Читать книгу Electron Transfer - Shunichi Fukuzumi - Страница 2

1  Cover

2  Acknowledgments

3  1 Introduction

4  2 Marcus Theory of Electron Transfer

5  3 Photosynthetic Reaction Center Models

6  4 Electron Donor–Acceptor Dyads

7  5 Supramolecular Electron Transfer 5.1 Cation–Anion Binding 5.2 π‐Complexes 5.3 Electron‐Transfer Switching 5.4 Dendrimers 5.5 Supramolecular Solar Cells

8  6 Effects of Metal Ions on Photoinduced Electron Transfer

9  7 Photoredox Catalysis 7.1 Photocatalytic Oxygenation 7.2 Photocatalytic Oxibromination 7.3 CarbonCarbon Bond Formation 7.4 DNA Cleavage 7.5 Anti‐Markovnikov Hydroetherification 7.6 Photocatalytic Cycloaddition 7.7 Photocatalytic Hydrotrifluoromethylation 7.8 Photocatalytic Hydrogen Evolution

10  8 Hydrogen Storage 8.1 Interconversion Between Hydrogen and Formic Acid 8.2 Interconversion Between Hydrogen and NADH 8.3 Hydrogen Evolution from Alcohols 8.4 Hydrogen Evolution from Paraformaldehyde

11  9 Metal Ion‐Coupled Electron Transfer (MCET) 9.1 MCET of O2 9.2 Binding Modes of Metal Ions 9.3 Self‐Organized MCET 9.4 Accelerating and Decelerating Effects of Metal Ions 9.5 Driving Force Dependence of MCET Rate Constants 9.6 MCET Coupled with Hydrogen Bonding 9.7 MCET Catalysis 9.8 MCET of Metal‐Oxo Complexes 9.9 PCET of Metal‐Oxo Complexes 9.10 Unified Mechanism of MCET and PCET of Metal‐Oxo Complexes 9.11 MCET of Metal‐Peroxo Complexes

12  10 Catalytic Reduction of O₂

13  11 Catalytic Oxidation of H₂O

14  12 Production of Hydrogen Peroxide from Water and Oxygen as a Solar Fuel

15  13 Production and Usage of Hydrogen Peroxide as a Solar Fuel in Seawater

16  14 Photosystem II Mimic

17  15 Conclusion and Perspective

18  References

19  Index

20  End User License Agreement