Читать книгу The Romance of War Inventions - Thomas W. Corbin - Страница 4

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The origin of gunpowder appears to be lost in antiquity. At all events it has been in use for many centuries and is still made in many countries.

Most boys have tried to make it at some time or other and with varying degrees of success. Such experiments generally lead to a glorious blaze, a delightfully horrid smell and no harm to anyone, the experimenter owing his safety to his invariable lack of complete success, for although other and better explosives have superseded it for many purposes it is capable of doing a lot of harm when it is well made.

It consists of a mixture of charcoal, sulphur and saltpetre ground up very fine and mixed very intimately together. The mixture is wetted and pressed into cakes and dried, after which it is broken up into small pieces. The precise proportions of the various materials seem to vary a great deal in different countries, but generally speaking there is about 75 per cent of saltpetre (or to give it its scientific name, nitrate of potash), 15 per cent of charcoal and 10 per cent of sulphur.

Now gunpowder, like all explosives, is simply some thing or mixture of things which is capable of burning very quickly. When we light the fire we set going the process which we call combustion, or burning, and, as we know from our own experience, that process causes heat to be generated.

What takes place in the fire-grate is that the carbon of the coal enters into combination with oxygen from the air, the two together forming a new compound called "carbonic acid gas." There is nothing lost or destroyed in this process, the carbon and oxygen simply changing into the new substance, and could we weigh the gas produced we should find that it agreed precisely with the weight of the carbon and oxygen consumed. For the purpose for which we require the fire, namely, to heat the room, the chief feature about this process is not what is formed in the shape of gas, for that simply goes off up the chimney, but the heat which is liberated. We believe that in some mysterious way the heat is locked up in the coal. Latent is the term we use, which means hidden: in other words we believe that the heat is hidden in the coal: we cannot feel it or perceive it in any way, but it comes out when we let the carbon combine with the oxygen.

Why these two things combine at all is one of those mysteries which may never be solved. We have theories on the subject, but all we really know is that under certain conditions if they be in contact with one another they will combine, apparently for the simple reason that it is their nature so to do.

When we apply the match to the fire all we do is to set up the conditions under which the carbon and oxygen are able to follow their natural instincts, so to speak.

A coal fire, as we all know, burns slowly, for the simple reason that it is only at the surface of the lumps that carbon and oxygen are in contact. If we grind up the coal into a fine powder and then blow it into a cloud, so that every tiny particle is surrounded with air, a spark will cause an explosion. That is how these terrible explosions in coal-pits are caused.

This is sometimes seen on a small scale when one shakes the empty fire-shovel after putting coal on the fire to get rid of the fine dust adhering to it and to save making a mess in the fender. That little cloud of fine dust will often burst into flame like a mild explosion.

We see from this that to make an explosion we require fuel, just as we do to make a fire: but we need that it shall be very intimately mixed with oxygen, so that all of it can burn up in practically a single instant. Now in gunpowder we get these conditions fulfilled. We have the carbon in the shape of charcoal, we also have some sulphur which likewise burns readily, and we have saltpetre which contains oxygen.

Thus, you see, we do not need to go to the air for the oxygen, for the gunpowder possesses it already, locked up in the saltpetre. Moreover, we can see now why it is so important for all the materials to be ground up very fine, for it is only by so doing that we can ensure that every particle of charcoal or sulphur shall have particles of saltpetre close by ready to furnish oxygen at a moment's notice.

Another thing to be observed, for it lets us into the great key to the manufacture of nearly all explosives, is the scientific name of saltpetre. It is "nitrate of potassium," and all substances whose names begin with "nitr-" contain nitrogen: while the termination "ate" signifies the presence of oxygen. We need the oxygen to make the explosion but we do not need the nitrogen, yet the latter has to be present for without it the oxygen would be too slow in getting to work.

Nitrogen is one of the strangest substances on earth. Extremely lazy itself, it has the knack of hustling its companions, particularly oxygen, and making them work with tremendous fury. Whenever we get the lazy gas nitrogen to enter into a combination with other things we may confidently look for extraordinary activity of some sort.

So when we put a light to a quantity of gunpowder we set up those conditions under which the carbon and oxygen can combine, and at the same moment our lazy friend the nitrogen turns out his partner oxygen from the nitrate in which they were till then combined and a sudden burning is the result. The solid gunpowder is suddenly changed into a volume of hot gas 2500 times as great. That is to say, one cubic inch of gunpowder changes suddenly into 2500 cubic inches of gas. That sudden expansion to 2500 times its volume is what we term an explosion. If it takes place in an enclosed space so that the gas formed wants to expand but cannot, the result is a pressure of about forty tons per square inch.

If that enclosed space were the interior of a gun, that force of forty tons per square inch would be available for driving out the projectile.

Now, gunpowder is still used for sporting purposes and also for some special purposes in warfare, but it has the great disadvantage that it makes a lot of smoke, so that the enemy would be easily able to locate the guns were it to be used in them. As we know so well, by the messages from France, guns and rifles drop their shells and bullets apparently from nowhere and are extremely difficult to locate. That is owing to the use of improved powders one of the great features of which is their smokelessness.

The reason why gunpowder makes a dense smoke, is because the burning which takes place is very incomplete. Therefore, by some such means as a more intimate mixture of the materials a better and more complete burning must be brought about.

One of the best known of the new powders (they are all spoken of as powders, whatever their form, since they have taken the place of the old gunpowder) is nitro-glycerine, the basis of which is glycerine.

The way in which we obtain this useful material has already been explained. It consists of carbon, a lot of hydrogen and some oxygen. These are not merely mixed together but are in combination, just as oxygen and hydrogen are combined in water. Carbon and hydrogen will both combine with oxygen and will give off heat in the process, but in glycerine they are already happily united together and so glycerine itself is no use as an explosive. If, however, we bring nitric acid and sulphuric acid into contact with it a pair of new partnerships is set up, one being water and the other a compound containing carbon and hydrogen, a lot of oxygen and, most important of all, some of that disturbing, restless though lazy nitrogen.

This is nitro-glycerine, a particularly furious explosive, for that curious nitrogen seems to be so uncomfortable in his new surroundings that at the smallest provocation he will break up the whole combination and then there will be a mass of free atoms of carbon, hydrogen and oxygen, all seeking new partners, just right for a glorious explosion.

So furious and untamed is this stuff that it was almost useless until the famous Nobel hit upon the idea of taming it down by mixing it with an earth called Kieselguhr, which reduces its sensitiveness sufficiently to make it a very safe explosive to use. To this mixture Nobel gave the name of dynamite.

It is interesting at this point to compare the action of this typical modern explosive with that of the older gunpowder. The latter is only a mixture: the former is a chemical compound. The smallest particle of material in the gunpowder is a little lump containing millions of molecules and still more of atoms: when the nitrogen has broken up the original nitro-glycerine, just before the explosion actually takes place, we have a mixture of single atoms. Thus the mixture is far more intimate in the latter case and the burning is therefore quicker and more thorough.