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1.6.3 Plate Height

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The height equivalent to a theoretical plate H, as already defined (Eq. (1.4)), is calculated for reference compounds to permit a comparison of columns of different lengths. However, H does not behave as a constant; its value depends upon the compound chosen and upon the experimental conditions.

For a long time in gas chromatography, an adjustment value called the effective plate height Heff was calculated using the true efficiency, instead of the theoretical efficiency.

The calculation of Heff from the real efficiency uses Eq. (1.20):

(1.20)

Chemical Analysis

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