Читать книгу The Rheology Handbook - Thomas Mezger - Страница 81
Example 3: Hair shampoos containing surfactant superstructures
ОглавлениеIn the range of γ ̇ = 1 to 15 s-1 a shampoo displayed shear-thinning behavior and at γ ̇ = 30 s-1 occurred a dilatancy peak. The shampoo manufacturer wanted the shampoo to show a certain superstructure in this shear rate range, which corresponds to the process when flowing out of the shampoo bottle. Consumers then subconsciously believe that they have bought a liquid showing “body”. In this case, the goal was reached via superstructures, built up by visco-
elastic surfactants. (VES; see also Chapter 9.1.1d: worm-like micelles).
Note 3: Temperature-dependent shear thickening of elastomers .
Different temperatures can lead to fundamentally different kinds of flow behavior of filled and unfilled elastomers and rubber). mixtures.
Figure 3.19: Viscosity curve of a highly filled suspension showing immediate shear thickening when reaching the critical shear rate γ ̇ crit (“dilatant switch”)