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(2) Compressibility and Expansibility of the air

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57. Effect of Pressure on Liquids and Gases.—Both classes of fluids, liquids and gases, have many characteristics in common. Both are composed of molecules that move freely; hence both flow. At any point within a fluid the pressure is the same in all directions. Archimedes' Principle applies, therefore, to both liquids and gases.

We now come to an important difference between liquids and gases. Liquids are practically incompressible. "So much so, that if water is subjected to a pressure of 3000 kg. per sq. cm., its volume is reduced only about one-tenth." Gases show a very different behavior from liquids on being subjected to pressure. They may readily be compressed to a small fraction of their volume as is noticed on inflating a pneumatic tire. A gas has also the ability to spring back to a larger volume as soon as the pressure is released, as when a cork is driven from a pop gun. Not only is compressed air able to expand, but air under ordinary conditions will expand if it is released in a space where the pressure is less.

Hollow bodies, animals and plants, are not crushed by atmospheric pressure, because the air and gases contained within exert as much force outward as the air exerts inward.

58. Boyle's Law.—The relation between the volume and pressure of a gas was first investigated by Robert Boyle in the seventeenth century. The experiment by which he first discovered the law or the relation between the volume and the pressure of a gas is briefly described as follows:

Figs. 37 a and 37 b.—Boyle's law apparatus.

A glass tube is bent in the form of the capital letter J, the short arm being closed. A little mercury is poured in to cover the bend. (See Fig. 37 a.) Since the mercury is at the same level in both arms, the pressure in (A) is the same as in (B). Mercury is now poured into (A) until it stands in the long tube at a height above that in (B) which is equal to the height of the mercury column of the barometer. (See Fig. 37 b.) The air in (BC) is now under a pressure of two atmospheres (one atmosphere is due to the mercury column). On measurement the air in (BC) will be found to have just one-half of its original volume.

Thus doubling the pressure to which a gas is subjected reduces its volume to one-half. Tripling the pressure, reduces the volume to one-third and so on.

Careful experiments reveal the following law: The volume of a given mass of gas at constant temperature is inversely proportional to the pressure to which it is subjected.

This law is often expressed mathematically. P/P´ = V´/V, or PV = P´V´. Since doubling the pressure reduces the volume one-half, it doubles the density. Tripling the pressure triples the density. We therefore have P/P´ = D/D´ or the density of a gas directly proportional to its pressure.

Fig. 38.—Height and density of the air.

59. Height of the Atmosphere.—From its properties of compression and expansion, the air varies in density and pressure as one ascends in it. At a height of 3 miles the pressure is reduced to about one-half. This is an indication that one-half of the air is below this level. Balloonists have gone to a height of 7 miles, Glaser and Coxwell in England in 1862 and Berson in France in 1901. The atmosphere has been explored to a height of 30,500 meters (18.95 miles) by sending up self-registering barometers in small balloons which burst at great altitudes. A parachute protects the instruments from breakage from too rapid fall. This height of 30,500 meters was reached by a balloon sent up by William R. Blair, at Huron, South Dakota, September 1, 1910.

At a height of 35 miles, the density is estimated at ⅓0,000 of its value at sea-level. (See Fig. 38.) It is believed that some rarefied air exists for a considerable distance above this point, some estimates placing the extent at 100 miles, and others from 200 to 500 miles. Evidences of some air at such heights are shown by: (a) the height at which meteors first appear, (b) the height of the Aurora Borealis, and (c), the distance that the sun is below the horizon when the last traces of color disappear from the sky in the evening.

Although the exact limits of the atmosphere are unknown, the weight of a column of air 1 sq. cm. in cross-section, and extending upward as high as the atmosphere, may be accurately computed. For this column of air exactly balances the column of mercury in the tube of the barometer.

Below sea-level, the air increases rapidly in density and it is estimated that at a depth of 35 miles, the density of the air would be a thousand times that at the earth's surface, or more than that of water.

Physics

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