Читать книгу Petroleum Refining Design and Applications Handbook - A. Kayode Coker - Страница 41
VESSELS (STORAGE TANKS)
Оглавление1 1. For less than 3.8 m3 (1000 gal.), use vertical tanks on legs.
2 2. For 3.8–38 m3 (1000–10,000 gal.), use horizontal tanks on concrete supports.
3 3. Beyond 38 m3 (10,000 gal.) use vertical tanks on concrete foundations.
4 4. Liquids subject to breathing losses may be stored in tanks with floating or expansion roofs for conservation.
5 5. Freeboard is 15% below 1.9 m3 (500 gal.) and 10% above 1.9 m3 (500 gal.) capacity.
6 6. A 30-day capacity often is specified for raw materials and products but depends on connecting transportation equipment schedules.
7 7. Capacities of storage tanks are at least 1.5 times the size of connecting transportation equipment; for instance, 28.4-m3 (7500 gal.) tanker trucks, 130-m3 (34,500 gal.) rail cars, and virtually unlimited barge and tanker capacities.
Source: The above mentioned rules of thumb have been adapted from Walas, S.M., Chemical Process Equipment: Selection and Design, copyright 1988 with permission from Elsevier, all rights reserved.
Physical Properties Heuristics.
Units | Liquids | Liquids | Gases | Gases | Gases | |
---|---|---|---|---|---|---|
Water | Organic material | Steam | Air | Organic material | ||
Heat capacity | kJ/kg °C | 4.2 | 1.0–2.5 | 2.0 | 1.0 | 2.0–4.0 |
Density | kg/m3 | 1000 | 700–1500 | 1.29 at STP | ||
Latent heat | kJ/kg | 1200–2100 | 200–1000 | |||
Thermal conductivity | W/m °C | 0.55–0.70 | 0.10–0.20 | 0.025–0.07 | 0.025–0.05 | 0.02–0.06 |
Viscosity | kg/ms | 0°C 1.8 × 10−3 | Wide Range | 10–30 × 10−6 | 20–50 × 10−6 | 10–30 × 10−6 |
50°C 5.7 × 10−4 | ||||||
100°C 2.8 × 10−4 | ||||||
200°C 1.4 × 10−4 | ||||||
Prandtl no. | 1–15 | 10–1000 | 1.0 | 0.7 | 0.7–0.8 |
Source: Turton, R. et al., Analysis, Synthesis, and Design of Chemical Process, Prentice Hall International Series, 2001.
Typical Physical Property Variations with Temperature and Pressure.
Liquids | Liquids | Gases | Gases | |
---|---|---|---|---|
Property | Temperature | Pressure | Temperature | Pressure |
Density | Negligible | ρg = MW P/ZRT | ρg = MW P/ZRT | |
Viscosity | μ1 = AeB/T | Negligible | Significant only for >10 bar | |
Vapor pressure | P* = aeb/(T+c) | – | – | – |
Note: T is temperature (K), Tc is the critical Temperature (K), Tb is the normal boiling point (K), MV is molecular weight, P is pressure, Z is compressibility, R is the gas constant, and P* is the vapor pressure.
Source: Turton, R. et al., Analysis, Synthesis, and Design of Chemical Processes, Prentice Hall International Series, 2001.
Capacities of Process Units in Common Usagea.
