Читать книгу Geochemistry - William M. White - Страница 64
2.10 CALCULATING ENTHALPY AND ENTROPY CHANGES 2.10.1 Enthalpy changes due to changes in temperature and pressure
ОглавлениеFrom eqn. 2.68, we can see that the temperature derivative of enthalpy is simply the isobaric heat capacity:
and hence:
(2.111)
Thus, the change in enthalpy over some temperature interval may be found as:
(2.112)
Cp is often a complex function of temperature, so the integration is essential. Example 2.4 illustrates how this is done.