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Table of Contents

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Cover

Title Page Volume 1 Tutorial Lectures and Mechanism Studies

Copyright Page

Dedication Page

List of Contributors

Preface to Handbook of Aggregation‐Induced Emission

Preface to Volume 1: Fundamentals

1 The Mechanistic Understanding of the Importance of Molecular Motions to Aggregation‐induced Emission 1.1 Introduction 1.2 Restriction of Intramolecular Motion 1.3 Restricted Access to Conical Intersection 1.4 Restriction of Access to the Dark State 1.5 Suppression of Kasha’s Rule 1.6 Through Space Conjugation 1.7 Perspective References

2 Understanding the AIE Mechanism at the Molecular Level 2.1 Introduction 2.2 Theoretical Methods 2.3 Revealed AIE Mechanism 2.4 Visualize Calculated Parameters in Experiments 2.5 Molecular Design Based on AIE Mechanism 2.6 Summary and Outlook Acknowledgments References

10  3 Aggregation‐induced Emission from the Restriction of Double Bond Rotation at the Excited State 3.1 Introduction 3.2 AIE Phenomena and Applications from RDBR Mechanism 3.3 Conclusions References

11  4 The Expansion of AIE Thought 4.1 Aggregation‐Induced Emission 4.2 Photoluminescence Materials Based on Molecular Set 4.3 Mechanoluminescence Materials Based on Molecular Set 4.4 Mechanochromism Materials 4.5 Room Temperature Phosphorescence Materials Based on Molecular Uniting 4.6 Conclusion and Perspectives References

12  5 Clusterization‐Triggered Emission 5.1 Introduction 5.2 Pure n‐Electron Systems 5.3 Pure π‐Electron Systems 5.4 (n, π)‐Electrons Systems 5.5 Other Systems 5.6 Summary References

13  6 Crystallization‐induced Emission Enhancement 6.1 Introduction 6.2 Tetraphenylethylene Derivatives 6.3 CIEE Active Luminogens with Bulky Conjugation Core 6.4 Other High‐contrast CIEE Luminogens 6.5 Potential Applications 6.6 Summary and Perspective References

14  7 Surface‐fixation Induced Emission 7.1 Introduction 7.2 What Happened to the Characteristics of Molecules on the Clay Mineral Nanosheets 7.3 Clay–Molecular Complexes 7.4 Absorption Spectra of Clay–Molecular Complexes 7.5 Emission Enhancement Phenomenon in Clay–Molecular Complexes: S‐FIE 7.6 Mechanism of Surface‐Fixation Induced Emission 7.7 Summary and Outlook Acknowledgment References

15  8 Aggregation‐induced Delayed Fluorescence 8.1 Introduction 8.2 Novel Aggregation‐induced Delayed Fluorescence Luminogens 8.3 Conclusion and Outlook References

16  9 Homogeneous Systems to Induce Emission of AIEgens 9.1 Introduction 9.2 Homogeneous Solution 9.3 Liquid 9.4 Gels and Network Polymers 9.5 Crystalline Materials 9.6 Outlook and Future Perspectives References

17  10 Hetero‐aggregation‐induced Tunable Emission (HAITE) Through Cocrystal Strategy 10.1 Introduction 10.2 Interactions Within Organic Cocrystals 10.3 Preparation of Organic Cocrystals 10.4 Molecular Stacking Modes Within Organic Cocrystals 10.5 Characterization of Organic Cocrystals 10.6 HAITE Through Cocrystal Strategy 10.7 Summary and Outlook References

18  11 Anti‐Kasha Emission from Organic Aggregates 11.1 Introduction 11.2 Anti‐Kasha Emission from Aromatic Carbonyl Compounds in Aggregates 11.3 Anti‐Kasha Emission from Azulene Compounds in Aggregate 11.4 Anti‐Kasha Emission from Other Unconventional Aromatic Compounds in Aggregates 11.5 Conclusions References

19  12 Aggregation‐enhanced Emission: From Flexible to Rigid Cores 12.1 Introduction 12.2 Freely Moving Rotors‐induced Emission Enhancement 12.3 Guest‐induced Emission Enhancement 12.4 Conclusion Acknowledgment References

20  13 Room‐temperature Phosphorescence of Pure Organics 13.1 Introduction 13.2 Fundamental Mechanism in Organic Phosphorescence 13.3 Recent Progress in Organic RTP Materials 13.4 Conclusions and Perspectives References

21  14 A Global Potential Energy Surface Approach to the Photophysics of AIEgens: The Role of Conical Intersections 14.1 Introduction 14.2 Methodological Aspects 14.3 CI‐centered Global PES for AIEgens 14.4 Crystallization‐induced Phosphorescence 14.5 Effect of Intermolecular and Intramolecular Interactions on the Photophysics of AIEgens 14.6 New Challenges 14.7 Conclusions and Outlook References

22  15 Multicomponent Reactions as Synthetic Design Tools of AIE and Emission Solvatochromic Quinoxalines 15.1 Introduction 15.2 Synthetic Approaches to Quinoxalines via Multicomponent Reactions and One‐Pot Processes 15.3 Photophysical Properties and Emission Solvatochromicity of Quinoxalines 15.4 AIE Characteristics and Effects of Quinoxalines 15.5 Conclusion Acknowledgments References

23  16 Aggregation‐induced Emission Luminogens with Both High‐luminescence Efficiency and Charge Mobility 16.1 Introduction 16.2 p‐Type OSCs 16.3 n‐Type OSCs 16.4 Ambipolar OSCs 16.5 Conclusion and Perspective References

24  17 Morphology Modulation of Aggregation‐induced Emission 17.1 Introduction 17.2 Aggregation Modulation of AIE Bioprobes via Hydrophilicity Improvement 17.3 Thermodynamic Self‐assembly of AIE Materials 17.4 Morphology Tuning of AIE Nanoaggregates 17.5 Kinetic‐driven Preparation of AIE NPs 17.6 Conclusion and Outlook References

25  18 AIE‐active Polymer 18.1 Introduction 18.2 Photophysical Properties 18.3 Applications 18.4 Conclusion and Perspective Acknowledgments References

26  19 Liquid‐crystalline AIEgens 19.1 Introduction 19.2 Materials: Molecular Design 19.3 Applications of LC AIEgens 19.4 Conclusion References

27  20 Push–Pull AIEgens 20.1 Introduction 20.2 Basic Concept of Molecular Design 20.3 Push–Pull AIEgens from Rotor Structure 20.4 Push–Pull AIEgens from ACQ Chromophores 20.5 Concluding Remarks References

28  Index

29  End User License Agreement

Handbook of Aggregation-Induced Emission, Volume 1

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