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9LETTER 2
WHY A COPPER WIRE WILL CONDUCT ELECTRICITY

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My Dear Young Atomist:

You have learned that the simplest group which can be formed by protons and electrons is one proton and one electron chasing each other around in a fast game. This group is called an atom of hydrogen. A molecule of hydrogen is two of these groups together.

All the other possible kinds of groups are more complicated. The next simplest is that of the atom of helium. Helium is a gas of which small quantities are obtained from certain oil wells and there isn’t very much of it to be obtained. It is an inert gas, as we call it, because it won’t burn or combine with anything else. It doesn’t care to enter into the larger games of molecular groups. It is satisfied to be as it is, so that it isn’t much use in chemistry because you can’t make anything else out of it. That’s the reason why it is so highly recommended for filling balloons or airships, because it cannot burn or explode. It is not as light as hydrogen but it serves quite well for making balloons buoyant in air.

This helium atom is made up of four electrons and four protons. Right at the center there is a small closely crowded group which contains all the protons 10and two of the electrons. The other two electrons play around quite a little way from this inner group. It will make our explanations easier if we learn to call this inner group “the nucleus” of the atom. It is the center of the atom and the other two electrons play around about it just as the earth and Mars and the other planets play or revolve about the sun as a center. That is why we shall call these two electrons “planetary electrons.”

There are about ninety different kinds of atoms and they all have names. Some of them are more familiar than hydrogen and helium. For example, there is the iron atom, the copper atom, the sulphur atom and so on. Some of these atoms you ought to know and so, before telling you more of how atoms are formed by protons and electrons, I am going to write down the names of some of the atoms which we have in the earth and rocks of our world, in the water of the oceans, and in the air above.

Start first with air. It is a mixture of several kinds of gases. Each gas is a different kind of atom. There is just a slight trace of hydrogen and a very small amount of helium and of some other gases which I won’t bother you with learning. Most of the air, however, is nitrogen, about 78 percent in fact and almost all the rest is oxygen. About 20.8 percent is oxygen so that all the gases other than these two make up only about 1.2 percent of the atmosphere in which we live.


Pl. II.–Bird’s-eye View of Radio Central

(Courtesy of Radio Corporation of America).

11The earth and rocks also contain a great deal of oxygen; about 47.3 percent of the atoms which form earth and rocks are oxygen atoms. About half of the rest of the atoms are of a kind called silicon. Sand is made up of atoms of silicon and oxygen and you know how much sand there is. About 27.7 percent of the earth and its rocks is silicon. The next most important kind of atom in the earth is aluminum and after that iron and then calcium. Here is the way they run in percentages: Aluminum 7.8 percent; iron 4.5 percent; calcium 3.5 percent; sodium 2.4 percent; potassium 2.4 percent; magnesium 2.2 percent. Besides these which are most important there is about 0.2 percent of hydrogen and the same amount of carbon. Then there is a little phosphorus, a little sulphur, a little fluorine, and small amounts of all of the rest of the different kinds of atoms.

Sea water is mostly oxygen and hydrogen, about 85.8 percent of oxygen and 10.7 percent of hydrogen. That is what you would expect for water is made up of molecules which in turn are formed by two atoms of hydrogen and one atom of oxygen. The oxygen atom is about sixteen times as heavy as the hydrogen atom. However, for every oxygen atom there are two hydrogen atoms so that for every pound of hydrogen in water there are about eight pounds of oxygen. That is why there is about eight times as high a percentage of oxygen in sea water as there is of hydrogen.

Most of sea water, therefore, is just water, that is, pure water. But it contains some other substances as well and the best known of these is salt. Salt is a 12substance the molecules of which contain atoms of sodium and of chlorine. That is why sea water is about 1.1 percent sodium and about 2.1 percent chlorine. There are some other kinds of atoms in sea water, as you would expect, for it gets all the substances which the waters of the earth dissolve and carry down to it but they are unimportant in amounts.

