges, and various purely aquatic plants. These in their annual decay have shortly filled the shallow borders of the stagnating water, and by slow encroachments, going on through many years, they have occupied the deeper portions, aided by the trees, which, perishing, give their fallen branches and trunks, towards completing the work. The trees decay and fall, and become entirely converted into peat; or, as not unfrequently happens, especially in case of resinous woods, preserve their form, and to some extent their soundness.

In a similar manner, ponds and lakes are encroached upon; or, if shallow, entirely filled up by peat deposits. In the Great Forest of Northern New York, the voyager has abundant opportunity to observe the formation of peat-swamps, both as a result of beaver dams, and of the filling of shallow ponds, or the narrowing of level river courses. The formation of peat in water of some depth greatly depends upon the growth of aquatic plants, other than those already mentioned. In our Eastern States the most conspicuous are the Arrow-head, (Sagittaria); the Pickerel Weed, (Pontederia;) Duck Meat, (Lemna;) Pond Weed, (Potamogeton;) various Polygonums, brothers of Buckwheat and Smart-weed; and especially the Pond Lilies, (Nymphœa and Nuphar). The latter grow in water four or five feet deep, their leaves and long stems are thick and fleshy, and their roots, which fill the oozy mud, are often several inches in diameter. Their decaying leaves and stems, and their huge roots, living or dead, accumulate below and gradually raise the bed of the pond. Their living foliage which often covers the water almost completely for acres, becomes a shelter or support for other more delicate aquatic plants and sphagnums, which, creeping out from the shore, may so develop as to form a floating carpet, whereon the leaves of the neighboring wood, and dust scattered by the wind collect, bearing down the mass, which again increases above, or is reproduced until the water is filled to its bottom with vegetable matter.

It is not rare to find in our bogs, patches of moss of considerable area concealing deep water with a treacherous appearance of solidity, as the hunter and botanist have often found to their cost. In countries of more humid atmosphere, they are more common and attain greater dimensions. In Zealand the surfaces of ponds are so frequently covered with floating beds of moss, often stout enough to bear a man, that they have there received a special name "Hangesak." In the Russian Ural, there occur lakes whose floating covers of moss often extend five or six feet above the water, and are so firm that roads are made across them, and forests of large fir-trees find support. These immense accumulations are in fact floating moors, consisting entirely of peat, save the living vegetation at the surface.

Sometimes these floating peat-beds, bearing trees, are separated by winds from their connection with the shore, and become swimming peat islands. In a small lake near Eisenach, in Central Germany, is a swimming island of this sort. Its diameter is 40 rods, and it consists of a felt-like mass of peat, three to five feet in depth, covered above by sphagnums and a great variety of aquatic plants. A few birches and dwarf firs grow in this peat, binding it together by their roots, and when the wind blows, they act as sails, so that the island is constantly moving about upon the lake.

On the Neusiedler lake, in Hungary, is said to float a peat island having an area of six square miles, and on lakes of the high Mexican Plateau are similar islands which, long ago, were converted in fruitful gardens.

3. The different kinds of Peat.

Very great differences in the characters of the deposits in our peat-beds are observable. These differences are partly of color, some peats being gray, others red, others again black; the majority, when dry, possess a dark brown-red or snuff color. They also vary remarkably in weight and consistency. Some are compact, destitute of fibres or other traces of the vegetation from which they have been derived, and on drying, shrink greatly and yield tough dense masses which burn readily, and make an excellent fuel. Others again are light and porous, and remain so on drying; these contain intermixed vegetable matter that is but little advanced in the peaty decomposition. Some peats are almost entirely free from mineral matters, and on burning, leave but a few per cent. of ash, others contain considerable quantities of lime or iron, in chemical combination, or of sand and clay that have been washed in from the hills adjoining the swamps. As has been observed, the peat of some swamps is mostly derived from mosses, that of others originates largely from grasses; some contain much decayed wood and leaves, others again are free from these.

In the same swamp we usually observe more or less of all these differences. We find the surface peat is light and full of partly decayed vegetation, while below, the deposits are more compact. We commonly can trace distinct strata or layers of peat, which are often very unlike each other in appearance and quality, and in some cases the light and compact layers alternate so that the former are found below the latter.

The light and porous kinds of peat appear in general to be formed in shallow swamps or on the surface of bogs, where there is considerable access of air to the decaying matters, while the compacter, older, riper peats are found at a depth, and seem to have been formed beneath the low water mark, in more complete exclusion of the atmosphere, and under a considerable degree of pressure.

