Читать книгу Henley's Formulas, Recipes and Processes (Applied Chemistry) - Various - Страница 409
BATTERY FILLERS AND SOLUTIONS.
ОглавлениеI.—In the so-called dry batteries the exciting substance is a paste instead of a fluid; moisture is necessary to cause the reaction. These pastes are generally secret preparations. One of the earlier “dry” batteries is that of Gassner. The apparatus consists of a containing vessel of zinc, which forms the positive element; the negative one is a cylinder of carbon, and the space between is filled with a paste, the recipe for which is:
| Oxide of zinc | 1 part |
| Sal ammoniac | 1 part |
| Plaster | 3 parts |
| Chloride of zinc | 1 part |
| Water | 2 parts |
The usual form of chloride-of-silver battery consists of a sealed cell containing a zinc electrode, the two being generally separated by some form of porous septum. Around the platinum or silver electrode is cast a quantity of silver chloride. This is melted and generally poured into molds surrounding the metallic electrode. The exciting fluid is either a solution of ammonium chloride, caustic potassa, or soda, or zinc sulphate. As ordinarily constructed, these cells contain a paste of the electrolyte, and are sealed up hermetically in glass or hard-rubber receptacles.
II.—The following formula is said to yield a serviceable filling for dry batteries:
| Charcoal | 3 ounces |
| Graphite | 1 ounce |
| Manganese dioxide | 3 ounces |
| Calcium hydrate | 1 ounce |
| Arsenic acid | 1 ounce |
| Glucose mixed with dextrine or starch | 1 ounce |
Intimately mix, and then work into a paste of proper consistency with a saturated solution of sodium and ammonium chlorides containing one-tenth of its volume of a mercury-bichloride solution and an equal volume of hydrochloric acid. Add the fluid gradually, and well work up the mass.
| III.— | Calcium chloride, crystallized | 30 parts |
|---|---|---|
| Calcium chloride, granulated | 30 parts | |
| Ammonium sulphate | 15 parts | |
| Zinc sulphate | 25 parts |