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2.3 Polyols

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Polyols are characterized by the presence of several hydroxyl radicals in the same linear or cyclic molecule. In general, an accumulation of hydroxyl radicals in a compound raises the boiling point considerably (Table 2.2) due to the large number of hydrogen bonds, as well as increasing its viscosity and anti‐freeze properties. Parallel increases are observed in solubility and sweetness. Sugars are good examples of polyols.

TABLE 2.2 Impact of the Number of Hydroxyl Groups on the Boiling Point of Alcohols

Alcohols and polyols Boiling point(°C)
Ethanol CH3−CH2OH 78
Ethyleneglycol CH2OH−CH2OH 198
Glycerol CH2OH−CHOH−CH2OH 290
Handbook of Enology, Volume 2

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