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1.6.2 Seawater
ОглавлениеTable 1.5 shows thermo‐physical properties of standard seawater at 40 000 ppm and 25 °C.
Note that the comprehensive thermo‐physical properties of seawater as a function of temperature and salinity are presented in Appendix A.
The major six elements that comprise about 99% of seawater are chlorine (Cl−), sodium (Na+), sulfate (SO42−), magnesium (Mg+2), calcium (Ca+2), and potassium (K+), and standard seawater composition at 35 000 ppm are presented in Table 1.6.
Table 1.6 Standard seawater composition at salinity equal to ≈35 000 ppm.
Chemical ion | Concentration (ppm) | Valence | Total salt content (%) | mmol/kg | Molecular weight |
Chlorine Cl− | 19 345 | −1 | 55.03 | 546 | 35.453 |
Sodium Na+ | 10 752 | +1 | 30.59 | 468 | 22.990 |
Sulfate SO42− | 2701 | −2 | 7.68 | 28.1 | 96.062 |
Magnesium Mg2+ | 1295 | +2 | 3.68 | 53.3 | 24.305 |
Calcium Ca2+ | 416 | +2 | 1.18 | 10.4 | 40.078 |
Potassium K+ | 390 | +1 | 1.11 | 9.97 | 39.098 |
Bicarbonate HCO3− | 145 | −1 | 0.41 | 2.34 | 61.016 |
Bromide Br− | 66 | −1 | 0.19 | 0.83 | 79.904 |
Borate BO33− | 27 | −3 | 0.08 | 0.46 | 58.808 |
Strontium Sr2+ | 13 | +2 | 0.04 | 0.091 | 87.620 |
Fluoride F− | 1 | −1 | 0.003 | 0.068 | 18.998 |
Σxi = 35 151 ppm |
Note that Cl makes up to 55% of salt in seawater and NaCl makes up to 86% of salt in seawater.