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3 Vector Operations

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As indicated previously, a vector u is defined as a quantity possessing both a magnitude and a direction; the said magnitude is regularly denoted by ‖ u ‖, while information on the direction is often conveyed graphically – or else encompasses angles formed with the axes in some reference system. Two vectors, u and v, are said to be equal when their magnitudes are identical, i.e. ‖ u ‖ = ‖ v ‖, and also point in the same direction; however, they do not need to have the same origin.

A much more convenient way of handling vectors resorts, however, to their decomposition along the three directions of space in a typical Cartesian R3 domain, according to

(3.1)

and

(3.2)

here jx, jy, and jz denote unit, orthogonal vectors of a Cartesian system, defined as

(3.3)

(3.4)

and

(3.5)

– while

(3.6)

and

(3.7)

define u and v, respectively, via their coordinates.

According to Pythagoras’ theorem,

(3.8)

and likewise

(3.9)

this is a more general form than Eq. (2.431), yet it relies on application of the aforementioned theorem twice. In fact,

(3.10)

abides to Eq. (2.431), as long as ux and uy denote the projections of u onto the x‐ and y‐axis, respectively, and uxy denotes the projection of u onto the x0y plane; further application of Eq. (2.431) then supports

(3.11)

where uz denotes the projection of u onto the z‐axis. Insertion of Eq. (3.10) transforms Eq. (3.11) to

(3.12)

that retrieves Eq. (3.8), after taking square roots of both sides – as long as ∣ux ∣ ≡ ‖ ux ‖, ∣uy ∣ ≡ ‖ uy ‖, and ∣uz ∣ ≡ ‖ uz ‖; a similar reasoning obviously applies to vx, vy, and vz describing v . The general rules of trigonometry indicate, in turn, that angle θu (or θv) – formed with the y‐axis by the projection of u (or v) onto the y0z plane, is such that

(3.13)

and likewise

(3.14)

similar expressions can be laid out pertaining to angle ϕu (or ϕv) formed with the z‐axis by the projection of u (or v) onto the x0z plane, viz.

(3.15)

and similarly

(3.16)

Therefore, equality of u and v requires that ‖ u ‖ = ‖ v ‖ describing the same length, and θu = θv and ϕu = ϕv describing the same orientation – thus using up all three spatial degrees of freedom; upon inspection of the functional forms of Eqs. (3.8), (3.9), and (3.13)(3.16), one concludes that the said three equalities unequivocally enforce ux = vx, uy = vy, and uz = vz .

Mathematics for Enzyme Reaction Kinetics and Reactor Performance

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