Process unit | Capacity unit | Maximum value | Minimum value | Comment | |
---|---|---|---|---|---|
Horizontal vessel | Pressure (bar) | 400 | Vacuum | L/D typically 2–5 | |
Temperature (°C) | 400b | −200 | |||
Height (m) | 10 | 2 | |||
Diameter (m) | 2 | 0.3 | |||
L/D | 5 | 2 | |||
Vertical vessel | Pressure (bar) | 400 | 400 | L/D typically 2–5 | |
Temperature (°C) | 400b | −200 | |||
Height (m) | 10 | 2 | |||
Diameter (m) | 2 | 0.3 | |||
L/D | 5 | 2 | |||
Towers | Pressure (bar) | 400 | Vacuum | Normal Limits Diameter | L/D |
Temperature (°C) | 400b | −200 | 0.5 | 3.0–40c | |
Height (m) | 50 | 2 | 1.0 | 2.5–30c | |
Diameter (m) | 4 | 0.3 | 2.0 | 1.6–23c | |
L/D | 30 | 2 | 4.0 | 1.8–13c | |
Pumps | |||||
Reciprocating | Powerd (kW) | 250 | <0.1 | ||
Pressure (bar) | 1000 | ||||
Rotary and positive | Powerd (kW) | 150 | <0.1 | ||
Displacement | Pressure (bar) | 300 | |||
Centrifugal | Powerd (kW) | 250 | <0.1 | ||
Pressure (bar) | 300 | ||||
Compressors | |||||
Axial, Centrifugal + Recipr. | Powerd (kW) | 8000 | 50 | ||
Rotary | Powerd (kW) | 1000 | 50 | ||
Drives for compressor | |||||
Electric | Powere (kW) | 15,000 | <1 | ||
Steam turbine | Powere (kW) | 15,000 | 100 | ||
Gas turbine | Powere (kW) | 15,000 | 10 | ||
Internal combustion eng. | Powere (kW) | 15,000 | 10 | ||
Process heaters | Duty (MJ/h) | 500,000 | 10,000 | Duties different for reactive heaters/furnaces | |
Heat exchangers | Area (m2) | 1000 | 10 | For Area <10 m2 use | |
Tube Dia. (m) | 0.0254 | 0.019 | double-pipe exchanger | ||
Length (m) | 6.5 | 2.5 | |||
Pressure (bar) | 150 | Vacuum | For 150 < P < 400 bar | ||
Temperature (°C) | 400b | −200 | need special design |
aMost of the limits for equipment sizes shown here correspond to the limits used in the costing program (CAPCOST.BAS).
bMaximum temperature and pressure are related to the materials of construction and may differ from values shown here.
cFor 20 <L/D < 30 special design may be required. Diameter up to 7 m possible but over 4 m must be fabricated on site.
dPower values refer to fluid/pumping power.
ePower values refer to shaft power.
Source: Turton, R. et al., Analysis, Synthesis, and Design of Chemical Processes, Prentice Hall International Series, 2001.
Effect of Typical Materials of Construction on Product Color, Corrosion, Abrasion, and Catalytic Effects .
Metals | ||
---|---|---|
Material | Advantages | Disadvantages |
Carbon steel | Low cost, readily available, resists abrasion, standard fabrication, resists alkali | Poor resistance to acids and strong alkali, often causes discoloration and contamination |
Stainless steel | Resists most acids, reduces discoloration, available with a variety of alloys, abrasion less than mild steel | Not resistant to chlorides, more expensive, fabrication more difficult, alloy materials may have catalytic effects |
Monel–Nickel | Little discoloration, contamination, resistant to chlorides | Not resistant to oxidizing environments, expensive |
Hasteloy | Improved over Monel–Nickel | More expensive than Monel–Nickel |
Other exotic metals | Improves specific properties | Very high cost |
Non-metals | ||
Glass | Useful in laboratory and batch system, low diffusion at walls | Fragile, not resistant to high alkali, poor heat transfer, poor abrasion resistance |
Plastics | Good at low temperature, large variety to select from with various characteristics, easy to fabricate, seldom discolors, minor catalytic effects possible | Poor at high temperature, low strength, not resistant to high alkali conditions, low heat transfer, low cost |
Ceramics | Withstands high temperatures, variety of formulations available, modest cost | Poor abrasion properties, high diffusion at walls (in particular hydrogen), low heat transfer, may encourage catalytic reactions |
Source: Turton, R. et al., Analysis, Synthesis, and Design of Chemical Processes, Prentice Hall International Series, 2001.