Читать книгу Geochemistry - William M. White - Страница 75
2.11.4 Temperature and pressure dependence of the Gibbs free energy
ОглавлениеOne reason why the Gibbs free energy is useful is that its characteristic variables are temperature and pressure, which are the “external” variables of greatest interest in geochemistry. Since it is a state variable, we can deduce its temperature and pressure dependencies from eqn. 2.124, which are:
(2.128)
(2.129)