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(2) The States of Matter
Оглавление4. Physics Defined.—In the study of any science or field of knowledge, it is helpful to have a basis for grouping or classifying the facts studied. In physics we are to study the objects, forces, and changes about us, to understand them and their relations to one another. Accordingly, physics, dealing with the material world about us, is often defined as the science of matter and energy, matter being anything that occupies space and energy the capacity for doing work. This definition of physics while not strictly accurate is sufficiently comprehensive for our present purpose.
5. The Three States of Matter.—Our bodies are matter since they occupy space. Further, they possess energy since they are able to do work. In beginning the study of physics it will simplify our work if we study one of these topics before the other. We will therefore begin with matter and consider first its three states.
Some bodies are solid; as ice, iron, wax. Others are liquid; as water, mercury, oil. Still others are in the state of gas; as steam, air, and illuminating gas. Further we notice that the same substance may be found in any one of the three states. For example water may be either ice, water or steam; that is, either a solid, a liquid, or a gas.
Most persons have heard of liquid air and possibly some know of ice air, i.e., air cooled until it not only liquefies, but is solidified. On the other hand, iron may be melted and, if heated hot enough, may be turned into iron vapor. In fact most substances by heating or cooling sufficiently may be changed into any one of the three states.
Before defining the three states, let us consider the structure of matter. This may help us to answer the question: How is it possible to change a hard solid, such as ice, into a liquid, water, and then into an invisible gas like steam? This is explained by the molecular theory of matter.
6. The Molecular Theory of Matter.—It is believed that all bodies are made up of very small particles called molecules, and that these instead of being packed tightly together like square packages in a box, are, strange as it may seem, very loosely packed even in solids and do not permanently touch their neighbors. The size of these molecules is so minute that it has been estimated that if a drop of water could be magnified to the size of the earth, the molecules magnified in the same proportion would be in size between a baseball and a football. The air and all other gases are believed to be made up of molecules in rapid motion, striking and rebounding continually from one another and from any objects in contact with the gas.
7. States of Matter Defined.—These ideas of the structure of matter assist us in understanding the following definitions: A solid is that state of matter in which the molecules strongly cling together and tend to keep the same relative positions. (This of course follows from the tendency of a solid to retain a definite form.) A liquid is that state of matter in which the molecules tend to cling together, yet move about freely. Hence a liquid takes the form of any vessel in which it is placed. A gas is that state of matter in which the molecules move about freely and tend to separate indefinitely. Hence a gas will fill any space in which it is placed.
8. Effect of Heat on Matter.—It is further believed that when a body is heated, that the action really consists in making its molecules move or vibrate faster and faster as the heating progresses. This increase of motion causes the molecules to push apart from one another and this separation of the molecules causes an expansion of the body whether it be solid, liquid, or gas. Fig. 1 shows the expansion of air in an air thermometer. Fig. 2 shows the expansion of a solid on heating.
Fig. 1.—When the bulb is heated, the air within expands forcing down the water in the tube.
9. Physical and Chemical Changes. A change of state such as the freezing or boiling of water is called a physical change, for this change has not affected the identity of the substance. It is water even though it has become solid or gaseous. Heating a platinum wire red hot is also a physical change for the wire when on cooling is found to be the same substance as before. Further if salt or sugar be dissolved in water the act of solution is also a physical change since the identical substance (salt or sugar) is in the solution and may be obtained by evaporating the water.
Fig. 2 (a) represents a straight bar made of a strip of brass and a strip of iron riveted together and attached to a handle. Upon heating the compound bar in a gas flame, the brass expands faster than the iron causing the bar to bend toward the latter as in Fig. 2 (b).
If some sugar, however, is heated strongly, say in a test-tube, it is found to blacken, some water is driven off and on cooling some black charcoal is found in the tube instead of the sugar. This action which has resulted in a change in the nature of the substance treated is called a chemical change. To illustrate further, if some magnesium wire is heated strongly in a flame, it burns, giving off an intense light and when it cools one finds it changed to a light powdery substance like ashes. Chemical changes, or those that change the nature of the substance affected, are studied in chemistry. In physics we have to do only with physical changes, that is, with those changes that do not affect the nature of the substance.