The nature of the vegetation that flourishes in a bog, has much effect on the character of the peat. The peats chiefly derived from mosses that have grown in the full sunlight, have a yellowish-red color in their upper layers, which usually becomes darker as we go down, running through all shades of brown until at a considerable depth it is black. Peats produced principally from grasses are grayish in appearance at the surface, being full of silvery fibres—the skeletons of the blades of grasses and sedges, while below they are commonly black.

Moss peat is more often fibrous in structure, and when dried forms somewhat elastic masses. Grass peat, when taken a little below the surface, is commonly destitute of fibres; when wet, is earthy in its look, and dries to dense hard lumps.

Where mosses and grasses have grown together simultaneously in the same swamp, the peat is modified in its characters accordingly. Where, as may happen, grass succeeds moss, or moss succeeds grass, the different layers reveal their origin by their color and texture. At considerable depths, however, where the peat is very old, these differences nearly or entirely disappear.

The geological character of a country is not without influence on the kind of peat. It is only in regions where the rocks are granitic or silicious, where, at least, the surface waters are free or nearly free from lime, that mosses make the bulk of the peat.

In limestone districts, peat is chiefly formed from grasses and sedges.

This is due to the fact that mosses (sphagnums) need little lime for their growth, while the grasses require much; aquatic grasses cannot, therefore, thrive in pure waters, and in waters containing the requisite proportion of lime, grasses and sedges choke out the moss.

The accidental admixtures of soil often greatly affect the appearance and value of a peat, but on the whole it would appear that its quality is most influenced by the degree of decomposition it has been subjected to.

In meadows and marshes, overflowed by the ocean tides, we have salt-peat, formed from Sea-weeds (Algæ,) Salt-wort (Salicornia,) and a great variety of marine or strand-plants. In its upper portions, salt-peat is coarsely fibrous from the grass roots, and dark-brown in color. At sufficient depth it is black and destitute of fibres.

The fact that peat is fibrous in texture shows that it is of comparatively recent formation, or that the decomposition has been arrested before reaching its later stages. Fibrous peat is found near the surface, and as we dig down into a very deep bed we find almost invariably that the fibrous structure becomes less and less evident until at a certain depth it entirely disappears.

It is not depth simply, but age or advancement in decomposition, which determines these differences of texture.

The "ripest," most perfectly formed peat, that in which the peaty decomposition has reached its last stage—which, in Germany, is termed pitchy-peat or fat peat, (Pechtorf, Specktorf)—is dark-brown or black in color, and comparatively heavy and dense. When moist, it is firm, sticky and coherent almost like clay, may be cut and moulded to any shape. Dried, it becomes hard, and on a cut or burnished surface takes a luster like wax or pitch.

In Holland, West Friesland, Holstein, Denmark and Pomerania, a so-called mud-peat (Schlammtorf, also Baggertorf and Streichtorf,) is "fished up" from the bottoms of ponds, as a black mud or paste, which, on drying, becomes hard and dense like the pitchy-peat.

The two varieties of peat last named are those which are most prized as fuel in Europe.

Vitriol peat is peat of any kind impregnated with sulphate of iron (copperas,) and sulphate of alumina, (the astringent ingredient of alum.)

Swamp Muck.—In New England, the vegetable remains occurring in swamps, etc., are commonly called Muck. In proper English usage, muck is a general term for manure of any sort, and has no special application to the contents of bogs. With us, however, this meaning appears to be quite obsolete, though in our agricultural literature—formerly, more than now, it must be admitted—the word as applied to the subject of our treatise, has been qualified as Swamp Muck.

In Germany, peat of whatever character, is designated by the single word Torf; in France it is Tourbe, and of the same origin is the word Turf, applied to it in Great Britain. With us turf appears never to have had this signification.

Peat, no doubt, is a correct name for the substance which results from the decomposition of vegetable matters under or saturated with water, whatever its appearance or properties. There is, however, with us, an inclination to apply this word particularly to those purer and more compact sorts which are adapted for fuel, while to the lighter, less decomposed or more weathered kinds, and to those which are considerably intermixed with soil or silt, the term muck or swamp muck is given. These distinctions are not, indeed, always observed, and, in fact, so great is the range of variation in the quality of the substance, that it would be impossible to draw a line where muck leaves off and peat begins. Notwithstanding, a rough distinction is better than none, and we shall therefore employ the two terms when any greater clearness of meaning can be thereby conveyed.

