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2.2.1Polyacrylate salts

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Polyacrylate salts are simple polymers which stabilise pigments in water-borne paints, mainly emulsion paints. They are characterised by their high acid value, which promotes good anchoring to inorganic pigments. The highly ionic character means that there is a strong tendency to dissociate in water and this allows good electrostatic repulsion, which is associated with outstanding viscosity reduction. Common counter cations are sodium and ammonium. Coatings containing ammonium-neutralised polyacrylates are more resistant to water than sodium-neutralised ones. In general, the water resistance of polyacrylate salts is rather weak.


Figure 2.6a: Structural example of a polyacrylate salt

Additives for Water-borne Coatings

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