Читать книгу Geochemistry - William M. White - Страница 61
2.9 THE THIRD LAW AND ABSOLUTE ENTROPY 2.9.1 Statement of the third law
ОглавлениеThe entropies of substances tend toward zero as absolute zero temperature is approached, or as Lewis and Randall expressed it:
If the entropy of each element in some crystalline state may be taken as zero at the absolute zero of temperature, every substance has a finite positive entropy, but at absolute zero, the entropy may become zero, and does so become in the case of perfectly crystalline substances.