It happens, that in New England, the number of small shallow swales, that contain unripe or impure peat, is much greater than that of large and deep bogs. Their contents are therefore more of the "mucky" than of the "peaty" order, and this may partly account for New England usage in regard to these old English words.

By the term muck, some farmers understand leaf-mold (decayed leaves), especially that which collects in low and wet places. When the deposit is deep and saturated with water, it may have all the essential characters of peat. Ripe peat, from such a source is, however, so far as the writer is informed, unknown to any extent in this country. We might distinguish as leaf-muck the leaves which have decomposed under or saturated with water, retaining the well established term leaf-mold to designate the dry or drier covering of the soil in a dense forest of deciduous trees.

Salt-mud.—In the marshes, bays, and estuaries along the sea-shore, accumulate large quantities of fine silt, brought down by rivers or deposited from the sea-water, which are more or less mixed with finely divided peat or partly decomposed vegetable matters, derived largely from Sea-weed, and in many cases also with animal remains (mussels and other shell-fish, crabs, and myriads of minute organisms.) This black mud has great value as a fertilizer.

4. The Chemical Characters and Composition of Peat.

The process of burning, demonstrates that peat consists of two kinds of substance; one of which, the larger portion, is combustible, and is organic or vegetable matter; the other, smaller portion, remaining indestructible by fire is inorganic matter or ash. We shall consider these separately.

a. The organic or combustible part of peat varies considerably in its proximate composition. It is in fact an indefinite mixture of several or perhaps of many compound bodies, whose precise nature is little known. These bodies have received the collective names Humus and Geine. We shall employ the term humus to designate this mixture, whether occurring in peat, swamp-muck, salt-mud, in composts, or in the arable soil. Its chemical characters are much the same, whatever its appearance or mode of occurrence; and this is to be expected since it is always formed from the same materials and under essentially similar conditions.

Resinous and Bituminous matters.—If dry pulverized peat be agitated and warmed for a short time with alcohol, there is usually extracted a small amount of resinous and sometimes of bituminous matters, which are of no account in the agricultural applications of peat, but have a bearing on its value as fuel.

Ulmic and Humic acids.—On boiling what remains from the treatment with alcohol, with a weak solution of carbonate of soda (sal-soda), we obtain a yellowish-brown or black liquid. This liquid contains certain acid ingredients of the peat which become soluble by entering into chemical combination with soda.

On adding to the solution strong vinegar, or any other strong acid, there separates a bulky brown or black substance, which, after a time, subsides to the bottom of the vessel as a precipitate, to use a chemical term, leaving the liquid of a more or less yellow tinge. This deposit, if obtained from light brown peat, is ulmic acid; if from black peat, it is humic acid. These acids, when in the precipitated state, are insoluble in vinegar; but when this is washed away, they are considerably soluble in water. They are, in fact, modified by the action of the soda, so as to acquire much greater solubility in water than they otherwise possess. On drying the bulky bodies thus obtained, brown or black lustrous masses result, which have much the appearance of coal.

Ulmin and Humin.—After extracting the peat with solution of carbonate of soda, it still contains ulmin or humin. These bodies cannot be obtained in the pure state from peat, since they are mixed with more or less partially decomposed vegetable matters from which they cannot be separated without suffering chemical change. They have been procured, however, by the action of muriatic acid on sugar. They are indifferent in their chemical characters, are insoluble in water and in solution of carbonate of soda; but upon heating with solution of hydrate of soda they give dark-colored liquids, being in fact converted by this treatment into ulmic and humic acids, respectively, with which they are identical in composition.

The terms ulmic and humic acids do not refer each to a single compound, but rather to a group of bodies of closely similar appearance and properties, which, however, do differ slightly in their characteristics, and differ also in composition by containing more or less of oxygen and hydrogen in equal equivalents.

After complete extraction with hydrate of soda, there remains more or less undecomposed vegetable matter, together with sand and soil, were these contained in the peat.

Crenic and apocrenic acids.—From the usually yellowish liquid out of which the ulmic and humic acids have been separated, may further be procured by appropriate chemical means, not needful to be detailed here, two other bodies which bear the names respectively of Crenic Acid and Apocrenic Acid. These acids were discovered by Berzelius, the great Swedish chemist, in the water and sediment of the Porla spring, in Sweden.