Now we know something about the names of the important kinds of atoms and can take up again the question of how they are formed by protons and electrons. No matter what kind of atom we are dealing with we always have a nucleus or center and some electrons playing around that nucleus like tiny planets. The only differences between one kind of atom and any other kind are differences in the nucleus and differences in the number and arrangement of the planetary electrons which are playing about the nucleus.

No matter what kind of atom we are considering there is always in it just as many electrons as protons. For example, the iron atom is formed by a nucleus and twenty-six electrons playing around it. The copper atom has twenty-nine electrons as tiny planets to its nucleus. What does that mean about its nucleus? That there are twenty-nine more protons in the nucleus than there are electrons. Silver has even more planetary electrons, for it has 47. Radium has 88 and the heaviest atom of all, that of uranium, has 92.

We might use numbers for the different kinds of 13atoms instead of names if we wanted to do so. We could describe any kind of atom by telling how many planetary electrons there were in it. For example, hydrogen would be number 1, helium number 2, lithium of which you perhaps never heard, would be number 3, and so on. Oxygen is 8, sodium is 11, chlorine is 17, iron 26, and copper 29. For each kind of atom there is a number. Let’s call that number its atomic number.

Now let’s see what the atomic number tells us. Take copper, for example, which is number 29. In each atom of copper there are 29 electrons playing around the nucleus. The nucleus itself is a little inner group of electrons and protons, but there are more protons than electrons in it; twenty-nine more in fact. In an atom there is always an extra proton in the nucleus for each planetary electron. That makes the total number of protons and electrons the same.

About the nucleus of a copper atom there are playing 29 electrons just as if the nucleus was a teacher responsible for 29 children who were out in the play yard. There is one very funny thing about it all, however, and that is that we must think of the scholars as if they were all just alike so that the teacher couldn’t tell one from the other. Electrons are all alike, you remember. All the teacher or nucleus cares for is that there shall be just the right number playing around her. You could bring a boy in from some other play ground and the teacher couldn’t tell that he was a stranger but she would 14know that something was the matter for there would be one too many in her group. She is responsible for just 29 scholars, and the nucleus of the copper atom is responsible for just 29 electrons. It doesn’t make any difference where these electrons come from provided there are always just 29 playing around the nucleus. If there are more or less than 29 something peculiar will happen.

We shall see later what might happen, but first let’s think of an enormous lot of atoms such as there would be in a copper wire. A small copper wire will have in it billions of copper atoms, each with its planetary electrons playing their invisible game about their own nucleus. There is quite a little distance in any atom between the nucleus and any of the electrons for which it is responsible. There is usually a greater distance still between one atomic group and any other.

On the whole the electrons hold pretty close to their own circles about their own nuclei. There is always some tendency to run away and play in some other group. With 29 electrons it’s no wonder if sometimes one goes wandering off and finally gets into the game about some other nucleus. Of course, an electron from some other atom may come wandering along and take the place just left vacant, so that nucleus is satisfied.

We don’t know all we might about how the electrons wander around from atom to atom inside a copper wire but we do know that there are always a lot of them moving about in the spaces between 15the atoms. Some of them are going one way and some another.

It’s these wandering electrons which are affected when a battery is connected to a copper wire. Every single electron which is away from its home group, and wandering around, is sent scampering along toward the end of the wire which is connected to the positive plate or terminal of the battery and away from the negative plate. That’s what the battery does to them for being away from home; it drives them along the wire. There’s a regular stream or procession of them from the negative end of the wire toward the positive. When we have a stream of electrons like this we say we have a current of electricity.

We’ll need to learn more later about a current of electricity but one of the first things we ought to know is how a battery is made and why it affects these wandering electrons in the copper wire. That’s what I shall tell you in my next letter.[1]

[1]

The reader who wishes the shortest path to the construction and operation of a radio set should omit the next two letters.

Letters of a Radio-Engineer to His Son

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