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2.3.3 Multiple Energy Levels

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The multiple energy levels are possible by designing the stacks of solar cells on top of each cell with a different energy band gap to increase the absorption of light. The stacked structure of PV cell utilizes maximum sunlight and produces maximum energy conversion efficiency. The each cell should have same lattice parameters to decrease the energy losses [43]. The energy band gap values are summarized for various materials with their maximum absorption wavelength in Table 2.2. The band gap energy vs. λmax curve for different photoactive materials is shown in Figure 2.5.

Table 2.2 Energy band gap of various absorber and metal nanoparticles.

Material Energy band gap (eV) at 300K λmax (λ = hc/E = 1242/E) nm
Ge 0.66 1,881
Si 1.11 1,118
InP 1.27 977
CIGS 1.42 874
GaAs 1.43 868
CdTe 1.44 862
CZTS 1.5 828
CuO 1.7 730
CdSe 1.74 714
BiFeO3 2.09 594
Fe2O3 2.1 591
GaP 2.25 552
CdS 2.25 552
PbO 2.9 428
TiO2 3.2 388
SrTiO3 3.2 388
ZnO 3.4 365
SnO2 3.5 355
ZnS 3.6 345
SiO2 8.9 140
Fundamentals of Solar Cell Design

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