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More equilibria – taller peaks

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The apex of the peak gets higher when the plate number increases. It actually gets very much higher because the peak area remains constant (the vertical axis in Figure 2.9 is not drawn to scale). A higher peak in the graph means there are more molecules in the detector and a larger detector output signal, making the peak easier to measure. The chromatogram baseline always suffers from a little detector signal noise, so a higher peak has a better signal‐to‐noise ratio.

Process Gas Chromatographs

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