By the action upon peat of carbonate of ammonia, which is generated to some extent in the decay of vegetable matters and is also absorbed from the air, ulmic and humic acids are made soluble, and combine with the ammonia as well as with lime, oxide of iron, etc. In some cases the ulmates and humates thus produced may be extracted from the peat by water, and consequently occur dissolved in the water of the swamp from which the peat is taken, giving it a yellow or brown color.

Ulmates and Humates.—Of considerable interest to us here, are the properties of the compounds of these acids, that may be formed in peat when it is used as an ingredient of composts. The ulmates and humates of the alkalies, viz.: potash, soda, and ammonia, dissolve readily in water. They are formed when the alkalies or their carbonates act on ulmin and humin, or upon ulmates or humates of lime, iron, etc. Their dilute solutions are yellow, or brown.

The ulmates and humates of lime, magnesia, oxide of iron, oxide of manganese and alumina, are insoluble, or nearly so in water.

In ordinary soils, the earths and oxides just named, predominate over the alkalies, and although they may contain considerable ulmic and humic acids, water is able to extract but very minute quantities of the latter, on account of the insolubility of the compounds they have formed.

On the other hand, peat, highly manured garden soil, leaf-mold, rotted manure and composts, yield yellow or brown extracts with water, from the fact that alkalies are here present to form soluble compounds.

An important fact established by Mulder is, that when solutions of alkali-carbonates are put in contact with the insoluble ulmates and humates, the latter are decomposed; soluble alkali-ulmates and humates being formed, and in these, a portion of the otherwise insoluble ulmates and humates dissolve, so that thus, in a compost, lime, magnesia, oxide of iron, and even alumina may exist in soluble combinations, by the agency of these acids.

Crenates and Apocrenates.—The ulmic and humic acids when separated from their compounds, are nearly insoluble, and, so far as we know, comparatively inert bodies; by further change, (uniting with oxygen) they pass into or yield the crenic and apocrenic acids which, according to Mulder, have an acid taste, being freely soluble in water, and in all respects, decided acids. The compounds of both these acids with the alkalies are soluble. The crenates of lime, magnesia, and protoxide of iron are soluble, crenates of peroxide of iron and of oxide of manganese are but very slightly soluble; crenate of alumina is insoluble. The apocrenates of iron and manganese are slightly soluble; those of lime, magnesia, and alumina are insoluble. All the insoluble crenates and apocrenates, are soluble in solutions of the corresponding salts of the alkalies.

Application of these facts will be given in subsequent paragraphs. It may be here remarked, that the crenate of protoxide of iron is not unfrequently formed in considerable quantity in peat-bogs, and dissolving in the water of springs gives them a chalybeate character. Copious springs of this kind occur at the edge of a peat-bed at Woodstock, Conn., which are in no small repute for their medicinal qualities, having a tonic effect from the iron they contain. Such waters, on exposure to the air, shortly absorb oxygen, and the substance is thereby converted into crenate and afterwards into apocrenate of peroxide of iron, which, being but slightly soluble, or insoluble, separates as a yellow or brown ochreous deposit along the course of the water. By further exposure to air the organic acid is oxidized to carbonic acid, and hydrated oxide of iron remains. Bog-iron ore appears often to have originated in this way.

Gein and Geic acid.—Mulder formerly believed another substance to exist in peat which he called Gein, and from this by the action of alkalies he supposed geic acid to be formed. In his later writings, however, he expresses doubt as to the existence of such a substance, and we may omit further notice of it, especially since, if it really do occur, its properties are not distinct from those of humic acid.

We should not neglect to remark, however, that the word gein has been employed by some writers in the sense in which we use humus, viz.: to denote the brown or black products of the decomposition of vegetable matters.

It is scarcely to be doubted that other organic compounds exist in peat. As yet, however, we have no knowledge of any other ingredients, while it appears certain that those we have described are its chief constituents, and give it its peculiar properties. With regard to them it must nevertheless be admitted, that our chemical knowledge is not entirely satisfactory, and new investigations are urgently demanded to supply the deficiencies of the researches so ably made by Mulder, more than twenty years ago.

Elementary Composition of Peat.

After this brief notice of those organic compounds that have been recognized in or produced from peat, we may give attention to the elementary composition of peat itself.

Like that of the vegetation from which it originates, the organic part of peat consists of Carbon, Hydrogen, Oxygen and Nitrogen. In the subjoined table are given the proportions of these elements as found in the combustible part of sphagnum, of several kinds of wood, and in that of a number of peats in various stages of ripeness. They are arranged in the order of their content of carbon.