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Magma Redox Geochemistry
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Страница 1
Table of Contents
List of Tables
List of Illustrations
Guide
Pages
Страница 7
Страница 8
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1 Redox Equilibria: From Basic Concepts to the Magmatic Realm
ABSTRACT
1.1. GENERAL ASPECTS AND RATIONALE 1.1.1. Oxidation Number, Electron Transfer, and Half‐Reactions
1.1.2. The Redox Potential in Solutions and the Ligand Role
1.2. OXYGEN FUGACITY: THE CENTRALITY OF AN ELUSIVE PARAMETER
1.3. CONCLUDING REMARKS AND PERSPECTIVES
ACKNOWLEDGMENTS
REFERENCES
Страница 20
2 Redox Processes Before, During, and After Earth’s Accretion Affecting the Deep Carbon Cycle
ABSTRACT
2.1. THE REDOX STATE OF PLANETARY INTERIORS AND THE SPECIATION OF CARBON IN THE EARTH
2.2. OXIDATION STATE OF EARTH’S BUILDING BLOCKS AND EARLY DIFFERENTIATION
2.2.1. The Solar Nebula Redox State
The fO2 of Chondrites.
The fO2 of Planetesimals and the Role of Volatiles.
The Oxidation State of Earth’s Interior, Other Planets, and Meteorites.
2.3. MANTLE OXIDATION STATE OVER TIME AND ITS EFFECT ON THE C–O–H VOLATILE SPECIATION
2.3.1. The Redox State of the Upper Mantle and the Mobilization of Deep C
2.3.2. Is the fO
2
of the Transition Zone and Lower Mantle Recorded by Sublithospheric Diamonds?
2.3.3. Temporal and Spatial Evolution of the Redox State of the Asthenospheric Mantle
2.4. THE MANTLE GREAT OXIDATION EVENT: FACT OR ARTEFACT?
ACKNOWLEDGMENTS
REFERENCES
3 Oxygen Fugacity Across Tectonic Settings
ABSTRACT
3.1. INTRODUCTION
3.1.1. Theoretical Background
3.1.2. Fe‐Based Oxybarometry
3.1.3. Trace‐Element Oxybarometry
3.1.4. Other Oxybarometers
3.2. SAMPLE SELECTION, METHODOLOGY, AND DESIGN OF THIS STUDY
3.3. RESULTS
3.3.1. Fe‐Based Oxybarometry
Mid‐Ocean Ridges.
Arcs and Back Arcs.
Plumes.
3.3.2. V/Yb Concentrations
3.4. DISCUSSION
3.4.1. Linking the
f
O
2
of Volcanics and Mantle Lithologies
Degassing.
Crystal Fractionation.
Inferences about Mantle fO2
as a Function of Tectonic Setting.
3.5. CONCLUSIONS AND FUTURE DIRECTIONS
ACKNOWLEDGMENTS
METHODS APPENDIX
REFERENCES
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