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It’s All in the Numbers: Carbon Bonds

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Carbon is capable of forming four bonds. In bonding to itself and other elements, carbon uses a variety of types of hybridization. When it bonds to other atoms, for example, possible hybridizations include four single bonds, one double and two single bonds, two double bonds, or a triple and a single bond. Double bonds to oxygen atoms are particularly important in many biochemicals. Table 3-1 shows the number of bonds carbon may form with some selected nonmetals, along with the hybridization of those bonds.

TABLE 3-1 Possible Bonds of Carbon and Selected Nonmetals

Element Number of Possible Bonds with Carbon Some Possible Hybridizations for Second Period Elements
Carbon (C) 4 4 single (sp3); 2 single and 1 double (sp2); 1 single and 1 triple (sp); 2 double (sp)
Nitrogen (N) 3 3 single (sp3); 1 single and 1 double (sp2); 1 triple (sp)
Oxygen (O) 2 2 single (sp3); 1 double (sp2)
Sulfur (S) 2 2 single (sp3); 1 double (sp2)
Hydrogen (H) 1 1 single
Fluorine (F) 1 1 single
Chlorine (Cl) 1 1 single
Bromine (Br) 1 1 single
Iodine (I) 1 1 single
Biochemistry For Dummies

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